Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+)
8th Edition
ISBN: 9780135213759
Author: John McMurry, David Ballantine
Publisher: PEARSON+
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Textbook Question
Chapter 15.7, Problem 15.16P
Draw the structure of each acetal or ketal final product formed in the reactions shown in Problem 15.15 if an excess of alcohol was used.
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For the following monosaccharide, draw the products formed when treated with each reagent.
H
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-OH
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Modify the Fischer projection of the monosaccharide to represent the product.
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-ОН
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Benedict's reagent.
Modify the Fischer projection of the monosaccharide to represent the product.
H
H
-OH
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HO
H
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☐
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G
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For the following monosaccharide, draw the products formed when treated with each reagent.
H.
HO
H
H
OH
HO
H
H
OH
Part 1 of 2
CH₂OH
H₂ in the presence of a Pd catalyst.
Modify the Fischer projection of the monosaccharide to represent the product.
H
HO
-H
H
-OH
HO
-H
H
-OH
CH₂OH
Part 2 of 2
Benedict's reagent.
Modify the Fischer projection of the monosaccharide to represent the product.
HO
H
H
-OH
HO
H
H
-OH
CH₂OH
Q:
Following are Fischer projections for a groupof five-carbon sugars, all of which are aldopentoses. Identify thepairs that are enantiomers and the pairs that are epimers. (Thesugars shown here are not all of the possible five-carbon sugars.)
Chapter 15 Solutions
Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+)
Ch. 15.1 - Prob. 15.1PCh. 15.1 - Prob. 15.2PCh. 15.2 - Draw structures corresponding to the following...Ch. 15.2 - Prob. 15.1CIAPCh. 15.2 - Prob. 15.2CIAPCh. 15.2 - Prob. 15.4PCh. 15.2 - Draw the line structures and provide common names...Ch. 15.2 - Prob. 15.6KCPCh. 15.3 - For each compound shown next (ad), indicate...Ch. 15.3 - Prob. 15.8KCP
Ch. 15.4 - Prob. 15.9KCPCh. 15.5 - Indicate whether the following compounds will give...Ch. 15.6 - Draw line structures of the following compounds...Ch. 15.6 - Prob. 15.12PCh. 15.7 - Prob. 15.13PCh. 15.7 - Prob. 15.14PCh. 15.7 - Prob. 15.15PCh. 15.7 - Draw the structure of each acetal or ketal final...Ch. 15.7 - Prob. 15.17PCh. 15.7 - Prob. 15.18PCh. 15.7 - Prob. 15.19PCh. 15.7 - Prob. 15.1MRPCh. 15.7 - Prob. 15.2MRPCh. 15.7 - Prob. 15.3MRPCh. 15.7 - Prob. 15.3CIAPCh. 15.7 - (a) What are mirotubules? (b) Why would drugs that...Ch. 15.7 - Tetrodotoxin, found in the puffer fish, has been...Ch. 15 - Prob. 15.20UKCCh. 15 - Prob. 15.21UKCCh. 15 - Prob. 15.22UKCCh. 15 - Prob. 15.23UKCCh. 15 - Prob. 15.24UKCCh. 15 - Prob. 15.25UKCCh. 15 - ALDEHYDESAND KETONES (SECTIONS 15.1 AND 15.2)...Ch. 15 - Draw a structure for a compound that meets each of...Ch. 15 - Prob. 15.28APCh. 15 - Prob. 15.29APCh. 15 - Draw structures corresponding to the following...Ch. 15 - Draw structures corresponding to the following...Ch. 15 - Prob. 15.32APCh. 15 - Prob. 15.33APCh. 15 - The following names are incorrect. What is wrong...Ch. 15 - Prob. 15.35APCh. 15 - Prob. 15.36APCh. 15 - Prob. 15.37APCh. 15 - Prob. 15.38APCh. 15 - Prob. 15.39APCh. 15 - Prob. 15.40APCh. 15 - Draw the structures of the aldehydes that might be...Ch. 15 - Write the structures of the hemiacetal or...Ch. 15 - Write the structures of the hemiacetal or...Ch. 15 - Prob. 15.44APCh. 15 - Prob. 15.45APCh. 15 - Prob. 15.46APCh. 15 - Prob. 15.47APCh. 15 - Prob. 15.48APCh. 15 - Prob. 15.49APCh. 15 - Prob. 15.50CPCh. 15 - Prob. 15.51CPCh. 15 - Prob. 15.52CPCh. 15 - Prob. 15.53CPCh. 15 - Prob. 15.54CPCh. 15 - Name the following compounds: (a) (b) (c) (be sure...Ch. 15 - Draw the structural formulas of the following...Ch. 15 - Prob. 15.57CPCh. 15 - Complete the following equations (refer to Summary...Ch. 15 - Prob. 15.59CPCh. 15 - How could you differentiate between 3-hexanol and...Ch. 15 - The liquids 1-butanol and butanal have similar...Ch. 15 - Prob. 15.62CPCh. 15 - Prob. 15.63GPCh. 15 - Prob. 15.64GPCh. 15 - Using the ketone structural form of fructose...Ch. 15 - Prob. 15.66GP
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- Following are Fischer projections for a group of five-carbon sugars, all of which are aldopentoses. Identify the pairs that are enantiomers and the pairs that are epimers. (The sugars shown here are not all of the possible five-carbon sugars.) 1 СНО 2 СНО СНО Н-С—ОН Н-С—ОН Н—С—ОН Н-С—ОН НО —С—Н Н-С—ОН Н- С—ОН НО—С— Н НО—С—Н CH̟OH CH̟OH ČH̟OH в iоchemistry |61 STATE ATION Republic of the Philippines Romblon State University Romblan, Philippines 4 СНО 5 СНО 6 СНО НО—С—Н Н-С—ОН НО -С—Н Н—С—ОН НО -С—Н НО -С—Н H-C–OH Н-С—ОН НО—С—Н CH,OH ČH,OH CH,OHarrow_forwardIn solution, glucose exists predominantly in the cyclic hemiacetal form, which does not contain an aldehyde group. How is it possible for mild oxidizing agents to oxidize glucose?arrow_forwardModify the Fischer projection of the following aldose to show the compound that is formed when the aldose is treated with H2 in the presence of a Pd catalyst. CHO H -OH HO H H .OH CH₂OH X :ロ Garrow_forward
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