Organic Chemistry
7th Edition
ISBN: 9789332519046
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 1.13, Problem 35P
(a)
Interpretation Introduction
Interpretation:
The longer bond should be determined for given set of bonds.
(b)
Interpretation Introduction
Interpretation:
The stronger bond should be determined for given set of bonds.
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For each pair, circle the more polar bond
N—H or O—H
Br—F or Cl—F
Cl—H or B—H
H—F or H—C
S—Br or F—Br
Which is the strongest bond energy?
Cl(g) ΔH°f, = +121.3 kJ mol–1
CCl4(g) ΔH°f, = –95.98 kJ mol–1
HCl(g) ΔH°f, = –92.3 kJ mol–1
Question 8 options:
Cl–Cl in Cl2
H–Cl in HCl
C–Cl in CCl4
Rank these three hydrocarbons from weakest to strongest C–C bond.
C2H6 , C2H4 , C2H2
Rank these three hydrocarbons from shortest to longest C–C bond.
C2H6 , C2H4 , C2H2
Chapter 1 Solutions
Organic Chemistry
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 3PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...Ch. 1.3 - Explain why HCL has a smaller dipole moment than...
Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 15PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 19PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 21PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 23PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 32PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 35PCh. 1.14 - Prob. 36PCh. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - Prob. 41PCh. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - What of the following molecules would you expect...Ch. 1 - Prob. 46PCh. 1 - Prob. 47PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 51PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - 53. What is the hybridization of each of the...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Prob. 57PCh. 1 - Prob. 58PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 65PCh. 1 - Prob. 66PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 68PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - Prob. 73P
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- 25.) How many sigma and how many pi bonds are there in HCN? Write your answer as _____ sigma and _____ pi. For example, 6 sigma and 7 pi (no period at end).arrow_forwardCalculate ∆S° for NH₃(g) + HCl(g) → NH₄Cl(s). NH3 192.5 HCl 186.7 NH4Cl 94.6arrow_forwardWhich is the most polar bond? (a) CC (b) CH (c) NH (d) OH (e) Se-Harrow_forward
- Draw all possible resonance structures for each of these compounds. Determine the formal charge on each atom in each of the resonance structures: (a) O3 (b) SO2 (c) NO2 , (d) NO3arrow_forwardConsider the carbon-oxygen bond in formaldehyde (CH2O) and carbon monoxide (CO). In which molecule is the CO bond shorter? In which molecule is the CO bond stronger?arrow_forward7.35 Which one of the following contains botb ionic and covalent bonds? (a) BaCO3 , (b) MgCl2 , (c) BaO , (d) H2S , (e) So42arrow_forward
- The average C–O single bond energy is 358 kJ mol–1. The average C=O double bond energy is 799 kJ mol–1. What is the average bond energy closest to of the bond between C and O in CO32–? Question 13 options: 652 kJ mol–1 579 kJ mol–1 505 kJ mol–1arrow_forwardis more stable than 3 and 2 because ) is highest number of Covalent bond and it is natural So , is more stable than 3 , 2 . 3 ) is more stable than 6 and less stable than ou because ( 3 ) is less number of covalent bond and it is charged and it is no + charge in it . his lowest stable because - L covalent bond charged + charge in it ( unstable )arrow_forwardFor each of the following bonds, draw a figure indicating the direction of the bond dipole, including which end of the bond is positive and which is negative. a. S−Parrow_forward
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