General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Chapter 17, Problem 8E
What concentration of ammonia.
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General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 17 - For a solution that e 0.275M CH2CH2 COOH...Ch. 17 - For a solution that is 0164 U NH2 and 0.102MNH4Cl...Ch. 17 - Prob. 3ECh. 17 - In Example 16-4, we calculated the percent...Ch. 17 - Calculate [H2OOH-] in a solution that is (a)...Ch. 17 - Calculate [OH-] in a solution that is (a) 0.0062 U...Ch. 17 - What concentration of formate ion, [HCOO-], should...Ch. 17 - What concentration of ammonia. [NH2] , should be...Ch. 17 - Calculate the pH of a buffer that is a. 0.012 M...Ch. 17 - Lactic acid, CH2CH(OH)COOH , is found in sour...
Ch. 17 - Indicate which of the following aqueous solutions...Ch. 17 - The H2PO4-HPO4- combination plays a role in...Ch. 17 - What is the pH of a solution Obtained by adding...Ch. 17 - What the pH of solution prepared by dissolving...Ch. 17 - You wish to prepare a buffer solution w pH = 945...Ch. 17 - You prepare a buffer solution by dissolving 2.00 g...Ch. 17 - If 0.55 ml. of 12 M HCI is added to 0100 L of the...Ch. 17 - If 0.35 mL of 15 P.4 NH is added to 0750 L of the...Ch. 17 - You are asked to prepare e buffer solution why a...Ch. 17 - You are asked to reduce the pH of the 03001 of...Ch. 17 - Given 1.00 L of a solution that is 0.100 hl...Ch. 17 - Given 125mL of a solution that is 0.0500 M CH2NH2...Ch. 17 - A solution of volume 750 mL contars 15.5 mmol...Ch. 17 - A solution of volume 0.500 L contains 1.68 g NH...Ch. 17 - A handbook lets various procedures for preparing...Ch. 17 - An acetic acid-sodium acetate buffer can be...Ch. 17 - A handbook lists the following data: Which of...Ch. 17 - With reference to the indicators listed in...Ch. 17 - In use of acid—base indicators, a. Why is it...Ch. 17 - The indicator methyl red has a pKHIN=4.95 . It...Ch. 17 - Phenol red indicator changes from yellow to red in...Ch. 17 - Thymol blue indicator has two pH ranges. It...Ch. 17 - In the titration of 10.00 mL of 0.04050 M HCI with...Ch. 17 - Solution (a) is 1000 mL of 0.100 N HCI and...Ch. 17 - A 25.00 mL sample of H2PO4(aq) requires 31.15 mL...Ch. 17 - A 2000 ml sample of H2PO4(aq) requires 18.67 mL...Ch. 17 - Two aqueous solutions are mixed 50.0 mL of 0.0150M...Ch. 17 - Two solutions are mixed 100.0 mL of HCI(aq) with...Ch. 17 - Calculate the pH at the points in the titration of...Ch. 17 - Calculate the pH at the points m the titration...Ch. 17 - Calculate the pH at the points in the titration of...Ch. 17 - Calculate the pH at the points lithe titration of...Ch. 17 - Explain why the volume of 0.100 M NeOH required to...Ch. 17 - Explain whether the equivalence point of each of...Ch. 17 - Sketch the titration curves of the following...Ch. 17 - Determine the blowing characteristeristics of the...Ch. 17 - In the titration of 2000 mL of 0175 M NaOH,...Ch. 17 - In the titration of 25.00mL of 0.100M CH2COOH ,...Ch. 17 - Sketch a titration curve (pH versus mL of titrant)...Ch. 17 - Sketch a titration curve (pH versus mL of titrant)...Ch. 17 - For me titration of 25.00 mL of 0.100M NaOH with...Ch. 17 - For the titration of 25.00 mL 0.100M NH2 with...Ch. 17 - Is a solution that is 0.10 M Na2S(aq) likely to be...Ch. 17 - Is a solution of sodium dihydrogen citrate,...Ch. 17 - Sodium phosphate Na2PO4 , is made commecie1y by...Ch. 17 - Both sodium hydrogen carbonate (sodium...Ch. 17 - The pH of a solution of 19.5 g of malonic acid in...Ch. 17 - The ionization constants of ortho-phthalic acid...Ch. 17 - What stoichimetric concentration of the indicated...Ch. 17 - What stocichiometric concentration of the...Ch. 17 - Using appropriate equilibrium constants but...Ch. 17 - Prob. 62ECh. 17 - Sodium hydrogen sulfate NaHSO4 , an acidic salt...Ch. 17 - You are given 250.0mL of 0.100M CH3 CH2 COOH...Ch. 17 - Even though the carbonic acid-hydrogen carbonate...Ch. 17 - Thymol blue in its acid range is not a suitable...Ch. 17 - Rather than calculate the pH for different volumes...Ch. 17 - Use the method of Exercise 67 to determine the...Ch. 17 - A buffer solution can be prepared by starting with...Ch. 17 - You are asked to prepare a KH2PO4-Na2HPO2 solution...Ch. 17 - You are asked to bring the pH of 0.500 L of 0.500...Ch. 17 - Because an acid-base indicator a weak acid, I can...Ch. 17 - The neutralization of NaOH 2by HCl is represented...Ch. 17 - The titration of a weak acid by a weak base a not...Ch. 17 - At times a salt of a we base can be titrated by a...Ch. 17 - Sulfuric acid is a diprotic acid, strong in the...Ch. 17 - Carbonic acid is a weak diprotic acid (H2CO2) with...Ch. 17 - Prob. 78IAECh. 17 - Complete the derivation of equation (17.10)...Ch. 17 - Explain why equation (17.10) fads when applied to...Ch. 17 - Prob. 81IAECh. 17 - Prob. 82IAECh. 17 - Prob. 83IAECh. 17 - Prob. 84IAECh. 17 - Prob. 85IAECh. 17 - Calculate the pH of a solution that is 0.050 U...Ch. 17 - Prob. 87IAECh. 17 - The Henderson-Hasselbalch equation can be written...Ch. 17 - The pH of ocean water depends on the amount of...Ch. 17 - A sample of water contains 23.0 g L1 of Na+ (aq),...Ch. 17 - Prob. 91IAECh. 17 - Prob. 92FPCh. 17 - In some cases the titration curve for a mature of...Ch. 17 - Amino acids contain both an acidic carboxylic acid...Ch. 17 - In your own words, define or explain the following...Ch. 17 - Prob. 96SAECh. 17 - Explain the important distinctions between each...Ch. 17 - Write equations to show how each of the following...Ch. 17 - Sketch the titration curves that you would expect...Ch. 17 - A 2500-mL sample of 0.0100M C8C5COOH (Kg=6.3103)...Ch. 17 - Prob. 101SAECh. 17 - Prob. 102SAECh. 17 - Prob. 103SAECh. 17 - Prob. 104SAECh. 17 - Prob. 105SAECh. 17 - Calculate the pH of a 0.5 M solution of Ca(HSe)2...Ch. 17 - Prob. 107SAECh. 17 - Prob. 108SAECh. 17 - Prob. 109SAECh. 17 - Prob. 110SAECh. 17 - Prob. 111SAE
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- What mass of NH4Cl must be added to 0.750 L of a 0.100-M solution of NH3 to give a buffer solution with a pH of 9.26? (Him: Assume a negligible change in volume as the solid is added.)arrow_forwardCalculate the pH of a solution that is 0.20 M HOCl and 0.90 M KOCl. In order for this buffer to have pH = pKa, would you add HCl or NaOH? What quantity (moles) of which reagent would you add to 1.0 L of the original buffer so that the resulting solution has pH = pKa?arrow_forwardWhat volume of 0.200 M HCl must be added to 500.0 mL of 0.250 M NH3 to have a buffer with a pH of 9.00?arrow_forward
- Ka for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid, HCHO2, and 494 mL of 0.524 M sodium formate, NaCHO2. Calculate the pH of this solution at 25C after 110 mL of 0.152 M HCl has been added to this buffer.arrow_forwardA 0.400-M solution of ammonia was titrated with hydrochloric acid to the equivalence point, where the total volume was 1.50 times the original volume. At what pH does the equivalence point occur?arrow_forwardSketch two pH curves, one for the titration of a weak acid with a strong base and one for a strong acid with a strong base. How are they similar? How are they different? Account for the similarities and the differences.arrow_forward
- How many grams of NaOH must be added to 1.00 L of a buffer made from 0.150 M NH3 and 10.0 g of NH4Cl so that the pH increases by one unit (e.g., from 5 to 6)? Ka for NH4+ is 5.61010.arrow_forwardA good buffer generally contains relatively equal concentrations of weak acid and conjugate base. If you wanted to buffer a solution at pH = 4.00 or pH = 10.00, how would you decide which weak acidconjugate base or weak baseconjugate acid pair to use? The second characteristic of a good buffer is good buffering capacity. What is the capacity of a buffer? How do the following buffers differ in capacity? How do they differ in pH? 0.01 M acetic acid/0.01 M sodium acetate 0.1 M acetic acid/0.1 M sodium acetate 1.0 M acetic acid/1.0 M sodium acetatearrow_forwardConsider die titration of 50.0 mL of 0.10 M H3A (Ka1 = 5.0 104, Ka2 = 1.0 108, Ka3 = 1.0 1012) titrated by 0.10 M KOH. a. Calculate the pH of the resulting solution at 125 mL of KOH added. b. At what volume of KOH added does pH = 3.30? c. At 75.0 mL of KOH added, is the solution acidic or basic?arrow_forward
- When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.arrow_forwardCalculate the pH change when 10.0 mL of 0.100-M NaOH is added to 90.0 mL pure water, and compare the pH change with that when the same amount of NaOH solution is added to 90.0 mL of a buffer consisting of 1.00-M NH3 and 1.00-M NH4Cl. Assume that the volumes are additive. Kb of NH3 = 1.8 × 10-5.arrow_forward2. If an acetic acid/sodium acetate buffer solution is prepared from 100. mL of 0.10 M acetic acid what volume of 0.10 M sodium acetate must be added to have a pH of 4.00? 100. mL 50. mL 36 mL 18 mLarrow_forward
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