Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 12.4, Problem 8P
Draw the products formed when triacylglycerol A is treated with each reagent, forming compounds
B and C. Rank A, B, and C in order of increasing melting point.
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Draw the products formed when triacylglycerol A is treated with each reagent. Rank compounds A, B, and C in order of increasing melting point.
Draw the products formed when triacylglycerol A is treated with each reagent. Rank compounds A, B, and C in order of increasing melting point.a. H2O, H+b. H2 (excess), Pd-C → Bc. H2(1 equiv), Pd-C → C
Write the structure of the following compounds: γ-lactol
Chapter 12 Solutions
Organic Chemistry (6th Edition)
Ch. 12.1 - Prob. 1PCh. 12.3 - Problem 12.2 What alkane is formed when each...Ch. 12.3 - Prob. 3PCh. 12.3 - Prob. 4PCh. 12.3 - Prob. 5PCh. 12.3 - Prob. 6PCh. 12.3 - Compound Molecular formula before...Ch. 12.4 - Problem 12.8 Draw the products formed when...Ch. 12.5 - Prob. 9PCh. 12.5 - Prob. 10P
Ch. 12.5 - Problem 12.11 (a) Draw the structure of a compound...Ch. 12.5 - Prob. 12PCh. 12.5 - Prob. 13PCh. 12.6 - Problem 12.14 Draw the products of each...Ch. 12.8 - Prob. 15PCh. 12.8 - Problem 12.16 Draw all stereoisomers formed when...Ch. 12.9 - Prob. 17PCh. 12.9 - Problem 12.18 Draw the products formed when both...Ch. 12.10 - Problem 12.19 Draw the products formed when each...Ch. 12.10 - Prob. 20PCh. 12.10 - Prob. 21PCh. 12.11 - Problem 12.22 Draw the products formed when each...Ch. 12.11 - Prob. 23PCh. 12.12 - Problem 12.24 Draw the organic products in each of...Ch. 12.13 - Prob. 25PCh. 12 - 12.29 Draw the products formed when A is treated...Ch. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Prob. 33PCh. 12 - Draw the organic products formed when cyclopentene...Ch. 12 - Draw the organic products formed when allylic...Ch. 12 - Prob. 39PCh. 12 - Prob. 40PCh. 12 - Prob. 41PCh. 12 - What alkene is needed to synthesize each 1,2-diol...Ch. 12 - 12.48 Draw the products formed in each oxidative...Ch. 12 - What alkene or alkyne yields each set of products...Ch. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Prob. 50PCh. 12 - 12.57 Draw the product of each asymmetric...Ch. 12 - 12.60 Identify A in the following reaction...Ch. 12 - Prob. 58PCh. 12 - 12.62 It is sometimes necessary to isomerize a cis...Ch. 12 - 12.63 Devise a synthesis of each compound from...Ch. 12 - Prob. 61P
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- What products are formed by hydrolysis of each lactone or lactam with acid?arrow_forwarddraw the products formed when triacylglycerol is treated with: H2 (excess), Pd-Carrow_forward1. Draw the structure of a triacylglycerol formed from glycerol, one molecule of stearic acid, and two molecules of oleic acid. The stearic acid should form an ester bond with the 2° OH group of glycerolarrow_forward
- A triglyceride can be optically active if it contains two or more different fatty acids.(a) Draw the structure of an optically active triglyceride containing one equivalent of myristic acid and two equivalentsof oleic acid.(b) Draw the structure of an optically inactive triglyceride with the same fatty acid composition.arrow_forward1. Some marine plankton contain triacylglycerols formed from the polyunsaturated fatty acid (PUFA) such as: CH3CH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2COOH a) Draw the skeletal structure of the given PUFA showing the preffered stereogenic arrangement for a naturally-occuring lipid at each double bond. b) Write the systematic name of the fatty acid. c) What type of omega-n acid is this fatty acid? d) Would you expect this fatty acid to be a soild or liquid at room temperature?arrow_forwardDraw the product(s) formed when the triacylglycerol A is treated with: a) H2O, H+(acidic medium) b) H2 (excess), Pd-Cc) H2 (1 equiv(, Pd-Carrow_forward
- Draw the products formed when the given triacylglycerol is hydrolyzed with water in the presence of sulfuric acidarrow_forwardDraw a triacylglycerol made from glycerol, myristic acid, palmitic acid, and oleic acid. Place palmitic acid at the middle position.arrow_forwardA triglyceride can be optically active if it contains two or more different fatty acids.(a) Draw the structure of an optically active triglyceride containing one equivalent of myristic acid and two equivalentsof oleic acidarrow_forward
- How HCl converts the hemiacetal to an acetal called a glycoside ?arrow_forwardWhat is the composition of the soap prepared by hydrolysis of the attachedtriacylglycerol?arrow_forwardDraw the products that form when the thioester CH3CH2CH2COSCoA is hydrolyzed with water. Differentiate products by greater or lesser molecular weight.arrow_forward
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