Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 19, Problem 92QRT
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What is standard free energy change for the formation of NO(g) from N2 and O2 at 298K given that
ΔH° = 180.7 kJ and ΔS° = 24.7 J/K ?
a. 173.3 kJ
b. 24.7 kJ
c. 180.7 kJ
d. 205.4kJ
Given the thermodynamic data below, calculate the value of the equilibrium constant for the reaction shown at 25.0ºCN₂ (g) + 3 H₂ (g) ⇄ 2 NH₃ (g)ΔHº = -92.22 kJΔSº = -198.59 J/KK = _____ at 25.0ºC
Use the data in appendix 4 and the information below to calculate the standard free energy of formation for C4H10(g)
2C4H10(g) + 13O2(g) 8CO2(g) + 10H2O(l) ΔG°= 25490 kJ.
Chapter 19 Solutions
Chemistry: The Molecular Science
Ch. 19.1 - Prob. 19.1ECh. 19.1 - Prob. 19.2ECh. 19.2 - Prob. 19.3CECh. 19.2 - Prob. 19.4CECh. 19.3 - Prob. 19.5ECh. 19.4 - Prob. 19.1PSPCh. 19.4 - Prob. 19.6ECh. 19.4 - Prob. 19.7ECh. 19.4 - Prob. 19.2PSPCh. 19.5 - Prob. 19.8CE
Ch. 19.5 - Prob. 19.9ECh. 19.5 - Prob. 19.3PSPCh. 19.5 - Use the terms oxidation, reduction, oxidizing...Ch. 19.5 - Prob. 19.11ECh. 19.6 - Prob. 19.13ECh. 19.6 - Prob. 19.14ECh. 19.6 - Prob. 19.15CECh. 19.6 - Prob. 19.16CECh. 19.6 - Prob. 19.4PSPCh. 19.6 - Prob. 19.5PSPCh. 19.6 - Prob. 19.17ECh. 19.6 - Prob. 19.6PSPCh. 19.6 - Prob. 19.7PSPCh. 19.6 - Prob. 19.8PSPCh. 19 - Prob. 1QRTCh. 19 - Prob. 2QRTCh. 19 - Prob. 3QRTCh. 19 - Prob. 4QRTCh. 19 - Prob. 5QRTCh. 19 - Prob. 6QRTCh. 19 - Prob. 7QRTCh. 19 - Prob. 8QRTCh. 19 - Prob. 9QRTCh. 19 - Prob. 10QRTCh. 19 - Prob. 11QRTCh. 19 - Prob. 12QRTCh. 19 - Prob. 13QRTCh. 19 - Prob. 14QRTCh. 19 - Prob. 15QRTCh. 19 - Prob. 16QRTCh. 19 - Prob. 17QRTCh. 19 - Prob. 18QRTCh. 19 - Prob. 19QRTCh. 19 - Prob. 20QRTCh. 19 - Prob. 21QRTCh. 19 - Prob. 22QRTCh. 19 - Prob. 23QRTCh. 19 - Prob. 24QRTCh. 19 - Prob. 25QRTCh. 19 - Prob. 26QRTCh. 19 - Identify the substance or substances produced by...Ch. 19 - Prob. 28QRTCh. 19 - Prob. 29QRTCh. 19 - Prob. 30QRTCh. 19 - Prob. 31QRTCh. 19 - Prob. 32QRTCh. 19 - Prob. 33QRTCh. 19 - Prob. 34QRTCh. 19 - Prob. 35QRTCh. 19 - Prob. 36QRTCh. 19 - Prob. 37QRTCh. 19 - Prob. 38QRTCh. 19 - Prob. 39QRTCh. 19 - Prob. 40QRTCh. 19 - Prob. 41QRTCh. 19 - Prob. 42QRTCh. 19 - A human body contains approximately 5 L of blood....Ch. 19 - Prob. 44QRTCh. 19 - Prob. 45QRTCh. 19 - Prob. 46QRTCh. 19 - Prob. 47QRTCh. 19 - Prob. 48QRTCh. 19 - Prob. 49QRTCh. 19 - Prob. 50QRTCh. 19 - Prob. 51QRTCh. 19 - Prob. 52QRTCh. 19 - Prob. 53QRTCh. 19 - Prob. 54QRTCh. 19 - Prob. 55QRTCh. 19 - Prob. 56QRTCh. 19 - Prob. 57QRTCh. 19 - Prob. 58QRTCh. 19 - Prob. 59QRTCh. 19 - Prob. 60QRTCh. 19 - Prob. 61QRTCh. 19 - Prob. 62QRTCh. 19 - Prob. 63QRTCh. 19 - Prob. 64QRTCh. 19 - Prob. 65QRTCh. 19 - Prob. 66QRTCh. 19 - Prob. 67QRTCh. 19 - Prob. 68QRTCh. 19 - Prob. 69QRTCh. 19 - Prob. 70QRTCh. 19 - Prob. 71QRTCh. 19 - Prob. 72QRTCh. 19 - Prob. 73QRTCh. 19 - Prob. 74QRTCh. 19 - Use the phase diagram for sulfur for Question 75....Ch. 19 - Prob. 76QRTCh. 19 - Prob. 77QRTCh. 19 - Prob. 78QRTCh. 19 - Prob. 79QRTCh. 19 - Prob. 80QRTCh. 19 - A natural brine found in Arkansas has a bromide...Ch. 19 - Prob. 82QRTCh. 19 - Prob. 83QRTCh. 19 - Prob. 84QRTCh. 19 - At 20. C the vapor pressure of white phosphorus is...Ch. 19 - Prob. 86QRTCh. 19 - Assume that the radius of Earth is 6400 km, the...Ch. 19 - Prob. 88QRTCh. 19 - Prob. 89QRTCh. 19 - Prob. 90QRTCh. 19 - Prob. 91QRTCh. 19 - Prob. 92QRTCh. 19 - Prob. 93QRTCh. 19 - Prob. 94QRTCh. 19 - Prob. 95QRTCh. 19 - Use a Born-Haber cycle (Sec. 5-13) to calculate...Ch. 19 - Prob. 97QRTCh. 19 - Elemental analysis of a borane indicates this...Ch. 19 - Prob. 99QRTCh. 19 - Prob. 100QRT
