Chemical Principles in the Laboratory
Chemical Principles in the Laboratory
11th Edition
ISBN: 9781305264434
Author: Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher: Brooks Cole
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Chapter 12, Problem 3ASA

You are given a colorless unknown solution that contains one of the following salts: NaA , NaB , NaC . In solution, each salt dissociates completely into the Na + ion and the anion A , B , or C , whose properties are given in Problem 2. The Na + ion is effectively inert. Given the availability of solutions of A 2 , B 2 , and C 2 , develop a simple procedure for identifying the salt that is present in your unknown.

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Both the reactants Sodium Carbonate and the product sodium Chloride are white solids and cannot be distinguished by looking at them. Can you think of any chemical tests you could do to prove that it is not NaCI2?
A student was given five labeled solutions: NiCl2 , Pb(NO3)2 , NaOH , Na2C2O4 , and CuSO4 .  After mixing these solutions in pairs, the student recorded her observations on Table 3.  She was then given five labeled solutions: A, B, C, D, and E.  After mixing these solutions in pairs, the student recorded her observations on Table 4.  The one thing that she does know about these solutions is that the unknowns are the same solutions as the knowns.  So what are the five unknown solutions, i.e. list out A= , B= , C= , D= , E= . Table 3: KNOWNS XXX CuSO4 Na2C2O4 NaOH Pb(NO3)2 NiCl2 NR, blue green solution NR, green solution green ppt, green solution NR, green solution Pb(NO3)2 white ppt, blue solution white ppt, clear colorless solution white ppt, clear colorless solution XXX NaOH blue ppt, blue solution NR, clear colorless solution XXX XXX Na2C2O4 white ppt, blue solution XXX XXX XXX   Table 4:  UNKNOWNS XXX E D C B A blue ppt, blue solution white ppt, clear colorless…
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