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Concept explainers
(a)
Interpretation: The IUPAC name for the given compound is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the
(b)
Interpretation: The IUPAC name for the given compound is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.
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Chapter 19 Solutions
ORGANIC CHEMISTRY
- Maleic acid and fumaric acid are the cis- and trans- isomers, respectively, of C2H2(COOH)2, a dicarboxylic acid. Draw and label their structures.arrow_forwardGive an IUPAC and common name for each of the following naturally occurring carboxylic acids: (a) CH3CH(OH)CO2H (lactic acid); (b) HOCH2CH2C(OH)(CH3)CH2CO2H (mevalonic acid).arrow_forwardDraw the organic product formed when the following com-pounds undergo a substitution reaction: (a) acetic acid and methylamine; (b) butanoic acid and 2-propanol; (c) formic acidand 2-methyl-1-propanol.arrow_forward
- Draw the organic product formed when the following compounds undergo a substitution reaction: (a) acetic acid and methyl-amine; (b) butanoic acid and 2-propanol; (c) Formica acid and 2-methyl-1-propanol.arrow_forwardWrite an equation to show the proton transfer between each alkene or cycloalkene and HCl. Where two carbocations are possible, show each. (a) CH,CH,CH=CHCH, (b) 2-Pentene Cyclohexenearrow_forwardIn each of the following reactions, two possible organic products can be formed. Draw both organic products in each case and then circle the one formed in greatest quantity in each case. HC (a) 1) NaH, 2) acid (b) CH,CH,OH (c) CH,CH,OH NH2 (d) Oarrow_forward
- 1. (a) Draw the structures of the eight isomeric pentyl alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol system. (c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and a tertiary alcohol of the formula C,H13OH.arrow_forwardDraw a structural formula for each alcohol. (a) 2-Methyl-2-propyl-1,3-propanediol (b) 1-Octanol (c) 3,3-Dimethylcyclohexanolarrow_forwardDraw the organic product formed when the following compounds undergo a substitution reaction:(a) acetic and 1-hexanol; (b) propanoic acid and dimethylamine; (c) ethanoic acid and dimethylamine.arrow_forward
- Give the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene Name the functional group: (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group:arrow_forward(a) Write the IUPAC names of the following compounds :(i) CH3CO(CH2)4CH3 (ii) Ph — CH = CH — CHO(b) Describe the following conversions in not more than two steps :(i) Ethanol to 3-Hydroxybutanal (ii) Benzoic acid to m-Nitrobenzyl alcohol(iii) Propanone to Propenearrow_forwardDraw the structure and name the product formed if the following alcohols are oxidized. Assume an excess of the oxidizing agent is used. If the alcohol is not expected to react with a chemical oxidizing agent, write NR (no reaction).(a) CH3CH2CH2CH2OH(b) 2-butanol(c) 2-methyl-2-propanol(d) 2-methyl-1-propanolarrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
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