Chapter 15, Problem 15.2P

(a)

Interpretation Introduction

Interpretation:

Whether the catalytic reaction is limited by the external diffusion or not is to be stated.

Concept introduction:

The rate law of the chemical reaction states that the rate of reaction is the function of the concentration of the reactants and the products present in that specific reaction. The rate is actually predicted by the slowest step of the reaction.

If there is a chemical reaction which has reactants A and B that reacts to form products then their rate law is given as follows.

    $r=k{\left[A\right]}^a{\left[B\right]}^b$

Here, $\left[A\right]$ is the concentration of the reactant A, $\left[B\right]$ is the concentration of the reactant B and $k$ is the rate constant.

(b)

Interpretation Introduction

Interpretation:

The conditions due to which the catalytic reaction is limited by the external diffusion are to be stated.

Concept introduction:

The rate law of the chemical reaction states that the rate of reaction is the function of the concentration of the reactants and the products present in that specific reaction. The rate is actually predicted by the slowest step of the reaction.

If there is a chemical reaction which has reactants A and B that reacts to form products then their rate law is given as follows.

    $r=k{\left[A\right]}^a{\left[B\right]}^b$

Here, $\left[A\right]$ is the concentration of the reactant A, $\left[B\right]$ is the concentration of the reactant B and $k$ is the rate constant.

(c)

Interpretation Introduction

Interpretation:

Whether the reaction rate is limited or not is to be stated.

Concept introduction:

The rate law of the chemical reaction states that the rate of reaction is the function of the concentration of the reactants and the products present in that specific reaction. The rate is actually predicted by the slowest step of the reaction.

If there is a chemical reaction which has reactants A and B that reacts to form products then their rate law is given as follows.

    $r=k{\left[A\right]}^a{\left[B\right]}^b$

Here, $\left[A\right]$ is the concentration of the reactant A, $\left[B\right]$ is the concentration of the reactant B and $k$ is the rate constant.

(d)

Interpretation Introduction

Interpretation:

The conditions due to which the rate of the catalytic reaction is limited by the external diffusion are to be stated.

Concept introduction:

The rate law of the chemical reaction states that the rate of reaction is the function of the concentration of the reactants and the products present in that specific reaction. The rate is actually predicted by the slowest step of the reaction.

If there is a chemical reaction which has reactants A and B that reacts to form products then their rate law is given as follows.

    $r=k{\left[A\right]}^a{\left[B\right]}^b$

Here, $\left[A\right]$ is the concentration of the reactant A, $\left[B\right]$ is the concentration of the reactant B and $k$ is the rate constant.

(e)

Interpretation Introduction

Interpretation:

Whether the reaction is limited by internal diffusion is to be stated.

Concept introduction:

The rate law of the chemical reaction states that the rate of reaction is the function of the concentration of the reactants and the products present in that specific reaction. The rate is actually predicted by the slowest step of the reaction.

If there is a chemical reaction which has reactants A and B that reacts to form products then their rate law is given as follows.

    $r=k{\left[A\right]}^a{\left[B\right]}^b$

Here, $\left[A\right]$ is the concentration of the reactant A, $\left[B\right]$ is the concentration of the reactant B and $k$ is the rate constant.

(f)

Interpretation Introduction

Interpretation:

The conditions due to which the reaction is limited by internal diffusion are to be stated.

Concept introduction:

The rate law of the chemical reaction states that the rate of reaction is the function of the concentration of the reactants and the products present in that specific reaction. The rate is actually predicted by the slowest step of the reaction.

If there is a chemical reaction which has reactants A and B that reacts to form products then their rate law is given as follows.

    $r=k{\left[A\right]}^a{\left[B\right]}^b$

Here, $\left[A\right]$ is the concentration of the reactant A, $\left[B\right]$ is the concentration of the reactant B and $k$ is the rate constant.

(g)

Interpretation Introduction

Interpretation:

The overall effectiveness factor for a flow rate of $10\text{g}\cdot \text{mol/h}$ at $\text{360}\text{K}$ is to be stated.

Concept introduction:

The rate law of the chemical reaction states that the rate of reaction is the function of the concentration of the reactants and the products present in that specific reaction. The rate is actually predicted by the slowest step of the reaction.

If there is a chemical reaction which has reactants A and B that reacts to form products then their rate law is given as follows.

    $r=k{\left[A\right]}^a{\left[B\right]}^b$

Here, $\left[A\right]$ is the concentration of the reactant A, $\left[B\right]$ is the concentration of the reactant B and $k$ is the rate constant.

(h)

Interpretation Introduction

Interpretation:

The internal effectiveness factor at $\text{367}\text{K}$ is to be stated.

Concept introduction:

The rate law of the chemical reaction states that the rate of reaction is the function of the concentration of the reactants and the products present in that specific reaction. The rate is actually predicted by the slowest step of the reaction.

If there is a chemical reaction which has reactants A and B that reacts to form products then their rate law is given as follows.

    $r=k{\left[A\right]}^a{\left[B\right]}^b$

Here, $\left[A\right]$ is the concentration of the reactant A, $\left[B\right]$ is the concentration of the reactant B and $k$ is the rate constant.

(i)

Interpretation Introduction

Interpretation:

The concentration at the rate $r=R/2$ inside the porous catalyst at $\text{367}\text{K}$ if the concentration at the external catalyst surface is $0.01{\text{mol/dm}}^{\text{3}}$ is to be stated.

Concept introduction:

The rate law of the chemical reaction states that the rate of reaction is the function of the concentration of the reactants and the products present in that specific reaction. The rate is actually predicted by the slowest step of the reaction.

If there is a chemical reaction which has reactants A and B that reacts to form products then their rate law is given as follows.

    $r=k{\left[A\right]}^a{\left[B\right]}^b$

Here, $\left[A\right]$ is the concentration of the reactant A, $\left[B\right]$ is the concentration of the reactant B and $k$ is the rate constant.