Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 12.3, Problem 2P
What
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b. 
c. 
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a. What is the chemical structure of biphenyl, circle functional groupsdifferent than alkane, alkene, alkyne? b. Is it polar or nonpolar? _______________________ c. What is its water solubility in g/L? __________________________
Draw the structure of sec-butylcycloheptane
an amount of alkene requires 5.6 liters of HCl under normal conditions to fully act. The same amount, when acting with Br2, causes a weight gain of 7 grams. Find:
a) the molecular formula of the alkene
b) the amount of alcohol required to prepare the alkene.
Chapter 12 Solutions
Organic Chemistry (6th Edition)
Ch. 12.1 - Prob. 1PCh. 12.3 - Problem 12.2 What alkane is formed when each...Ch. 12.3 - Prob. 3PCh. 12.3 - Prob. 4PCh. 12.3 - Prob. 5PCh. 12.3 - Prob. 6PCh. 12.3 - Compound Molecular formula before...Ch. 12.4 - Problem 12.8 Draw the products formed when...Ch. 12.5 - Prob. 9PCh. 12.5 - Prob. 10P
Ch. 12.5 - Problem 12.11 (a) Draw the structure of a compound...Ch. 12.5 - Prob. 12PCh. 12.5 - Prob. 13PCh. 12.6 - Problem 12.14 Draw the products of each...Ch. 12.8 - Prob. 15PCh. 12.8 - Problem 12.16 Draw all stereoisomers formed when...Ch. 12.9 - Prob. 17PCh. 12.9 - Problem 12.18 Draw the products formed when both...Ch. 12.10 - Problem 12.19 Draw the products formed when each...Ch. 12.10 - Prob. 20PCh. 12.10 - Prob. 21PCh. 12.11 - Problem 12.22 Draw the products formed when each...Ch. 12.11 - Prob. 23PCh. 12.12 - Problem 12.24 Draw the organic products in each of...Ch. 12.13 - Prob. 25PCh. 12 - 12.29 Draw the products formed when A is treated...Ch. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Prob. 33PCh. 12 - Draw the organic products formed when cyclopentene...Ch. 12 - Draw the organic products formed when allylic...Ch. 12 - Prob. 39PCh. 12 - Prob. 40PCh. 12 - Prob. 41PCh. 12 - What alkene is needed to synthesize each 1,2-diol...Ch. 12 - 12.48 Draw the products formed in each oxidative...Ch. 12 - What alkene or alkyne yields each set of products...Ch. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Prob. 50PCh. 12 - 12.57 Draw the product of each asymmetric...Ch. 12 - 12.60 Identify A in the following reaction...Ch. 12 - Prob. 58PCh. 12 - 12.62 It is sometimes necessary to isomerize a cis...Ch. 12 - 12.63 Devise a synthesis of each compound from...Ch. 12 - Prob. 61P
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- Give the IUPAC name for each alkene.arrow_forwarda) Write the name b) draw the structure product formed from the reaction of 3-methylpent-2-ene 1) H2O in the presence of H2SO4 2)ethanol in the presence of H2SO4arrow_forwardRank each group of alkanes in order of increasing boiling point. Explain your choice of order.arrow_forward
- Give an IUPAC name for the following as hydrocarbons with the benzene ring as a substituent: a. b.arrow_forwardWhat reactions are needed to convert alcohol A to either alkyne B or alkyne C?arrow_forwardCompare the boiling point of toluene, cyclohexene, and heptane. Why the molecular mass of toluene is lower than the of heptane, but the boiling point of toluene is higher than heptane? Why cyclohexane are unsaturated but lower boiling point than heptane?arrow_forward
- Ethers (general formula R—O—R)have many important uses. Until recently,methyl tert-butyl ether (MTBE, right)was used as an octane booster and fueladditive for gasoline. It increases the oxy-gen content of the fuel, which reducesCO emissions. MTBE is synthesized bythe catalyzed reaction of 2-methylpropene with methanol.(a) Write a balanced equation for the synthesis of MTBE. (Hint:Alcohols add to alkenes similarly to the way water does.)(b) If the government required that auto fuel mixtures contain2.7% oxygen by mass to reduce CO emissions, how many gramsof MTBE would have to be added to each 100. g of gasoline?(c) How many liters of MTBE would be in each liter of fuel mix-ture? (The density of both gasoline and MTBE is 0.740 g/mL.)(d) How many liters of air (21% O₂ by volume) are needed at24C and 1.00 atm to fully combust 1.00 L of MTBE?arrow_forwardAlkenes are not soluble in water because they are a. polar b. hydrophilic c. hydrophobic d. less dense than waterarrow_forwardGlycerol contains: a. oxygens which are each bonded to two alkyl groups b. oxygens single-bonded to primary and secondary carbons c. Oxygens double-bonded to carbon, with alkyls on both sides d. Oxygens double-bonded to carbon, with alkyls on one side only e. Oxygens double-bonded to carbon, with an alkyl on one side and an --OH on the other sidearrow_forward
- Give the IUPAC name for each. a. I have 5-bromo-3methylheptanearrow_forwardSeveral factors can affect alkene stability. Explain why alkene A is more stable than alkene B even though both contain disubstituted carbon–carbon double bonds.arrow_forward2. a. What is the chemical structure of naphthalene, circle functional groups different than alkane,alkene, alkyne? b. Is it polar or nonpolar? _______________________ c. What is its water solubility in g/L? _________________________arrow_forward
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