(a)
Interpretation:
The synthesis of
Concept introduction:
Oxymercuration reaction is a type of reaction in which an
Answer to Problem 11.61AP
The synthesis of
Explanation of Solution
The mercuric acetate
Figure 1
The route of synthesis of the formation of
(b)
Interpretation:
The synthesis of
Concept introduction:
The substances which on addition removes oxygen atom or hydrogen atom from the other substance, that is, reduces the other substances are known as reducing agents. Reducing agents themselves get oxidized. Strong reducing agents like
Answer to Problem 11.61AP
The synthesis of
Explanation of Solution
The treatment of
Figure 2
The route of synthesis of the formation of
(c)
Interpretation:
The synthesis of
Concept introduction:
Grignard reagents are
Answer to Problem 11.61AP
The synthesis of
Explanation of Solution
The reaction of tert-butyl bromide with
Figure 3
The route of synthesis of the formation of
(d)
Interpretation:
The synthesis of the given compound from the compounds that contain
Concept introduction:
Oxidation is the process in which there is an addition of oxygen atom or removal of hydrogen atom. The agents used for the oxidation reaction is known as oxidizing agents. It oxidizes the other substance and gets reduced in the reaction. The common oxidizing agents are nitric acid, oxygen and potassium dichromate.
Answer to Problem 11.61AP
The synthesis of the given compound from the compounds that contain
Explanation of Solution
The reaction of ethnethiol with
Figure 4
The synthesis of the given compound from the compounds that contain
(e)
Interpretation:
The synthesis of the given compound from an alkene is to be drawn.
Concept introduction:
Oxidation is the process in which there is an addition of oxygen atom or removal of hydrogen atom. The agents used for the oxidation reaction is known as oxidizing agents. It oxidizes the other substance and gets reduced in the reaction. The common oxidizing agents are nitric acid, oxygen and potassium dichromate.
Answer to Problem 11.61AP
The synthesis of the given compound from an alkene is shown below.
Explanation of Solution
The reaction of
Figure 5
The synthesis of the given compound from an alkene is shown in Figure 5.
(f)
Interpretation:
The synthesis of cyclohexyl isopropyl ether from cyclohexene is to be drawn.
Concept introduction:
Oxidation is the process in which there is an addition of oxygen atom or removal of hydrogen atom. The agents used for the oxidation reaction is known as oxidizing agents. It oxidizes the other substance and gets reduced in the reaction. The common oxidizing agents are nitric acid, oxygen and potassium dichromate.
Answer to Problem 11.61AP
The synthesis of cyclohexyl isopropyl ether from cyclohexene is shown below.
Explanation of Solution
The compound,
Figure 6
The synthesis of cyclohexyl isopropyl ether from cyclohexene is shown Figure 6.
(g)
Interpretation:
The synthesis of cyclohexyl isopropyl ether from cyclohexene is to be drawn.
Concept introduction:
Oxymercuration reaction is a type of reaction in which an alkene gets converted to alcohol. The mercuric acetate is used in the reaction as a reagent. This reagent attacks the alkene to form a cyclic intermediate compound which further undergoes reduction to form alcohol.
Answer to Problem 11.61AP
The synthesis of cyclohexyl isopropyl ether from cyclohexene is shown below.
Explanation of Solution
The mercuric acetate
Figure 7
The synthesis route of cyclohexyl isopropyl ether from cyclohexene is shown in Figure 7.
(h)
Interpretation:
The synthesis of the given compound from
Concept introduction:
Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases
Answer to Problem 11.61AP
The synthesis of the given compound from
Explanation of Solution
Bromination of alkene occurs with
Grigmard reagent reacts with the ethylene oxide followed by the hydrolysis to form an alcohol which upon oxidation by
Figure 8
The synthesis of the given compound from
(i)
Interpretation:
The synthesis of the given compound from
Concept introduction:
An
Oxidation is the process in which there is an addition of oxygen atom or removal of hydrogen atom. The agents used for the oxidation reaction is known as oxidizing agents. It oxidizes the other substance and gets reduced in the reaction. The common oxidizing agents are nitric acid, oxygen and potassium dichromate.
Answer to Problem 11.61AP
The synthesis of the given compound from
Explanation of Solution
Epoxidation of
Figure 9
The synthesis route of the given compound from
(j)
Interpretation:
The synthesis of the given compound from
Concept introduction:
An epoxide is cyclic ether. It can be prepare by the reaction of alkene with percarboxylic acid with removal of carboxylic acid. An epoxide undergoes ring opening reactions with an acid to give a product with inversion configuration.
Oxidation is the process in which there is an addition of oxygen atom or removal of hydrogen atom. The agents used for the oxidation reaction is known as oxidizing agents. It oxidizes the other substance and get reduced in the reaction. The common oxidizing agents are nitric acid, oxygen and potassium dichromate.
Answer to Problem 11.61AP
The synthesis of the given compound from
Explanation of Solution
Epoxidation of
Figure 10
The synthesis route of the given compound from
(k)
Interpretation:
The synthesis of given compound from the allyl chloride is to be drawn.
Concept introduction:
The nucleophilic substitution reactions depend upon the nucleophilicity and concentration of the nucleophile. There are two types of nucleophilic substitution reaction.
The
Answer to Problem 11.61AP
The synthesis of given compound from the allyl chloride is shown below.
Explanation of Solution
Allyl chloride reacts with
Figure 11
The synthesis of given compound from the allyl chloride is shown in Figure 11.
(l)
Interpretation:
The synthesis of the given compound is to be drawn.
Concept introduction:
Wolff Kishner Reduction is a reaction in which aldehydes and
Answer to Problem 11.61AP
The synthesis of the given compound is shown below.
Explanation of Solution
The reaction of cyclopentenyl methanol with
Figure 12
The synthesis of the given compound is shown in Figure 12.
(m)
Interpretation:
The synthesis of the given compound is to be drawn.
Concept introduction:
The substances which on addition removes oxygen atom or hydrogen atom from the other substance, that is, reduces the other substances are known as reducing agents. Reducing agents themselves get oxidized. Strong reducing agents like
Answer to Problem 11.61AP
The synthesis of the given compound is shown below.
Explanation of Solution
The alcohol is reduced in presence of
Figure 13
The synthesis of the given compound is shown in Figure 13.
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- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningEBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENT