Concept explainers
Use the activity series in Table 15.3 to predict whether each of the following reactions will occur spontaneously:
a.
b.
c.
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Basic Chemistry
- How is the pH scale defined? What range of pH values corresponds to acidic solutions? What range corresponds to basic solutions? Why is pH = 7.00 considered neutral? When the pH of a solution changes by one unit, by what factor does the hydrogen ion concentration change in the solution? How is pOH defined? How arc pH and pOH for a given solution related? Explain.arrow_forwardSome calculators cannot display results of an antilog calculation if the power of 10 is greater than 99. This shortcoming can come into play for determining equilibrium constants of redox reactions, which are sometimes quite large. Solve the following expressions for K: (a) logK=45.63 , (b) logK=25.00 , (c) logK=20.63 . is the relationship among the three expressions and the three answers? How can you use this relationship to solve problems that exceed 1099 even if your calculator will not carry out the calculation directly?arrow_forwardFor the reaction Cu2+(aq) + Zn(s) → Cu(s) + Zn2+ (aq), why can’t you generate electric current by placing a piece of copper metal and a piece of zinc metal in a solution containing CuCl2(aq) and ZnCl2(aq)?arrow_forward
- Some metals, such as iron, can be oxidized to more than one oxidation state. Obtain the balanced net ionic equations for the following oxidation reduction reactions, in which nitric acid is reduced to nitric oxide, NO. a Oxidation of iron metal to iron(II) ion by nitric acid. b Oxidation of iron(II) ion to iron(III) ion by nitric acid. c Oxidation of iron metal to iron(III) by nitric acid. [Consider adding the a and b equations.]arrow_forwardAssign an oxidation number to the underlined atom in each ion or molecule. (a) Fe2O3, (b) H2SO4, (C) CO32- (C) NO2+arrow_forwardSolubility and Solubility Product You put 0.10-mol samples of KNO3, (NH4)2S, K2S, MnS, AgCl, and BaSO4 into separate flasks and add 1.0 L of water to each one. Then you stir the solutions for 5 minutes at room temperature. Assume that you have 1.0 L of solution in each case. a Are there any beakers where you would observe solid still present? How do you know? b Can you calculate the potassium ion concentration, K+, for the solutions of KNO3 and K2S? If so, do the calculations, and then compare these K+ concentrations. c For the solutions of (NH4)2S, K2S, and MnS, how do the concentrations of sulfide ion, S2, compare? (You dont need to calculate an answer at this point; just provide a rough comparison.) Be sure to justify your answer. d Are there any cases where you need more information to calculate the sulfide-ion concentration for the solutions of (NH4)2S, K2S, and MnS from part c? If so, what additional information do you need? e Consider all of the solutions listed at the beginning of this problem. For which ones do you need more information than is given in the question to determine the concentrations of the ions present? Where can you find this information? f How is the solubility of an ionic compound related to the concentrations of the ions of the dissolved compound in solution?arrow_forward
- Calculate the value of E for each of the following reactions. Decide whether each is product-favored at equilibrium in the direction written. [Reaction (d) is carried out in basic solution.] (a) Br2() + Mg(s) Mg2+(aq) + 2 Br(aq) (b) Zn2+(aq) + Mg(s) Zn(s) + Mg2+(aq) (c) Sn2+(aq) + 2 Ag+(aq) Sn4+(aq) + 2Ag(s) (d) 2 Zn(s) + O2(g) + 2 H2O() + 4 OH(aq) 2[Zn(OH)4]2(aq)arrow_forwardConsider the following galvanic cell: Calculate the concentrations of Ag+(aq) and Ni2+(aq) once the cell is dead.arrow_forward12.19 For each of the following equations, write the equilibrium expression for the reverse reaction. 2C(s) + O,(g)^2CO(g) AgCl(s)5=BAg+(aq) + Crarrow_forward
- Some metals, such as thallium, can be oxidized to more than one oxidation state. Obtain the balanced net ionic equations for the following oxidation reduction reactions, in which nitric acid is reduced to nitric oxide, NO. a Oxidation of thallium metal to thallium(I) ion by nitric acid. b Oxidation of thallium(I) ion to thallium(III) ion by nitric acid. c Oxidation of thallium metal to thallium(III) by nitric acid. [Consider adding the a and b equations.]arrow_forwardWhich of the following ions is most easily reduced? (a) Cu2+(aq) (b) Zn2+(aq) (c) Fe2+(aq) (d) Ag+(aq) (e) Al3+(aq)arrow_forward
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