EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 16.10, Problem 23CC

(a)

Interpretation Introduction

Interpretation: The type of sigmatropic rearrangement in each reaction should be described by using brackets and two numbers.

Concept Introduction : The pericyclic reaction that involves the changing of the location of the σ bond, is known as sigmatropic rearrangement. It is written by two numbers in the brackets that depict the number of atoms separating the bond (already formed bond) and the bond breaking in the transition state.

(b)

Interpretation Introduction

Interpretation: The type of sigmatropic rearrangement in each reaction should be described by using brackets and two numbers.

Concept Introduction : The pericyclic reaction that involves the changing of the location of the σ bond, is known as sigmatropic rearrangement. It is written by two numbers in the brackets that depict the number of atoms separating the bond (already formed bond) and the bond breaking in the transition state.

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