ORGANIC CHEMISTRY
6th Edition
ISBN: 9781264073610
Author: SMITH
Publisher: MCG
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 1, Problem 87P
Interpretation Introduction
Interpretation: The reason corresponding to the fact that the given carbocation A is more stable than given carbocation B is to be stated by using the principles of resonance theory.
Concept introduction: The method by which overall delocalization of electrons can be described in a particular molecule is known as resonance.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Determining the Relative Energy of Resonance Structures and the Hybrid Draw a second resonance structure for carbocation A, as well as the hybrid of both resonance structures. Then use Rules [1]–[3] to rank the relative stability of both resonance structures and the hybrid.
Use the principles of resonance theory to explain why carbocation A ismore stable than carbocation B.
The bond dissociation energy of one of the C–H bonds is considerablyless than the bond dissociation energy of the other. Which C–H bondis weaker? Offer an explanation.
Chapter 1 Solutions
ORGANIC CHEMISTRY
Ch. 1.1 - While the most common isotope of nitrogen has a...Ch. 1.2 - Label each bond in the following compounds as...Ch. 1.3 - Draw a valid Lewis structure for each species. a....Ch. 1.3 - Prob. 9PCh. 1.4 - Draw Lewis structures for each molecular formula....Ch. 1.6 - Classify each pair of compounds as isomers or...Ch. 1.6 - Prob. 12PCh. 1.6 - Prob. 13PCh. 1.6 - Prob. 14PCh. 1.6 - Prob. 16P
Ch. 1.6 - Prob. 17PCh. 1.7 - Prob. 18PCh. 1.7 - Prob. 19PCh. 1.7 - Using the principles of VSEPR theory, you can...Ch. 1.8 - Convert each condensed formula to a Lewis...Ch. 1.8 - Prob. 22PCh. 1.8 - Prob. 23PCh. 1.8 - Convert each skeletal structure to a complete...Ch. 1 - Citric acid is responsible for the tartness of...Ch. 1 - Zingerone gives ginger its pungent taste. a.What...Ch. 1 - Assign formal charges to each and atom in the...Ch. 1 - Prob. 44PCh. 1 - Prob. 46PCh. 1 - Draw all possible isomers for each molecular...Ch. 1 - 1.45 Draw Lewis structures for the nine isomers...Ch. 1 - Prob. 52PCh. 1 - Prob. 53PCh. 1 - Prob. 54PCh. 1 - Consider compounds A-D, which contain both a...Ch. 1 - Draw in all the carbon and hydrogen atoms in each...Ch. 1 - 1.61 Convert each molecule into a skeletal...Ch. 1 - Prob. 65PCh. 1 - Predict the hybridization and geometry around each...Ch. 1 - Prob. 68PCh. 1 - Ketene, , is an unusual organic molecule that has...Ch. 1 - Rank the following bonds in order of increasing...Ch. 1 - Two useful organic compounds that contain Cl atoms...Ch. 1 - Use the symbols + and to indicate the polarity of...Ch. 1 - Prob. 74PCh. 1 - Anacin is an over-the-counter pain reliever that...Ch. 1 - 1.77 Stalevo is the trade name for a medication...Ch. 1 - 1.78 and are two highly reactive carbon...Ch. 1 - 1.79 The N atom in (acetamide) is hybridized,...Ch. 1 - Prob. 83PCh. 1 - Prob. 84PCh. 1 - Prob. 85PCh. 1 - Prob. 86PCh. 1 - Prob. 87PCh. 1 - Prob. 88P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Structures with carbocations can often also have resonance forms. Draw the other resonance structure for the moleculearrow_forward14. With reference to compound A, is compound B an isomer, resonance structure or neither? d Compound A Compound Barrow_forwardHydrocarbon A possesses a significant dipole, even though it is composed of only C—C and C—H bonds. Explain why the dipole arises and use resonance structures to illustrate the direction of the dipole. Which ring is more electron rich?arrow_forward
- Fluorene is essentially non-polar. Briefly explain, with respect to atoms that are present and absent in fluorene, and their relative electronegativities, why fluorene is non-polar.arrow_forwardAll are true or false a) A radical contains an atom that has an octet of electrons. b) Chlorination is faster than bromination. c) Less stable radicals generally do not rearrange to more stable radicals.arrow_forward3. Which of the following molecules are conjugated? For those which are conjugated, write a resonance structure.arrow_forward
- Considering the indicated carbon–halogen bonds, which bond is predicted to have the higher bond dissociation energy? Which bond is stronger?arrow_forwardThe following is generic depiction of a reaction using the curve arrow formalism. -D Which of these statements is not correct for this reaction? Electrons move from C to B. Electrons move from B to A. O In the products, a bond forms between C and B. O In the products, A would have a positive charge.arrow_forwardWhat resonance hybrid of benzene explains ?arrow_forward
- Hydrocarbon A possesses a significant dipole, even though it iscomposed of only C—C and C—H bonds. Explain why the dipole arisesand use resonance structures to illustrate the direction of the dipole.Which ring is more electron rich?arrow_forward1. What is resonance theory? State five conclusionstgan can be drawn from the theory. 2.What factors confer aromaticity to an organic molecule. 3. What are the various ways by which alkenes can be synthesized. 4. State the two main experiment that were used to establish the extra stability of the benzene molecule.arrow_forwardWhich of the following concepts explains why a tertiary carbocation is more stable than a primary carbocation? a. Hyperconjugation b. Resonance c. Electronegativity T d. he octet rulearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co