The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols. Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified. Concept introduction: In a condensation reaction, two molecules join together to form a large molecule with the removal of small molecule such as water.

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Answer 1

Question

Chapter 14.7, Problem 14.13P

(a)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In a condensation reaction, two molecules join together to form a large molecule with the removal of small molecule such as water.

(b)

Interpretation Introduction

To determine: The formation of the given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson reaction.

(c)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

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Starting with cyclohexanone, show how to prepare these compounds. In addition to the given starting material, use any other organic or inorganic reagents as necessary. a. Cyclohexanol b. Cyclohexene c. cis-1,2-Cyclohexanediol d. 1-Methylcyclohexanol e. 1-Methylcyclohexene f. 1-Phenylcyclohexanol g. 1-Phenylcyclohexene h. Cyclohexene oxide i. trans-1,2-Cyclohexanediol

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Answer 2

Question

Chapter 14.7, Problem 14.13P

(a)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In a condensation reaction, two molecules join together to form a large molecule with the removal of small molecule such as water.

(b)

Interpretation Introduction

To determine: The formation of the given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson reaction.

(c)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

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Answer 3

Question

Chapter 14.7, Problem 14.13P

(a)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In a condensation reaction, two molecules join together to form a large molecule with the removal of small molecule such as water.

(b)

Interpretation Introduction

To determine: The formation of the given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson reaction.

(c)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

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Answer 4

Question

Chapter 14.7, Problem 14.13P

(a)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In a condensation reaction, two molecules join together to form a large molecule with the removal of small molecule such as water.

(b)

Interpretation Introduction

To determine: The formation of the given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson reaction.

(c)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

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Answer 5

Chapter 14.7, Problem 14.13P

(a)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In a condensation reaction, two molecules join together to form a large molecule with the removal of small molecule such as water.

(b)

Interpretation Introduction

To determine: The formation of the given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson reaction.

(c)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

Answer 6

Chapter 14.7, Problem 14.13P

(a)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In a condensation reaction, two molecules join together to form a large molecule with the removal of small molecule such as water.

Answer 7

Chapter 14.7, Problem 14.13P

(a)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In a condensation reaction, two molecules join together to form a large molecule with the removal of small molecule such as water.

Answer 8

(b)

Interpretation Introduction

To determine: The formation of the given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson reaction.

Answer 9

(b)

Interpretation Introduction

To determine: The formation of the given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson reaction.

Answer 10

(c)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

Answer 11

(c)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14.2C - Rank the given solvents in decreasing order of...Ch. 14.2D - Prob. 14.2P Ch. 14.2D - In the presence of 18-crown-6, potassium...Ch. 14.3B - Give a common name (when possible) and a...Ch. 14.3C - Prob. 14.5P Ch. 14.3C - Name the following heterocyclic ethers.Ch. 14.4 - Propose a fragmentation to account for each...Ch. 14.5 - Prob. 14.8P Ch. 14.5 - Prob. 14.9P Ch. 14.6 - Prob. 14.10P

Solution Summary: The author explains the formation of diethyl ether in good yield by condensation of the corresponding alcohol and the alternative method.

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Chapter 14 Solutions