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- Although nitrogen trifluoride (NF3) is a thermally stable compound, nitrogen triiodide (NI3) is known to be a highly explosive material. NI3 can be synthesized according to the equation BN(s) + 3IF(g) BF3(g) + NI3(g) a. What is the enthalpy of formation for NI3(s) given the enthalpy of reaction (307 kJ) and the enthalpies of formation for BN(s) (254 kJ/mol), IF(g) (96 kJ/mol), and BF3(g) (1136 kJ/mol)? b. It is reported that when the synthesis of NI3 is conducted using 4 moles of IF for every 1 mole of BN, one of the by-products isolated is [IF2]+[BF4]. What are the molecular geometries of the species in this by-product? What are the hybridizations of the central atoms in each species in the by-product?arrow_forwardWhen boron hydrides burn in air, the reactions are very exothermic (a) Write a balanced equation for the combustion of B5H9(g) in air to give B2O3(s) and H2O(g). (b) Calculate the enthalpy of combustion for B5H9(g) (fH = 73.2 kJ/mol), and compare it with the enthalpy of combustion of B2H6 (2038 kJ/mol). (The enthalpy of formation of B2O3(s) is 1271.9 kJ/mol.) (c) Compare the enthalpy of combustion of C2H6(g) with that of B2H6(g). Which transfers more energy as heat per gram?arrow_forwardThe thermite reaction is highly exothermic as illustrated as follows: Fe2O3 (s) + 2 Al (s) --> 2 Fe (s) + Al2O (s) + 850 kJ What mass of aluminum would be required to produce 375 kJ of energy?arrow_forward
- What is the free energy change in a reaction of 21.77 g of zinc metal at 25°C? (kJ, 0.01) Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s)arrow_forwardThe Haber process is very important for agriculture because it converts N2( g) from the atmosphere into bound nitrogen, which can be taken up and used by plants. The Haber process reaction is N2( g) + 3 H2( g)<--->2 NH3( g). The reaction is exothermic but is carried out at relatively high temperatures. Why?arrow_forwardActually, the carbon in CO2(g) is thermodynamically unstable with respect to the carbon in calcium carbonate(limestone). Verify this by determining the standardGibbs free energy change for the reaction of lime,CaO(s), with CO2(g) to make CaCO3(s).arrow_forward
- The reaction of quicklime, CaO, with water produces slaked lime, Ca(OH)2, which is widely used in the construction industry to make mortar and plaster. The reaction of quicklime and water is highly exothermic: CaO(s)+H2O(l)Ca(OH)2(s)H=350kJmol1 (a) What is the enthalpy of reaction per gram of quicklime that reacts?. (b) How much heat, in kilojoules, is associated with the production of 1 ton of slaked lime?arrow_forwardUse the standard free energy of formation data in Appendix G to determine the free energy change for each of the following reactions, which are run under standard state conditions and 25 C. Identify each as either spontaneous or nonspontaneous at these conditions. (a) MnO2(s)Mn(s)+O2(g) (b) H2(g)+Br2(l)2HBr(g) (c) Cu(s)+S(g)CuS(s) (d) 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(g) (e) CH4(g)+O2(g)C(s,graphite)+2H2O(g) (f) CS2(g)+3Cl2(g)CCl4(g)+S2Cl2(g)arrow_forwardUsing values of fH and S, calculate the standard molar free energy of formation, fG, for each of the following: (a) Ca(OH)2(s) (b) Cl(g) (c) Na2CO3(s) Compare your calculated values of fG with those listed in Appendix L. Which of these formation reactions are predicted to be product-favored at equilibrium at 25 C?arrow_forward
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