Intro Spectroscopy
Intro Spectroscopy
5th Edition
ISBN: 9781305221796
Author: PAVIA
Publisher: Cengage
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The first three absorption lines in the pure rotational spectrum of gaseous 12C16O are found to have the frequencies 1.15 × 1011, 2.30 × 1011, and 3.46 × 1011 s21. Calculate:(a) The moment of inertia I of CO (in kg m2)(b) The energies of the J 5 1, J 5 2, and J 5 3 rotational levels of CO, measured from the J 5 0 state (in joules)(c) The CUO bond length (in angstroms)
Assume that the H2 molecule behaves exactly like a harmonic oscillator with a force constant of 573N/m. (a) Find the energy (in eV) of its ground and first excited vibrational states. (b) Find the vibrational quantum number that approximately corresponds to its 4.5-eV dissociation energy.
A CO molecule is initially in the n = 2 vibrational level. If this molecule loses both vibrational and rotational energy and emits a photon, what are the photon wavelength and frequency if the initial angular momentum quantum number is l = 3?
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