Study Guide For The Physical Universe
16th Edition
ISBN: 9781259683466
Author: Konrad B Krauskopf, Arthur Beiser
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 13, Problem 3E
What is the principal bonding mechanism in organic molecules?
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In this problem you will model the mixing energy of a mixture in a relatively simple way, in order to relate the existence of a solubility gap to molecular behavior. Consider a mixture of A and B molecules that is ideal in every way but one: The potential energy due to the interaction of neighboring molecules depends upon whether the molecules are like or unlike. Let n be the average number of nearest neighbors of any given molecule (perhaps 6 or 8 or 10). Let Uo be the average potential energy associated with the interaction between neighboring molecules that are the same (A-A or B-B), and let UAB be the potential energy associated with the interaction of a neighboring unlike pair (A-B). There are no interactions beyond the range of the nearest neighbors; the values of Uo and UAB are independent of the amounts of A and B; and the entropy of mixing is the same as for an ideal solution.
Show that when the system is unmixed, the total potential energy due to all neighbor-neighbor…
Chapter 13 Solutions
Study Guide For The Physical Universe
Ch. 13 - Prob. 1MCCh. 13 - Prob. 2MCCh. 13 - Prob. 3MCCh. 13 - Prob. 4MCCh. 13 - As a class, the alkanes are a. highly reactive b....Ch. 13 - Prob. 6MCCh. 13 - Gasoline is a mixture of a. alkanes b. isomers of...Ch. 13 - Prob. 8MCCh. 13 - Unsaturated hydrocarbon molecules are...Ch. 13 - Prob. 10MC
Ch. 13 - Prob. 11MCCh. 13 - Prob. 12MCCh. 13 - Prob. 13MCCh. 13 - Prob. 14MCCh. 13 - Prob. 15MCCh. 13 - Prob. 16MCCh. 13 - Prob. 17MCCh. 13 - Prob. 18MCCh. 13 - Prob. 19MCCh. 13 - Prob. 20MCCh. 13 - Prob. 21MCCh. 13 - Prob. 22MCCh. 13 - Living cells consist mainly of a. carbohydrates b....Ch. 13 - Prob. 24MCCh. 13 - Prob. 25MCCh. 13 - Photosynthesis produces a. carbohydrates b....Ch. 13 - Prob. 27MCCh. 13 - Prob. 28MCCh. 13 - Prob. 29MCCh. 13 - Prob. 30MCCh. 13 - Prob. 31MCCh. 13 - Lipids are synthesized in plants and animals from...Ch. 13 - Prob. 33MCCh. 13 - Prob. 34MCCh. 13 - Proteins consist of combinations of a. amino acids...Ch. 13 - The number of amino acids important to life is a....Ch. 13 - Prob. 37MCCh. 13 - Prob. 38MCCh. 13 - Prob. 39MCCh. 13 - Prob. 40MCCh. 13 - Each three-nucleotide group in a DNA molecule...Ch. 13 - DNA is involved in which one or more of the...Ch. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - What is the principal bonding mechanism in organic...Ch. 13 - How can the different alkanes in petroleum be...Ch. 13 - Prob. 5ECh. 13 - Why are structural formulas more important in...Ch. 13 - The isomers of a compound have the same chemical...Ch. 13 - Distinguish between unsaturated and saturated...Ch. 13 - How many electrons are shared in a double bond...Ch. 13 - What kind of carbon-carbon bonds are found in...Ch. 13 - How many covalent bonds are present between the...Ch. 13 - In general, how do the reactivities of hydrocarbon...Ch. 13 - Prob. 13ECh. 13 - The alkanes of Sec. 13.2 are saturated...Ch. 13 - The structural formula of propane is given in Sec....Ch. 13 - Why does this structural formula not represent an...Ch. 13 - Why does this structural formula not represent an...Ch. 13 - Prob. 18ECh. 13 - Is it possible for a molecule with the formula...Ch. 13 - Is it possible for a molecule with the formula...Ch. 13 - Is it possible for a molecule with the formula...Ch. 13 - Each molecule of butyne, C4H6, has a triple bond...Ch. 13 - Each molecule of butene, C4H8, has a double bond...Ch. 13 - Prob. 24ECh. 13 - What is the difference between aromatic and...Ch. 13 - Why are all aromatic compounds unsaturated?Ch. 13 - The carbon atoms in normal hexane, C6H14, form a...Ch. 13 - Prob. 28ECh. 13 - When sugar undergoes fermentation to produce...Ch. 13 - To what class of organic compounds does the...Ch. 13 - To what class of organic compounds does the...Ch. 13 - What have the compounds in each of these pairs in...Ch. 13 - What have the compounds in each of these pairs in...Ch. 13 - Which of the following (a) dissolve in water, (b)...Ch. 13 - Compare the properties of a simple ester, for...Ch. 13 - Why do you think the compound whose structure is...Ch. 13 - Prob. 37ECh. 13 - Use structural formulas to show the reaction...Ch. 13 - Give structural formulas for the two isomeric...Ch. 13 - Prob. 40ECh. 13 - The structural formula of acetone is shown in...Ch. 13 - Use structural formulas to show the reaction...Ch. 13 - (a) Give structural formulas for the three isomers...Ch. 13 - Prob. 44ECh. 13 - How does a plant obtain its carbohydrates and...Ch. 13 - What are the products of the oxidation of glucose?...Ch. 13 - What is believed to be the origin of atmospheric...Ch. 13 - The ultimate source of the energy in food is the...Ch. 13 - Why are unsaturated fats liquid at room...Ch. 13 - Why do plants need nitrogen? Why can they not use...Ch. 13 - What are the basic structural units of proteins?...Ch. 13 - How many letters are there in the genetic code by...Ch. 13 - What change in a gene is involved in a mutation?...Ch. 13 - To which class of organic compounds do most of the...
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- In this problem you will model the mixing energy of a mixture in a relatively simple way, in order to relate the existence of a solubility gap to molecular behavior. Consider a mixture of A and B molecules that is ideal in every way but one: The potential energy due to the interaction of neighboring molecules depends upon whether the molecules are like or unlike. Let n be the average number of nearest neighbors of any given molecule (perhaps 6 or 8 or 10). Let Uo be the average potential energy associated with the interaction between neighboring molecules that are the same (A-A or B-B), and let UAB be the potential energy associated with the interaction of a neighboring unlike pair (A-B). There are no interactions beyond the range of the nearest neighbors; the values of Uo and UAB are independent of the amounts of A and B; and the entropy of mixing is the same as for an ideal solution. Find a formula for the total potential energy when the system is mixed, in terms of x, the fraction…arrow_forwardWhy do molecular compounds have low melting and boiling points compared to ionic compounds?arrow_forwardDiamond does not conduct electricity, because A) It's structure is very compact B) It is of crystalline nature C) There are only carbon atoms present in it D) No free electrons are present in itarrow_forward
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