Concept explainers
(a)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo
Primary alcohol:
Secondary alcohol:
(a)
Answer to Problem 14.67EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a ketone. This has to be formed from a secondary alcohol only on oxidation. The structure of the secondary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
(b)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and this id further oxidized to give carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Primary alcohol:
Secondary alcohol:
(b)
Answer to Problem 14.67EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a carboxylic acid. This has to be formed from aldehyde by oxidation. The aldehyde must have formed from primary alcohol by oxidation. The structure of the primary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
(c)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and this id further oxidized to give carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Primary alcohol:
Secondary alcohol:
(c)
Answer to Problem 14.67EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a aldehyde. The aldehyde must have formed from primary alcohol by oxidation. The structure of the primary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
(d)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and this id further oxidized to give carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Primary alcohol:
Secondary alcohol:
(d)
Answer to Problem 14.67EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a aldehyde. The aldehyde must have formed from primary alcohol by oxidation. The structure of the primary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
Want to see more full solutions like this?
Chapter 14 Solutions
General, Organic, And Biological Chemistry
- Write the structural formula for the product of the reaction.arrow_forwardFor this Retro-Claisen reaction, find the product.arrow_forwardWrite the reaction, occurring in the liver, that causes theoxidation of ethanol. What is the product of this reactionand what symptoms are caused by the product?arrow_forward
- Draw the alcohol used to produce each of the following ketones. Include all hydrogen atoms.arrow_forwardDraw the major organic product for each of the following reactions. You must show the correct stereochemistry of the product where relevant.arrow_forwardWhen you made soap, first you dissolved vegetable oil in ehanol. What happened to the ethanol during the reaction?arrow_forward
- discuss the following statement: “Whether the ΔG for a reaction is larger, smaller, or the same as ΔG° depends on the concentration of the compounds that participate in the reaction.”arrow_forwardWhy is it unlikely that nonenzymatic catalysts operate by preferentially binding the transition state?arrow_forwardExplain why NOT ALL hydrolysis of esters produces a sour smell.arrow_forward
- Human Anatomy & Physiology (11th Edition)BiologyISBN:9780134580999Author:Elaine N. Marieb, Katja N. HoehnPublisher:PEARSONBiology 2eBiologyISBN:9781947172517Author:Matthew Douglas, Jung Choi, Mary Ann ClarkPublisher:OpenStaxAnatomy & PhysiologyBiologyISBN:9781259398629Author:McKinley, Michael P., O'loughlin, Valerie Dean, Bidle, Theresa StouterPublisher:Mcgraw Hill Education,
- Molecular Biology of the Cell (Sixth Edition)BiologyISBN:9780815344322Author:Bruce Alberts, Alexander D. Johnson, Julian Lewis, David Morgan, Martin Raff, Keith Roberts, Peter WalterPublisher:W. W. Norton & CompanyLaboratory Manual For Human Anatomy & PhysiologyBiologyISBN:9781260159363Author:Martin, Terry R., Prentice-craver, CynthiaPublisher:McGraw-Hill Publishing Co.Inquiry Into Life (16th Edition)BiologyISBN:9781260231700Author:Sylvia S. Mader, Michael WindelspechtPublisher:McGraw Hill Education