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Concept explainers
(a)
Interpretation:
Resonance contributors for the given radical has to be drawn.
Concept introduction:
Radical or free radical:
Unpaired valence electron of an atom, molecule, or ion is called as radical.
Resonance:
Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.
(b)
Interpretation:
Resonance contributors for the given radical has to be drawn.
Concept introduction:
Radical or free radical:
Unpaired valence electron of an atom, molecule, or ion is called as radical.
Resonance:
Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.
(c)
Interpretation:
Resonance contributors for the given radical has to be drawn.
Concept introduction:
Radical or free radical:
Unpaired valence electron of an atom, molecule, or ion is called as radical.
Resonance:
Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.
(d)
Interpretation:
Resonance contributors for the given radical has to be drawn.
Concept introduction:
Radical or free radical:
Unpaired valence electron of an atom, molecule, or ion is called as radical.
Resonance:
Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.
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Chapter 12 Solutions
Organic Chemistry, Books a la Carte Edition (8th Edition)
- How does the following reaction ocurre, please draw al resonance possibilities. nucleophilic aromatic substitution reactionarrow_forwardIndicate which intermediate would be the most stable resonance contributorarrow_forwardWhat are the three resonance contributors and which one is the most stable form?arrow_forward
- a) Draw all resonance forms of 3-hydroxybenzaldehyde and of the corresponding conjugate base. W hich conclusions can you draw for its acidity (pKa) in comparison to phenol?| b) Draw all resonance forms of 3-hydroxybenzaldehyde and of the corresponding conjugate base. Which conclusions can you draw for its acidity (pKa) in comparison to phenol and 3-hydroxybenzaldehyde? c) Discuss the relative acidities of 2-hydroxybenzaldehyd und 4-hydroxybenzaldehyd.arrow_forwardDraw the resonance contributor for the following compound: CH3-C=O-NH2arrow_forwardDraw resonance contributors for each of the following species and rank them in order of decreasing contribution to the resonance hybrid. Then draw the resonance hybrid.arrow_forward
- Identify the sequence of curved arrows (electron movement) in the steps of the following reaction. :Br: • loss of leaving group, proton transfer • loss of leaving group, nucleophilic attack • loss of leaving group, rearrangement proton transfer, nucleophilic attackarrow_forwardIdentify A through O:arrow_forwardSelect the LEAST basic and MOST basic compounds belowarrow_forward
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