Concept explainers
(a)
Interpretation:
The concentration of Na+ in blood should be calculated.
Concept introduction:
The density can be calculated from mass and volume as follows:
From mass and molar mass, number of moles can be calculated as follows:
Also,
Here, n is number of moles, c is concentration and v is volume.
Thus,
(b)
Interpretation:
The concentration of ions in blood should be calculated.
Concept introduction:
The
Also,
(c)
Interpretation:
The osmotic pressure at 37 °C, should be calculated.
Concept introduction:
The number of moles is related to concentration and volume as follows:
The osmotic pressure is calculated as follows:
Or,
(d)
Interpretation:
The approximate freezing point of blood should be calculated.
Concept introduction:
The depression in freezing point can be calculated as follows:
Here,
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EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
- The freezing point of a 0.11 m solution of HNO2 is -0.20C. (a) What is i for the solution? (b) Is the solution made (i) of HNO2 molecules only? (ii) of H+ and NO2- only? (iii) of more HNO2 molecules than H+ ions? (iv) primarily of H+ and NO2- ions with some HNO2 molecules?arrow_forwardSolutions Introduced directly into the bloodstream have to be isotonic with blood; that is, they must have the same osmotic pressure as blood. An aqueous NaCl solution has to be 0.90% by mass to be isotonic with blood. What is the molarity of the sodium ions in solution? Take the density of the solution to be 1.00 g/mL.arrow_forwardThe freezing point of 0.10 M KHSO3 is -0.38C. Which of the following equations best represents what happens when KHSO3 dissolves in water? (a) KHSO3(s)KHSO3(aq) (b) KHSO3(s) K+(aq)+HSO3(aq) (c) KHSO3(s) K+(aq)+SO32(aq)+ H+(aq)arrow_forward
- A patient has a “cholesterol count” of 214. Like manyblood-chemistry measurements,this result is measured inunits of milligrams per deciliter (mgdL1). Determine the molar concentration of cholesterol inthis patient’s blood, taking the molar mass of cholesterolto be 386.64gmol1. Estimate the molality of cholesterol in the patient’sblood. If 214 is a typical cholesterol reading among men inthe United States, determine the volume of such bloodrequired to furnish 8.10 g of cholesterol.arrow_forwardThe Henry's law constant for the solubility of helium gas in water is 3.8104M/atm at 25C. (a) Express the constant for the solubility of helium gas in M/mm Hg. (b) If the partial pressure of He at 25C is 293 mm Hg, what is the concentration of dissolved He in mol/L at 25C? (c) What volume of helium gas can be dissolved in 10.00 L of water at 293 mm Hg and 25C? (Ignore the partial pressure of water.)arrow_forwardAqueous solutions introduced into the stream y injection must have the same osmotic pressure as blood; that is, they must be isotonic with blood. At 25C, the average osmotic pressure of blood is 7.7 atm. What is the molarity of an isotonic saline solution (NaCl in H2O)? Recall that NaCl is an electrolyte; assume complete conversion to Na+ and Cl- ions.arrow_forward
- A solution is made by dissolving 0.455 g of PbBr2 in 100 g of H2O at 50C. Based on the data in Table 8-1, should this solution be characterized as a. saturated or unsaturated b. dilute or concentratedarrow_forwardA 1.40-g sample of polyethylene, a common plastic, is dissolved in enough organic solvent to give 100.0 mL of solution. What is the average molar mass of the polymer if the measured osmotic pressure of the solution is 1.86 mm Hg at 25 C?arrow_forwardThe freezing point of a 0.21 m aqueous solution of H2SO4 is -0.796C. (a) What is i? (b) Is the solution made up primarily of (i) H2SO4 molecules only? (ii) H+ and HSO4- ions? (iii) 2H+ and 1SO42- ions?arrow_forward
- The osmotic pressure of a solution containing 7.0 g of insulin per liter is 23 torr at 25 C. What is the molar mass of insulin?arrow_forwardThe freezing point of a 0.031-m solution of copper(II) sulfate in water is 0.075 C. (a) Calculate the vant Hoff factor, i, for this solution. (b) Would the vant Hoff factor be larger, smaller, or the same for a 0.050-m solution of this compound?arrow_forward6-68 If we add 175 g of ethylene glycol, C2H6O2, per 1000. g of water to a car radiator, what will be the freezing point of the solution?arrow_forward
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