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Chapter 14, Problem 92QP
Interpretation Introduction
Interpretation:
The nature of PCC reagent in the preparation of ethanal from the ethanol is to be determined.
Concept Introduction
The preparation of
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In the table below, you are given three reactions. Complete the table by identifying the substance in each reaction that is being oxidized, the substance being reduced, the oxidizing agent, and the reducing agent
EQUATIONS
1. The formation of molecular bromine (Br2) from HBr and KBrO3 must be derived using redox
reactions.
a. Write the balanced (ionic) redox equation for the conversion of BrO3 into Br2
under acidic conditions. Label the half reaction as either oxidation or reduction.
b. Write the balanced (ionic) redox equation for the conversion of Br¯ into Br2 under
acidic conditions. Label the half reaction as either oxidation or reduction.
c. Write the balanced net (ionic) redox reaction (reduced to the lowest whole
number coefficients)
d. Rewrite the balanced net redox equation in complete (molecular) form using
KBrO3, HBr and CH3COOH as the reactants. (note that this step may require a bit
of manipulation as there are two sources of Ht: HBr and CH3COOH)
2. Write the equation for the reaction of acetanilide with molecular bromine (for the organic
compounds, draw the full structures, not condensed formulae).
3. Write the balanced equation for this experiment by adding these two equations.…
An unknown substance, X, was isolated from rabbit muscle. Its structure was determined from the following observations and experiments. Qualitative analysis showed that X was composed entirely of C, H, andO. A weighed sample of X was completely oxidized, and the H2O and CO2 produced were measured; this quantitative analysis revealed that X contained 40.00% C, 6.71% H, and 53.29% O by weight. The molecular mass of X, determined by mass spectrometry, was 90.00 u (atomic mass units; see Box 1-1). Infrared spectroscopy showed that X containedone double bond. X dissolved readily in water to give an acidic solution; the solution demonstrated optical activity when tested in a polarimeter.(a) Determine the empirical and molecular formula of X.(b) Draw the possible structures of X that fit the molecular formula and contain one double bond. Consider only linear or branched structures and disregard cyclic structures.Note that oxygen makes very poor bonds to itself.(c) What is the structural…
Chapter 14 Solutions
ACCESS CODE W/E TEXT CONNECT
Ch. 14 - Prob. 1QCCh. 14 - Prob. 2QCCh. 14 - How do chemical reactions provide electricity in...Ch. 14 - Prob. 4QCCh. 14 - Prob. 5QCCh. 14 - How do oxidation-reduction reactions generate...Ch. 14 - Prob. 7QCCh. 14 - Prob. 1PPCh. 14 - Assign oxidation numbers to each element in the...Ch. 14 - Prob. 3PP
Ch. 14 - Cadmium reacts with nickel(II) nitrate according...Ch. 14 - The reaction that occurs in most camera batteries...Ch. 14 - Prob. 6PPCh. 14 - Balance the following equation that occurs in...Ch. 14 - Prob. 8PPCh. 14 - Prob. 9PPCh. 14 - Prob. 1QPCh. 14 - Prob. 2QPCh. 14 - Prob. 3QPCh. 14 - Why is oxidation always coupled with reduction?Ch. 14 - Prob. 5QPCh. 14 - How do you know when something is reduced?Ch. 14 - When a strip of magnesium metal is placed in an...Ch. 14 - When a strip of nickel metal is placed in an...Ch. 14 - Consider the following reaction:...Ch. 14 - Consider the following reaction:...Ch. 14 - Prob. 11QPCh. 14 - Prob. 12QPCh. 14 - Indicate the oxidation number of each element in...Ch. 14 - Indicate the oxidation number of each element in...Ch. 14 - Prob. 15QPCh. 14 - Prob. 16QPCh. 14 - What is the oxidation number of phosphorus in each...Ch. 14 - Determine the oxidation number of chlorine in each...Ch. 14 - Indicate the oxidation number of phosphorus in...Ch. 14 - Determine the oxidation number of iodine in each...Ch. 14 - The ion shown has a charge of 2. What are the...Ch. 14 - The ion shown has a charge of 1. What are the...Ch. 14 - Prob. 23QPCh. 14 - Indicate the oxidation number of chromium in each...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Prob. 28QPCh. 14 - Prob. 29QPCh. 14 - Prob. 30QPCh. 14 - Under certain conditions, nitrogen gas reacts with...Ch. 14 - Under certain conditions, solid carbon reacts with...Ch. 14 - Consider the following reaction:...Ch. 14 - In the following oxidation-reduction reactions,...Ch. 14 - In the following oxidation-reduction reactions,...Ch. 14 - Draw a diagram of a voltaic cell that corresponds...Ch. 14 - Draw a diagram of a voltaic cell that corresponds...Ch. 14 - The figure shows a molecular-level representation...Ch. 14 - The figure shows a molecular-level representation...Ch. 14 - The reaction that occurs in a lead-acid battery is...Ch. 14 - The reaction that occurs in a lead-acid battery is...Ch. 14 - The nickel-cadmium battery is used in portable...Ch. 14 - The zinc-silver oxide battery, although expensive,...Ch. 14 - Balance the following half-reactions....Ch. 14 - Balance the following half-reactions....Ch. 14 - For each of the following, write balanced...Ch. 14 - For each of the following, write balanced...Ch. 14 - Prob. 49QPCh. 14 - Prob. 50QPCh. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Prob. 55QPCh. 14 - Complete and balance the following...Ch. 14 - Complete and balance the following...Ch. 14 - Complete and balance the following...Ch. 14 - Denitrification occurs when nitrogen in the soil...Ch. 14 - Prob. 60QPCh. 14 - Consider the partially labelled voltaic cell...Ch. 14 - Consider the partially labelled voltaic cell...Ch. 14 - Using the activity series in Figure 14.22, place...Ch. 14 - Using the activity series in Figure 14.22, place...Ch. 14 - What is electrolysis?Ch. 14 - Describe what happens at each electrode during the...Ch. 14 - Prob. 67QPCh. 14 - Prob. 68QPCh. 14 - Prob. 69QPCh. 14 - Prob. 70QPCh. 14 - Prob. 71QPCh. 14 - Prob. 72QPCh. 14 - Prob. 73QPCh. 14 - Prob. 74QPCh. 14 - If the chrome placing on an automobile bumper is...Ch. 14 - Prob. 76QPCh. 14 - Prob. 77QPCh. 14 - Prob. 78QPCh. 14 - Prob. 79QPCh. 14 - Prob. 80QPCh. 14 - Prob. 81QPCh. 14 - Prob. 82QPCh. 14 - Prob. 83QPCh. 14 - Prob. 84QPCh. 14 - Prob. 85QPCh. 14 - Prob. 86QPCh. 14 - Prob. 87QPCh. 14 - Prob. 88QPCh. 14 - Prob. 89QPCh. 14 - Prob. 90QPCh. 14 - Prob. 91QPCh. 14 - Prob. 92QPCh. 14 - Prob. 93QPCh. 14 - Prob. 94QPCh. 14 - Prob. 95QPCh. 14 - Prob. 96QPCh. 14 - Prob. 97QPCh. 14 - Prob. 98QPCh. 14 - Prob. 99QPCh. 14 - Prob. 100QPCh. 14 - Prob. 101QPCh. 14 - Prob. 102QPCh. 14 - Prob. 103QPCh. 14 - Prob. 104QPCh. 14 - Prob. 105QPCh. 14 - Prob. 106QPCh. 14 - Prob. 107QPCh. 14 - Prob. 108QPCh. 14 - Prob. 109QPCh. 14 - Prob. 110QP
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