GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY
GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY
4th Edition
ISBN: 9781260908435
Author: SMITH
Publisher: MCG
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Chapter 13, Problem 56P
Interpretation Introduction

(a)

Interpretation:

The resulting alcohol should be identified after reacting following alkene with H2O and H2SO4 :

  GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY, Chapter 13, Problem 56P , additional homework tip  1

Concept Introduction:

Alkenes are hydrocarbon molecules that consist of a carbon-carbon double bond which has the general formula of CnH2n .Alcohols are the hydrocarbon molecules that contain OH group in the molecule.

Reaction of an alkene with H2O and H2SO4 will form saturated alcohols and the reaction is called a hydration reaction.

The hydration reaction of alkenes follows the Markovnikov's rule.

Expert Solution
Check Mark

Answer to Problem 56P

  GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY, Chapter 13, Problem 56P , additional homework tip  2

Explanation of Solution

Unsaturated ( C4H8 )alkene molecules react with H2O and H2SO4 form alcohol. One-bond between a hydrogen atom and an oxygen atom in the H2O , is broken and also a one-bond between two carbon-carbon bonds is broken, meanwhile, new two bonds of COH and CH are formed.Hydrogenation occurs only in the presence of a strong acid such as H2SO4 . Refer to the below reaction;

  GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY, Chapter 13, Problem 56P , additional homework tip  3

Interpretation Introduction

(b)

Interpretation:

The resulting alcohol should be identified after reacting following alkene with H2O and H2SO4 :

  GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY, Chapter 13, Problem 56P , additional homework tip  4

Concept Introduction:

Alkenes are hydrocarbon molecules that consist of a carbon-carbon double bond which has the general formula of CnH2n . Alcohols are the hydrocarbon molecules that contain OH group in the molecule.

Reaction of an alkene with H2O and H2SO4 will form saturated alcohols and the reaction is calledhydration reaction.

Hydration reaction of alkenes follows the Markovnikov's rule.

Expert Solution
Check Mark

Answer to Problem 56P

  (CH3)2CHCOH(CH3)2

Explanation of Solution

Unsaturated ( C4H8 ) alkene molecules react with H2O and H2SO4 , form alcohols. One-bond between a hydrogen atom and an oxygen atom in the H2O is broken and also a one-bond between two carbon-carbon bond is broken, meanwhile, new two bonds of COH and CH are formed. Hydrogenation occurs only in the presence of a strong acid such as H2SO4 . Refer to the below reaction:

  (CH3)2C=C(CH3)2H2SO4/H2O(CH3)2CHCOH(CH3)2

Interpretation Introduction

(c)

Interpretation:

The resulting alcohol should be identified after reacting following alkene with H2O and H2SO4 :

  GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY, Chapter 13, Problem 56P , additional homework tip  5

Concept Introduction:

Alkenes are hydrocarbon molecules that consist of a carbon-carbon double bond which has the general formula of CnH2n . Alcohols are the hydrocarbon molecules that contain OH group in the molecule.

Reaction of an alkene with H2O and H2SO4 will form saturated alcohols and the reaction is called a hydration reaction.

Hydration reaction of alkenes follows the Markovnikov's rule.

Expert Solution
Check Mark

Answer to Problem 56P

  CH3CHOHCH2CH(CH3)2

Explanation of Solution

Unsaturated ( C4H8 ) alkene molecules react with H2O and H2SO4 , form alcohols. One-bond between a hydrogen atom and an oxygen atom in the H2O , is broken and also a one-bond between two carbon-carbon bonds is broken, meanwhile, new two bonds of COH and CH are formed. Hydrogenation occurs only in the presence of a strong acid such as H2SO4 . Hydration reaction of alkenes follows the Markovnikov's rule. When the addition of H2O a molecule to an unsymmetrical alkene, H atom binds to the less substituted carbon atom is known as Markovnikov's rule. This molecule also falls into the unsymmetrical alkene category, hence; Markovnikov's rule is applied to this molecule.

Refer to the below reaction:

  CH2=CHCH2CH(CH3)2H2SO4/H2OCH3CHOHCH2CH(CH3)2

Interpretation Introduction

(d)

Interpretation:

The resulting alcohol should be identified after reacting following alkene with H2O and H2SO4 :

  GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY, Chapter 13, Problem 56P , additional homework tip  6

Concept Introduction:

Alkenes are hydrocarbon molecules that consist of a carbon-carbon double bond which has the general formula of CnH2n . Alcohols are the hydrocarbon molecules that contain OH group in the molecule.

Reaction of an alkene with H2O and H2SO4 will form saturated alcohols and the reaction is called a hydration reaction.

Hydration reaction of alkenes follows the Markovnikov's rule.

Expert Solution
Check Mark

Answer to Problem 56P

  GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY, Chapter 13, Problem 56P , additional homework tip  7

Explanation of Solution

Unsaturated ( C4H8 ) alkene molecules react with H2O and H2SO4 , form alcohols. One-bond between a hydrogen atom and an oxygen atom in the H2O , is broken and also a one-bond between two carbon-carbon bonds is broken, meanwhile, new two bonds of COH and CH are formed. Hydrogenation occurs only in the presence of a strong acid such as H2SO4 . Hydration reaction of alkenes follows the Markovnikov's rule. When the addition of H2O molecule to an unsymmetrical alkene, H atom binds to the less substituted carbon atom is known as Markovnikov's rule. This molecule also falls into the unsymmetrical alkene category. Therefore,Markovnikov's rule is applied to this molecule.

Refer to the below reaction:

  GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY, Chapter 13, Problem 56P , additional homework tip  8

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Chapter 13 Solutions

GENERAL, ORGANIC & BIOLOGICAL CHEMISTRY

Ch. 13.3 - Prob. 13.5PCh. 13.3 - Prob. 13.6PCh. 13.3 - Prob. 13.7PCh. 13.3 - Prob. 13.8PCh. 13.6 - Prob. 13.7PPCh. 13.6 - Prob. 13.9PCh. 13.6 - What products is formed in each of the following...Ch. 13.6 - Prob. 13.9PPCh. 13.6 - What product is formed when l-pentene (CH3CH2CH2CH...Ch. 13.7 - Prob. 13.11PCh. 13.8 - Prob. 13.10PPCh. 13.8 - Prob. 13.12PCh. 13.8 - Prob. 13.13PCh. 13.10 - Prob. 13.11PPCh. 13.10 - Prob. 13.14PCh. 13.11 - Prob. 13.15PCh. 13.12 - Prob. 13.16PCh. 13.13 - Prob. 13.17PCh. 13.13 - Prob. 13.18PCh. 13 - Anethole, the major constituent of anise oil, is...Ch. 13 - Prob. 20PCh. 13 - What is the molecular formula for a hydrocarbon...Ch. 13 - Prob. 22PCh. 13 - Prob. 23PCh. 13 - Prob. 24PCh. 13 - Prob. 25PCh. 13 - Prob. 26PCh. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each compound. a....Ch. 13 - Give the IUPAC name for each compound. d....Ch. 13 - Give the IUPAC name for each alkene.Ch. 13 - Give the I UP AC name for each alkene.Ch. 13 - Give the IUPAC name for each cyclic compound.Ch. 13 - Give the IUPAC name for each cyclic compound.Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 36PCh. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Label the carbon-carbon double bond as cis or...Ch. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Prob. 47PCh. 13 - Prob. 48PCh. 13 - Prob. 49PCh. 13 - Prob. 50PCh. 13 - Prob. 51PCh. 13 - Prob. 52PCh. 13 - Prob. 53PCh. 13 - Prob. 54PCh. 13 - What alkyd halide is formed when each alkene is...Ch. 13 - Prob. 56PCh. 13 - Prob. 57PCh. 13 - Prob. 58PCh. 13 - What alkene is needed as a starting material to...Ch. 13 - Prob. 60PCh. 13 - Prob. 61PCh. 13 - Prob. 62PCh. 13 - Prob. 63PCh. 13 - Prob. 64PCh. 13 - Prob. 65PCh. 13 - Prob. 66PCh. 13 - Prob. 67PCh. 13 - Prob. 68PCh. 13 - Prob. 69PCh. 13 - Prob. 70PCh. 13 - Prob. 71PCh. 13 - Prob. 72PCh. 13 - Prob. 73PCh. 13 - Are o-bromochlorobenzene and m-bromochlorobenzene...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 77PCh. 13 - Prob. 78PCh. 13 - Prob. 79PCh. 13 - Prob. 80PCh. 13 - Prob. 81PCh. 13 - Prob. 82PCh. 13 - Prob. 83PCh. 13 - Prob. 84PCh. 13 - Prob. 85PCh. 13 - Eleostearic acid is an unsaturated fatty acid...Ch. 13 - Prob. 87PCh. 13 - Prob. 88PCh. 13 - Prob. 89PCh. 13 - Prob. 90PCh. 13 - Prob. 91PCh. 13 - Prob. 92PCh. 13 - Prob. 93PCh. 13 - Prob. 94PCh. 13 - Answer the following questions about compound A,...Ch. 13 - Prob. 96PCh. 13 - Answer the following questions about alkene C,...Ch. 13 - Prob. 98PCh. 13 - Prob. 99PCh. 13 - Prob. 100PCh. 13 - Prob. 101CPCh. 13 - Prob. 102CP
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