Concept explainers
a.
Interpretation: All the constitutional isomers that have molecular formulas
Concept Introduction: The molecules that possess the same molecular formula but differ in the structural arrangement of atoms in the molecule are said to be isomers of each other.
a.
Answer to Problem 32PP
Explanation of Solution
For the first isomer structure, all two-carbon atoms are written in a straight chain and the chlorine atom is bonded to one of the carbon atoms as:
There is no other possibility for the different structural formula
b.
Interpretation: All the constitutional isomers that have molecular formulas
Concept Introduction: The molecules that possess the same molecular formula but differ in the structural arrangement of atoms in the molecule are said to be isomers of each other.
b.
Answer to Problem 32PP
Isomer I:
Isomer II:
Explanation of Solution
The different structural the arrangement of atoms in the molecule
- All two-carbon atoms are written in a straight chain and two chlorine atoms are bonded to one of the carbon atoms resulting in:
- Interchanging the position of one hydrogen atom at first carbon with one chlorine atom of the second carbon atom.
Isomer I:
Isomer II:
c.
Interpretation: All the constitutional isomers that have molecular formulas
Concept Introduction: The molecules that possess the same molecular formula but differ in the structural arrangements of atoms in the molecule are said to be isomers of each other.
c.
Answer to Problem 32PP
Isomer I:
Isomer II:
Explanation of Solution
The different structural arrangement of atoms in the molecule
- All two-carbon atoms are written in a straight chain and three chlorine atoms are bonded to one of the carbon atoms resulting in:
- Interchanging the position of one hydrogen atom at first carbon with one chlorine atom of the second carbon atom.
Isomer I:
Isomer II:
d.
Interpretation: All the constitutional isomers that have molecular formulas
Concept Introduction: The molecules that possess the same molecular formula but differ in the structural arrangements of atoms in the molecule are said to be isomers of each other.
d.
Answer to Problem 32PP
Isomer I:
Isomer II:
Isomer III:
Isomer IV:
Isomer V:
Explanation of Solution
The different structural arrangement of atoms in the molecule
- All six-carbon atoms are written in a straight chain resulting in:
- Five-carbon atoms are written in a straight chain and a methyl group is attached to the second carbon resulting in:
- Five-carbon atoms are written in a straight chain and a methyl group is attached to the third carbon resulting in:
- Four-carbon atoms are written in a straight chain and a methyl group is attached to the second and third carbon resulting in:
- Four-carbon atoms are written in a straight chain and two methyl groups are attached to the second carbon resulting in:
Isomer I:
Isomer II:
Isomer III:
Isomer IV:
Isomer V:
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Chapter 1 Solutions
ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
- 8. CH3CCH (propyne or methylacetylene) Projection Drawing: Perspective Drawing: lives a. Predict the angel HCC (the first carbon) CCC. b. Predict the molecular geometry around each carbon atomarrow_forwardWhich of the following C-C bonds is the shortest? A. в D E Select one: O a. A O b. B O c. C O d. D О е. Еarrow_forwardHow are the molecules in the following pair related? H3C CH₂ CH₂ CI Select one: O A. III O B. II O C. I H₂C-CH CI I. They are isomers. II. They are resonance structures. III. Neither of the choices is correct. CH3arrow_forward
- 7. Which of the molecules below is a constitutional isomer of the other three? Me Н. Me H H. H H H. Me Et Me H H. Me H Ét i-Pr H. A D. B.arrow_forward4. Provide the molecular formula and draw the skeletal structure for the following molecules. H.. HH N-H H:0: C-H H. H. H H-c-C-H CH3 H2 H3C C. N. H. H. C-H C-H 'N. CH3 CH3 C. H H H. Serotonin Caffeinearrow_forward2. What type of chemical bonding is present in the following compound? CH3CH2CH2CH2Br O a. A O b. B O C. C O d. D A) Polar covalent B) Hydrogen C) lonic D) polar covalent and non-polar covalentarrow_forward
- 1. What is the relationship between the following compounds? H :0: H H:0: H H-C=C-C-C-C-H H-C-C-C=Ċ-H H HH H. H-C-H B. constitutional isomers C. the same structure A. isotopes D. composed of different elements E. no relationship 2. What is the correct Lewis structure for HN3, including the formal charges? CIHarrow_forwardof How are the molecules in the following pair related? NH H₂C CH3 Select one: A. III OB. II O C. I and I. They are isomers. II. They are resonance structures. III. They are different compounds, not isomers. Clear my choice H₂C OH NHarrow_forwarda. Which bond would be longer? b. Which bond would be stronger? 1. C - Cl or C - I 2 C - C or C - Cl 3 H - Cl or H - Farrow_forward
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning