CHEMISTRY: W/MASTERING CHEMISTRY
13th Edition
ISBN: 9781323479551
Author: Pearson
Publisher: PEARSON C
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Textbook Question
Chapter 16.6, Problem 16.10.2PE
Practice Exercise 2
Niacin, one of the B vitamins, has the molecular structure shown at the right. A 0.020 M solution of niacin has a pH of 3.26. What is the acid dissociation constant for niacin?
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Learning Check Determine the pH of a 0.1M solution of the salt NaF basic due to F- Kb=Kw/Ka UNIVERSITY x² / 0.1 = 2.87e-11 I C F- 0.1M -X + H₂O → OH- + HF (aq) aq. E (0.1-x)≈ 0.1 N/A -X • N/A pOH=? 0 +x X 16.3. Salt solutions are not neutral if the ions are weak acids or bases pH=? 0 +x
What is the pH of a 0.420 M solution of C₅H₅NHBr (Kb of C₅H₅N is 1.7 × 10⁻⁹)?
(Answer is not 11.16)
Baseline Question: Calculate the pH of a 5.6x10-9M HCl aqueous solution. ANS: pH=6.99
Commentary: Since I know HCl is a strong acid and ionization is 100%, I thought I could find pH as -log(5.6x10-9), however my teacher said that was incorrect . She did a Kw=[OH-][H3O+] to find x. Use image below to see my work. The answer to the question is pH= 6.99.
Actual Question:I want to know why we had to do an ICE table and find "x" (another H3O concentration) instead of -log(5.6x10-9).
Chapter 16 Solutions
CHEMISTRY: W/MASTERING CHEMISTRY
Ch. 16.2 - Practice Exercise 1 Consider the following...Ch. 16.2 - Prob. 16.1.2PECh. 16.2 - Prob. 16.2.1PECh. 16.2 - Practice Exercise 2 When lithium oxide (Li2O) is...Ch. 16.2 - Based on information in Figure 16.4, place the...Ch. 16.2 - Practice Exercise 2 For each reaction, use Figure...Ch. 16.3 - Practice Exercise 1 In a certain acidic solution...Ch. 16.3 - Practice Exercise 2 Indicate whether solutions...Ch. 16.3 - Prob. 16.5.1PECh. 16.3 - Prob. 16.5.2PE
Ch. 16.4 - Practice Exercise 1 A solution at 250C has [OH-] =...Ch. 16.4 - Practice Exercise 2 In a sample of lemon juice,...Ch. 16.4 - Practice Exercise 1 A solution at 25° C has pOH =...Ch. 16.4 - Prob. 16.7.2PECh. 16.5 - Practice Exercise 1 Order the following three...Ch. 16.5 - Prob. 16.8.2PECh. 16.5 - Practice Exercise 1 Order the following three...Ch. 16.5 - Prob. 16.9.2PECh. 16.6 - Prob. 16.10.1PECh. 16.6 - Practice Exercise 2 Niacin, one of the B vitamins,...Ch. 16.6 - Prob. 16.11.1PECh. 16.6 - Practice Exercise 2 A 0.020 M solution of niacin...Ch. 16.6 - Practice Exercise 1 What is the pH of a 0.40 M...Ch. 16.6 - Practice Exercise 2 The Ka for niacin (Sample...Ch. 16.6 - Prob. 16.13.1PECh. 16.6 - Prob. 16.13.2PECh. 16.6 - Practice Exercise 1 What is the pH of a 0.28 M...Ch. 16.6 - Practice Exercise 2 Calculate the pH of a 0.020 M...Ch. 16.7 - Prob. 16.15.1PECh. 16.7 - Practice Exercise 2 Which of the following...Ch. 16.7 - Prob. 16.16.1PECh. 16.7 - Practice Exercise 2 What is the morality of an...Ch. 16.8 - Practice Exercise 1 By using information from...Ch. 16.8 - Practice Exercise 2 Based on information in...Ch. 16.9 - Prob. 16.18.1PECh. 16.9 - Prob. 16.18.2PECh. 16.9 - Practice Exercise 1 How many of the following...Ch. 16.9 - Practice Exercise 2 Predict whether the...Ch. 16.10 - Prob. 16.20.1PECh. 16.10 - In each pair, choose the compound that gives the...Ch. 16 - Prob. 1DECh. 16 - a. Identify the Br ted-Lowry acid and base in the...Ch. 16 - Prob. 2ECh. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - 16.5 The following diagrams represent aqueous...Ch. 16 - Prob. 6ECh. 16 - Which of these statements about how the percent...Ch. 16 - 16.8 Each of the three molecules shown here...Ch. 16 - Prob. 9ECh. 16 - Which of the following diagrams best represent an...Ch. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - 16.14 Which of the following statements is...Ch. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Identify the Bronsted-Lowry acid and the...Ch. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - 16.29 Calcualte [H +] for each of the following...Ch. 16 - Prob. 30ECh. 16 - 16.31 At the freezing point of water (0 o C), K10...Ch. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - 16.35 Complete the following table by calculating...Ch. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - 16.38 Carbon dioxide in the atmosphere dissolves...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - write the chemical equation and the Ka expression...Ch. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - Calculate the pH of each of the following solution...Ch. 16 - Prob. 60ECh. 16 - Prob. 61ECh. 16 - Prob. 62ECh. 16 - Calculate the percent ionization of hydrazoic acid...Ch. 16 - 16.64 Calculate the percent ionization of...Ch. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - 16.68 The hypochlorite ion, CIO- , acts as a weak...Ch. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - Calculate the molar concentration of OH- in a...Ch. 16 - 16.72 Calculate the molar concentration of OH- in...Ch. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - a. Given that Ka for acetic acid is 1.8 10-5 and...Ch. 16 - 16.78
a. Given that Kb for ammonia is 1.8 X 10 -5...Ch. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Pyridinium bromide (C5H5NHBr) is a strong...Ch. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - 16.86 An unknown salt is either KBr, NH4 C1, KCN,...Ch. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - 16.89 Based on their compositions and structures...Ch. 16 - Prob. 90ECh. 16 - 16.91 Indicate whether each of the following...Ch. 16 - Prob. 92ECh. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - Prob. 97ECh. 16 - Prob. 98ECh. 16 - Prob. 99AECh. 16 - Prob. 100AECh. 16 - Prob. 101AECh. 16 - Prob. 102AECh. 16 - Prob. 103AECh. 16 - Prob. 104AECh. 16 - Benzoic acid (C6H5COOH) and aniline (C6H5NH2) are...Ch. 16 - Prob. 106AECh. 16 - Prob. 107AECh. 16 - Prob. 108AECh. 16 - Butyric acid is responsible for the foul smell of...Ch. 16 - Prob. 110AECh. 16 - Prob. 111AECh. 16 - Prob. 112AECh. 16 - 1S.113 Many moderately large organic molecules...Ch. 16 - Prob. 114AECh. 16 - Prob. 115AECh. 16 - Prob. 116IECh. 16 - Prob. 117IECh. 16 - Prob. 118IECh. 16 - Prob. 119IECh. 16 - 16.120 At 50 oC, the ion-product constant for H2...Ch. 16 - Prob. 121IECh. 16 - Prob. 122IECh. 16 - Prob. 123IECh. 16 - Prob. 124IECh. 16 - Prob. 125IECh. 16 - Prob. 126IE
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- You have prepared dilute solutions of equal molar concentrations of HC2H3O2 (acetic arid), HNO2, HF, and HCN. Rank the solutions from the highest pH to the lowest pH. (Refer to Table 16.1.)arrow_forwardExercise 16.2 Calculate [H+] in a solution in which [OH]=2.0102M. Is this solution acidic, neutral, or basic?arrow_forwardExercise 16.1 Which of the following represent conjugate acid—base pairs? a. H2O, H2O+ b. OH-, HNO3 c. H2SO4, SO42-d. HC2H3O2, C2H3O2-arrow_forward
- Exercise 16.7 Calculate the pH of a solution of 5.0103M HC1.arrow_forwardA 0.010 M solution of ammonia, NH3, has a pH of 10.6 at 25C. What is the concentration of hydroxide ion? (One way to solve this problem is to find the pOH first and then calculate the hydroxide-ion concentration.)arrow_forwardWhat are the concentrations of hydrogen ion and acetate ion in a solution of 0.10 M acetic acid, HC2H3O2? What is the pH of the solution? What is the degree of ionization? See Table 16.1 for the value of Ka.arrow_forward
- Identify the Lewis acid and the Lewis base in each of the following reactions. Write the chemical equations using electron-dot formulas. a. b. O2 + CO2 CO32arrow_forwardBenzoic acid, HC7H5O2, and its salts are used as food preservatives. What is the concentration of benzoic acid in an aqueous solution of 0.015 M sodium benzoate? What is the pH of the solution? Ka for benzoic acid is 6.3 105.arrow_forwardpractice pH a.) determine the pH of a nitric acid solution (HNO3) that has been prepared by mixing 2.0 mL of 1.0 M HNO3 with 98.0 mL of water b.) determine the pH of a 25 mL carbonic acid solution (H2CO3) with concentration of 5.7 x 10-5 M. assume all protons will dissociate from the acid and react with water to form hydronium ions. c.) determine the pH and pOH of a NaOH solution that has been prepared by diluting 20.0 mL of 6.0 M NaOH with 80.0 mL of water. d.) determine the pH and pOH of a Ca(OH)2 solution that has been prepared by mixing 0.26 g of Ca(OH)2 pellets in 750 mL of water.arrow_forward
- Consider the following beakers. Each contains a solution of the hypothetical atom X. a Arrange the beakers in order of increasing concentration of X. b Without adding or removing X, what specific things could you do to make the concentrations of X equal in each beaker? (Hint: Think about dilutions.)arrow_forwardThe beaker on the left below represents a buffer solution of a weak acid HA and its conjugate base, A. (Water molecules and spectator ions have been omitted for clarity.) a Which beaker on the right, X or Y, depicts the solution after the addition of two formula units of NaOH? b How many HCl molecules can be added to the original buffer solution before the buffer capacity is exceeded? c Draw a picture of the solution where the buffer capacity has been exceeded by the addition of HCl.arrow_forwardThe ionization constant for water (Kw) is 5.9 × 10–14 at 50 °C. What is the [H3O+], [OH–], pH, and pOH for pure water at 50 °C? Question 30 options: a) [H3O+] = 2.4 x 10-7 M [OH–] = 2.4 x 10-7 M pH = 6.61 pOH = 6.61 b) [H3O+] = 6.5x 10-7 M [OH–] = 0.1 x 10-7 M pH = 5.01 pOH = 8.05 c) [H3O+] = 5.3 x 10-7 M [OH–] = 2.8 x 10-7 M pH = 1.82 pOH = 7.45 d) [H3O+] = 1.7 x 10-7 M [OH–] = 1.7 x 10-7 M pH = 6.77 pOH = 6.77arrow_forward
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