Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Question
Chapter 15, Problem 3P
Interpretation Introduction
Interpretation:
The difference between the structure of an aliphatic
Concept Introduction:
The derivative of ammonia which is formed by replacement of one or more hydrogen atoms by any r group or organic groups is said to amine.
The general structure of amine (primary, secondary and tertiary) is given by:
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Below is the structure of Clemastine and its functional groups. Which of
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Ether
Tertiary amines
CH
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Halogenated aromatic
hydrocarbon
Aromatic
hydrocarbon
Aliphatic hydrocarbons
Clemastine (Tavist)
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Halogenated aromatic hydrocarbon is lipophilic.
Tertiary amine is hydrophobic.
Ether is hydrophilic.
Acid Anhydride
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17-50
Draw the structure of the amine salt produced when
each of the following amines reacts with HCl.
a. CH3-CH,-CH2-NH2
b. CH3-NH-CH3
CH3
c. CH,-CH-CH;-NH, d.[NH-CH;-Ch
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Chapter 15 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 15.1 - Prob. 15.1QCCh. 15.2 - Problem 16-2 Write a structural formula for each...Ch. 15.2 - Prob. 15.3QCCh. 15.3 - Problem 16-4 Select the stronger base from each...Ch. 15.3 - Prob. 15.5QCCh. 15 - 16-6 Answer true or false. te/7-Butylamine is a 3°...Ch. 15 - Prob. 2PCh. 15 - Prob. 3PCh. 15 - 16-9 In what way are pyridine and pyrimidine...Ch. 15 - Prob. 5P
Ch. 15 - Prob. 6PCh. 15 - Prob. 7PCh. 15 - 16-13 Classify each amino group as primary,...Ch. 15 - Prob. 9PCh. 15 - 16-15 There are eight primary amines with the...Ch. 15 - Prob. 11PCh. 15 - 16-17 Propylamine (bp 48°C), ethylmethylamine (bp...Ch. 15 - 16-18 Account for the fact that 1-butanamine (bp...Ch. 15 - 16-19 2-Me thy 1 propane (bp -12°C), 2-propanol...Ch. 15 - Prob. 15PCh. 15 - Prob. 16PCh. 15 - Prob. 17PCh. 15 - Prob. 18PCh. 15 - Prob. 19PCh. 15 - Prob. 20PCh. 15 - 16-26 The p/fb of amphetamine is approximately 3.2...Ch. 15 - 16-27 Guanidine, p/Ca 13.6, is a very strong base,...Ch. 15 - 16-28 Following is the structural formula of...Ch. 15 - Prob. 24PCh. 15 - Prob. 25PCh. 15 - Prob. 26PCh. 15 - 16*32 Many tumors of the breast are correlated...Ch. 15 - Prob. 28PCh. 15 - Prob. 29PCh. 15 - Prob. 30PCh. 15 - (Chemical Connections 15B ) Identify all...Ch. 15 - Prob. 32PCh. 15 - Prob. 33PCh. 15 - Prob. 34PCh. 15 - Prob. 35PCh. 15 - Prob. 36PCh. 15 - (Chemical Connections 15D ) Suppose you saw this...Ch. 15 - Prob. 38PCh. 15 - Prob. 39PCh. 15 - Prob. 40PCh. 15 - 16-46 Arrange these three compounds in order of...Ch. 15 - Prob. 42PCh. 15 - Prob. 43PCh. 15 - Prob. 44PCh. 15 - Prob. 45PCh. 15 - Prob. 46PCh. 15 - Prob. 47PCh. 15 - Prob. 48PCh. 15 - 16-54 Several poisonous plants, including Atropa...Ch. 15 - Prob. 50PCh. 15 - Prob. 51PCh. 15 - Prob. 52PCh. 15 - 16-58 Following is a structural formula of...Ch. 15 - Prob. 54P
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- 16-13 Classify each amino group as primary, secondary, or tertiary and as aliphatic or aromatic. Serotonin (a neurotransmitter) Diphenhydramine (the hydrochloride salt is the antihistamine Benadryl) Lysine (an amino acid)arrow_forward17-11 What is the difference in structure between an aromatic aldehyde and an aliphatic aldehyde?arrow_forward16-15 There are eight primary amines with the molecular formula C5H13N. (a) Name and draw a structural formula for each amine. (b > Which of these amines are chiral?arrow_forward
- 18-23 Characterize the structural features necessary to make a good synthetic detergent.arrow_forward16-35 (Chemical Connections 16B ) What is an alkaloid? Are all alkaloids basic to litmus?arrow_forward18-19 The following compounds have approximately the same molecular weight: hexanoic acid, heptanal, and 1-heptanol. Arrange them in order of increasing boiling point.arrow_forward
- 18-17 Hexanoic (caproic) acid has a solubility in water of about 1 g/100 mL water. Which part of the molecule contributes to water solubility,'and which part prevents solubility?arrow_forwardComplete this table for different amine compounds. Chemical propylamine quaternary ammonium ion methylphenylamine Molecular formula C3H9N C₂H7N C5H13N C4H10N Structural formula (CH3)3N (CH3)2NH CH 3 I (CH₂) 11 | H3C(CH2) 11 -N-(CH₂)11CH3 NHCH3 (CH₂)11 CH3 CH3CH2CH2-NH-CH3 + Classification Tertiary Quaternary Tertiary Secondaryarrow_forwardAmines with more than 6 carbons are soluble in: a) aqueous HCI b) aqueous NaHCO3 d) water c) aqueous NaOH Which of the following would give a positive iodoform test? acetone a) benzophenone c) 3-pentanone d) cyclopentanone meth "Saponification" as the term is used in organic chemistry means: a) acidic hydrolysis of an ester b) basic hydrolysis of an ester c) acidic hydrolysis of an amide d) basic hydrolysis of an amide 3. ( Propylamine can be synthesized by the LiAlH4 reduction of: a) CH3CH2CECH b) CH3CH=NH d)) CH3CH2CEN c) CH3CH2NO2arrow_forward
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