ETEXT+MASTERINGCHEMISTRY STANDALONE AC
7th Edition
ISBN: 9781269736947
Author: Bruice
Publisher: PEARSON
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Textbook Question
Chapter 12.4, Problem 17P
Show how the Suzuki and/or Heck reactions can be used to prepare the following compounds:
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Propose a synthesis for the following molecule starting from benzene. Be sure to show all necessary reagents and the intermediates after each reaction. You do not need to show reaction mechanisms.
Choose the right reagent or series of reagents from the ones listed below to prepare 2-pentanone from acetylene.
NaNH2NaNH2 followed by CH3CH2CH2BrCH3CH2CH2Br, then disiamylborane followed by H2O2H2O2, HO−HO−
H2H2, Lindlar followed by H2OH2O, H+H+
NaNH2NaNH2 and CH3CH2CHOCH3CH2CHO
NaNH2NaNH2 followed by H2OH2O, H+H+
NaNH2NaNH2 followed by CH3CH2CH2BrCH3CH2CH2Br, then H2OH2O, H2SO4H2SO4, HgSO4
Choose one.
How would you accomplish the following conversion of nitrobenzene to benzene?
Chapter 12 Solutions
ETEXT+MASTERINGCHEMISTRY STANDALONE AC
Ch. 12.1 - Prob. 1PCh. 12.2 - Which is more reactive an organolithium compound...Ch. 12.2 - Prob. 3PCh. 12.3 - PROBLEM 6♦
Explain why tertiary alkyl halides...Ch. 12.3 - Muscalure is the sex attractant of the common...Ch. 12.3 - Prob. 8PCh. 12.3 - Prob. 9PCh. 12.3 - Prob. 10PCh. 12.4 - Prob. 13PCh. 12.4 - Prob. 14P
Ch. 12.4 - Prob. 15PCh. 12.4 - Show how the Suzuki and/or Heck reactions can be...Ch. 12.4 - Identify two pairs of an alkyl bromide and an...Ch. 12.5 - Prob. 19PCh. 12.5 - Draw the product of ring-closing metathesis for...Ch. 12.5 - Prob. 22PCh. 12 - Prob. 23PCh. 12 - Prob. 24PCh. 12 - Identify A through H.Ch. 12 - 26. Using the given starting material, any...Ch. 12 - Prob. 27PCh. 12 - Prob. 28PCh. 12 - Prob. 29PCh. 12 - Using ethynyleyclohexane as a starting material...Ch. 12 - Prob. 31PCh. 12 - Using the given starting material, any necessary...Ch. 12 - Prob. 33PCh. 12 - A student added an equivalent of...Ch. 12 - Using the given starting material, any necessary...Ch. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - Bombykol is the sex pheromone of the silk moth....Ch. 12 - Prob. 39PCh. 12 - A dibromide loses only one bromine when it reacts...Ch. 12 - What starting material is required in order to...Ch. 12 - Prob. 42PCh. 12 - Prob. 1PCh. 12 - Prob. 2PCh. 12 - Prob. 3PCh. 12 - Prob. 4P
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