The structure of the carbonyl compound and the amine used to form the given imine is to be predicted. Concept introduction: The reaction between ketone / aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

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Esters can be prepared by the reaction of carboxylic acids with alcohols. Bearing this in mind, propose a route to the preparation of γ-Butyrolactone, the structure of which is shown below.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Expert Solution & Answer

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See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 6

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 7

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 14

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 15

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 16

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 17

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 18.3 - Give the IUPAC name and (if possible) a common...Ch. 18.5D - NMR spectra for two compounds are given here,...Ch. 18.5D - Why were no products from the McLafferty...Ch. 18.5D - Use equations to show the fragmentation leading to...Ch. 18.5E - Prob. 18.5P Ch. 18.7D - Show how you would synthesize each compound from...Ch. 18.8 - Prob. 18.7P Ch. 18.9 - Predict the products of the following reactions....Ch. 18.9 - Show how the following transformations may be...Ch. 18.10 - Prob. 18.10P

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Chapter 18 Solutions