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A cylinder with a piston contains a sample of a thin gas. The kind of gas and the
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- On a hot summer day, the density of air at atmospheric pressure at 35.0C is 1.1455 kg/m3. a. What is the number of moles contained in 1.00 m3 of an ideal gas at this temperature and pressure? b. Avogadros number of air molecules has a mass of 2.85 102 kg. What is the mass of 1.00 m3 of air? c. Does the value calculated in part (b) agree with the stated density of air at this temperature?arrow_forwardCylinder A contains oxygen (O2) gas, and cylinder B contains nitrogen (N2) gas. If the molecules in the two cylinders have the same rms speeds, which of the following statements is false? (a) The two gases haw different temperatures. (b) The temperature of cylinder B is less than the temperature of cylinder A. (c) The temperature of cylinder B is greater than the temperature of cylinder A. (d) The average kinetic energy of the nitrogen molecules is less than the average kinetic energy of the oxygen molecules.arrow_forwardOne process for decaffeinating coffee uses carbon dioxide ( M=44.0 g/mol) at a molar density of about 14,0 mol/m3 and a temperature of about 60 . (a) Is CO2 a solid, liquid, gas, or supercritical fluid under those conditions? (b) The van der Waals constants for carbon dioxide are a=0.3658 Pa m6/mol2 and b=4.286105 m3/mol. Using the van der Waals equation, estimate pressure of CO2 at that temperature and density. `arrow_forward
- A sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P21.65). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state, (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally, (f) Find Q, W, and Eint for each of the processes, (g) For the whole cycle A B C A, find Q, W, and Eint.arrow_forwardA gas is at 200 K. If we wish to double the rms speed of the molecules of the gas, to what value must we raise its temperature? (a) 283 K (b) 400 K (c) 566 K (d) 800 K (e) 1 130 Karrow_forwardOne cylinder contains helium gas and another contains krypton gas at the same temperature. Mark each of these statements true, false, or impossible to determine from the given information. (a) The rms speeds of atoms in the two gases are the same. (b) The average kinetic energies of atoms in the two gases are the same. (c) The internal energies of 1 mole of gas in each cylinder are the same. (d) The pressures in the two cylinders ale the same.arrow_forward
- Consider a gas filling two connected chambers that are separated by a removable barrier (Fig. P20.68). The gas molecules on the left (red) are initially at a higher temperature than the ones on the right (blue). When the barrier between the two chambers is removed, the molecules begin to mix and move from one chamber to the other. a. Describe what happens to the temperature in the left chamber and in the right chamber as time goes on, once the barrier is open. Discuss in terms of the mixing of the molecules from each gas. b. Describe what happens to the most probable speed and average speed in the left chamber and in the right chamber as time goes on, once the barrier is open. Do they increase or decrease by the same factor? Explain. FIGURE P20.68 Problems 68 and 69.arrow_forwardHow many moles are there in (a) 0.0500 g of N2 gas (M = 28.0 g/mol)? (b) 10.0 g of CO2 gas (M = 44.0 g/mol)? (c) How many molecules are present in each case?arrow_forwardA 0.500-m3 container holding 3.00 mol of ozone (O3) is kept at a temperature of 250 K. Assume the molecules have radius r = 2.50 1010 m. What are the a. mean free path and b. mean free time between collisions for an ozone molecule in the container?arrow_forward
- A sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P17.68). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state. (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally. (f) Find Q, W, and Eint for each of the processes. (g) For the whole cycle A B C A, find Q, W, and Eint. Figure P17.68arrow_forwardA 1.00-mol sample of hydrogen gas is heated at constant pressure from 300 K to 420 K. Calculate (a) the energy transferred to the gas by heat, (b) the increase in its internal energy, and (c) the work done on the gas.arrow_forwardAn aluminum rod 0.500 m in length and with a cross-sectional area of 2.50 cm2 is inserted into a thermally insulated vessel containing liquid helium at 4.20 K. The rod is initially at 300 K. (a) If one-half of the rod is inserted into the helium, how many liters of helium boil off by the time the inserted half cools to 4.20 K? Assume the upper half does not yet cool. (b) If the circular surface of the upper end of the rod is maintained at 300 K, what is the approximate boil-off rate of liquid helium in liters per second after the lower half has reached 4.20 K? (Aluminum has thermal conductivity of 3 100 W/m K at 4.20 K; ignore its temperature variation. The density of liquid helium is 125 kg/m3.)arrow_forward
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