ORGANIC CHEMISTRY
4th Edition
ISBN: 9781119745105
Author: Klein
Publisher: WILEY
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Chapter 12.4, Problem 11ATS
Interpretation Introduction
Interpretation:
The given reaction is the conversion of
Concept introduction:
It is done by calculating the oxidation state of the atoms. If there is an increase in the charge on any atom, it is said to be oxidized. If there is a decrease in the oxidation state of the atom, it is said to be reduced. The oxidation state of the carbon on which the change has occurred must be calculated by cleaving the bonds between carbon and the atom to which it is attached.
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I2 (aq) + CH3COCH3 (aq) HI (aq) + ICH2COCH3 (aq)Iodine in solution has a yellow-brown color, whereas the acetone and both products are colorless. This means that we can run the reaction using iodine as the limiting reagent, and when we see that the yellow-brown color of the iodine has disappeared, we know that the reaction has stopped and all of the iodine has been consumed.
Recall that to calculate a rate of reaction, we would like toknow the change in concentration of a reactant or product during a fixed amount of time. Wewill choose the reactant iodine in this case, because its brown color allows us to determinewhen its concentration has fallen to zero.
Rate = –Δ[I2] / Δt = – ([I2]final – [I2]initial) / ([tfinal – tinitial) = – (0 – [I2]initial) / (tfinal – 0) = [I2]initial / tfinal
Run several trials at different concentrations of reactants and use themethod of initial rates to obtain values for k, x, y, and z in the rate law.
Rate = k [I2]x [acetone]y [H+]z
Run the…
82. The space shuttle Orbiter utilizes the oxidation of methylhy-
drazine by dinitrogen tetroxide for propulsion:
4N₂H3CH3(1) + 5N₂O4 (1) 12H₂O(g) + 9N₂(g) + 4CO2(8)
Calculate AH for this reaction.
▬▬▬▬▬▬▬▬▬▬
8.
With refrence to the reaction observation below, write down the structural formula of X, Y
and Z. Write equation when Y react with Iodine in basic medium, Tollens reagent and
hydroxylamine.
Chapter 12 Solutions
ORGANIC CHEMISTRY
Ch. 12.1 - Prob. 1LTSCh. 12.1 - Prob. 1PTSCh. 12.1 - Prob. 2ATSCh. 12.1 - Prob. 3CCCh. 12.2 - Prob. 4CCCh. 12.3 - Prob. 8CCCh. 12.3 - Prob. 9CCCh. 12.4 - Prob. 3LTSCh. 12.4 - Prob. 10PTSCh. 12.4 - Prob. 11ATS
Ch. 12.4 - Prob. 4LTSCh. 12.4 - Prob. 12PTSCh. 12.4 - Prob. 13ATSCh. 12.6 - Prob. 14CCCh. 12.6 - Prob. 5LTSCh. 12.6 - Prob. 15PTSCh. 12.6 - Prob. 16PTSCh. 12.7 - Prob. 18CCCh. 12.9 - Prob. 6LTSCh. 12.9 - Prob. 19PTSCh. 12.9 - Prob. 20ATSCh. 12.9 - Prob. 21CCCh. 12.10 - Prob. 7LTSCh. 12.10 - Prob. 22PTSCh. 12.10 - Prob. 23ATSCh. 12.13 - Prob. 8LTSCh. 12.13 - Prob. 24PTSCh. 12.13 - Prob. 25ATSCh. 12.13 - Prob. 26CCCh. 12.13 - Prob. 9LTSCh. 12.13 - Prob. 27PTSCh. 12.13 - Prob. 28ATSCh. 12 - Prob. 29PPCh. 12 - Prob. 30PPCh. 12 - Prob. 31PPCh. 12 - Prob. 32PPCh. 12 - Prob. 33PPCh. 12 - Prob. 34PPCh. 12 - Prob. 35PPCh. 12 - Prob. 36PPCh. 12 - Prob. 37PPCh. 12 - Prob. 38PPCh. 12 - Prob. 39PPCh. 12 - Prob. 40PPCh. 12 - Prob. 41PPCh. 12 - Prob. 42PPCh. 12 - Prob. 43PPCh. 12 - Prob. 44PPCh. 12 - Prob. 45PPCh. 12 - Prob. 46PPCh. 12 - Prob. 47PPCh. 12 - Prob. 48PPCh. 12 - Prob. 49PPCh. 12 - Prob. 50PPCh. 12 - Prob. 51PPCh. 12 - Prob. 52PPCh. 12 - Prob. 53ASPCh. 12 - Prob. 54ASPCh. 12 - Prob. 55ASPCh. 12 - Prob. 62IPCh. 12 - Prob. 64IPCh. 12 - Prob. 65IPCh. 12 - Prob. 66IPCh. 12 - Prob. 67IPCh. 12 - Prob. 68IPCh. 12 - Prob. 69IPCh. 12 - Prob. 74IP
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