Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Suggest a physical interpretation of the dependence of the Gibbs energy on the pressure.
Briefly distinguish between spontaneity criteria of simple and non simple systems im terms of Gibbs and Helmholtz free energies
Without doing a calculation, decide whether the presence of (a) attractive, (b) repulsive interactions between gas molecules will raise or lower the molar Gibbs energy of a gas relative to its 'perfect' value.
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- The fugacity coefficient of a certain gas at 290 K and 2.1 MPa is 0.68. Calculate the difference of its molar Gibbs energy from that of a perfect gas in the same state.arrow_forwardHow does the Gibbs energy of a pure material change with increasing the temperature at constant pressure? Provide the appropriate equations as well!arrow_forwardWith a typical example, explain the concept of residual entropyarrow_forward
- The change in the Gibbs energy of a certain constant-pressure process is found to fit the expression ΔG/J = −85.40 + 36.5(T/K). Use the Gibbs–Helmholtz equation to calculate the value of ΔH for the process.arrow_forwardDerive a formula for the molar Gibbs free energy change of a closed system at constant temperature if the system obeys the equation of state PV = nRT + nCP where C is a constant.arrow_forward
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