ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
4th Edition
ISBN: 9781119659587
Author: Klein
Publisher: WILEY
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Chapter 15.4, Problem 4ATS
Interpretation Introduction
Interpretation: The chemical equivalent of hydrogen is to be identified.
Concept introduction: The number of signals in a 1 H NMR spectrum reveals the variety of protons present (protons in different electronic environments). Chemically similar protons will only emit one signal since they inhabit the same electronic surroundings. If a symmetry operation—either rotation or reflection—allows for the swap of two protons, then they are chemically identical.
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What is the major organic product of the following reaction?
H,0/ heat
HO2C.
.co.CH
.co.H
HO,C
HO
HOC
(A)
(В)
(C)
(D)
1.4
4 (a) Calculate the value of Kc for the reaction:
PC13 (g) +
Cl₂ (8)
PC15 (8)
Given that when 8.4 mol of PC15 (g)
AH = Positive
Kc =
is mixed with 1.8 mol of PC13 (g) and
allowed to come to equilibrium in a 10 dm³ container the amount of
PC1, at equilibrium is 7.2 mol.
¹5 (g)
(b) Explain the effect of the following changes below on the value of
Kc:
(i) Increasing temperature
(ii) Lowering the concentration of chlorine (C1₂)
(iii) Addition of a catalyst
A.
How CO2
be converted
value-added products mediated by ionic
liquids such as CO2 hydrogenation, HCOOH, CH4 and other hydrocarbons, HCOOCH3 and
can
to
carbonates etc.
B. What are biocompatible ionic liquids and their application in pharmaceutics?
Chapter 15 Solutions
ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
Ch. 15.4 - Prob. 1LTSCh. 15.4 - Prob. 1PTSCh. 15.4 - Prob. 2PTSCh. 15.4 - Prob. 3PTSCh. 15.4 - Prob. 4ATSCh. 15.4 - Prob. 2LTSCh. 15.5 - Prob. 3LTSCh. 15.6 - Prob. 4LTSCh. 15.6 - Prob. 11PTSCh. 15.6 - Prob. 12PTS
Ch. 15.6 - Prob. 13PTSCh. 15.7 - Prob. 5LTSCh. 15.7 - Prob. 15PTSCh. 15.8 - Prob. 6LTSCh. 15.8 - Prob. 19PTSCh. 15.10 - Prob. 8LTSCh. 15.10 - Prob. 23PTSCh. 15.10 - Prob. 24PTSCh. 15 - Prob. 32PPCh. 15 - Prob. 33PPCh. 15 - Prob. 34PPCh. 15 - Prob. 35PPCh. 15 - Prob. 36PPCh. 15 - Prob. 37PPCh. 15 - Prob. 38PPCh. 15 - Prob. 39PPCh. 15 - Prob. 40PPCh. 15 - Prob. 41PPCh. 15 - Prob. 42PPCh. 15 - Prob. 43PPCh. 15 - Prob. 44PPCh. 15 - Prob. 45PPCh. 15 - Prob. 51PPCh. 15 - Prob. 52PPCh. 15 - Prob. 53PPCh. 15 - Prob. 54PPCh. 15 - Prob. 55PPCh. 15 - Prob. 56PPCh. 15 - Prob. 57PPCh. 15 - Prob. 72IPCh. 15 - Prob. 73IPCh. 15 - Prob. 74IPCh. 15 - Prob. 75IPCh. 15 - Prob. 76IPCh. 15 - Prob. 77IPCh. 15 - Prob. 78IPCh. 15 - Prob. 79IPCh. 15 - Prob. 80IPCh. 15 - Prob. 81IP
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