Organic Chemistry
8th Edition
ISBN: 9781337516402
Author: Brown
Publisher: Cengage
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Chapter 19.9, Problem AQ
Interpretation Introduction
Interpretation:
The type of given reaction has to be identified.
Concept introduction:
Fischer esterification reaction:
- • The reaction of an alcohol and a
carboxylic acid to form an ester under acidic condition is called Fischer esterification reaction. - • Alcohol act as a nucleophile and attack on the carbonyl carbon of the acid.
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Draw the structure(s) of the major organic product(s) of the following reaction.
1. Complete the following reactions.
a.
b.
C.
N
HIN
1. LiAlH4
2. H₂O*
1. NaAlH4
2. H₂O*
1. LiAlH4
2. H₂O*
. Use stepwise synthesis including reagents and intermediates to complete the
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1)
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Chapter 19 Solutions
Organic Chemistry
Ch. 19.2 - Prob. 19.1PCh. 19.2 - Prob. 19.2PCh. 19.2 - Prob. 19.3PCh. 19.3 - Prob. 19.4PCh. 19.3 - Prob. 19.5PCh. 19.3 - Prob. 19.6PCh. 19.5 - Prob. 19.7PCh. 19.5 - Prob. 19.8PCh. 19.5 - Prob. 19.9PCh. 19.6 - Prob. 19.10P
Ch. 19.6 - Prob. 19.11PCh. 19.7 - Prob. 19.12PCh. 19.8 - Prob. 19.13PCh. 19.8 - Prob. 19.14PCh. 19.8 - Prob. 19.15PCh. 19.8 - Prob. 19.16PCh. 19.9 - Prob. 19.17PCh. 19.9 - Prob. AQCh. 19.9 - Prob. BQCh. 19.9 - Prob. CQCh. 19.9 - Prob. DQCh. 19.9 - Prob. EQCh. 19.9 - Prob. FQCh. 19.9 - Prob. GQCh. 19.9 - Intermediate G in Synthesis III is produced as a...Ch. 19.9 - Prob. IQCh. 19.9 - Prob. JQCh. 19 - Prob. 19.18PCh. 19 - Prob. 19.19PCh. 19 - Prob. 19.20PCh. 19 - Prob. 19.21PCh. 19 - Prob. 19.22PCh. 19 - Prob. 19.23PCh. 19 - Cyclohexene can be converted to...Ch. 19 - Prob. 19.25PCh. 19 - Prob. 19.26PCh. 19 - Prob. 19.27PCh. 19 - Prob. 19.28PCh. 19 - Prob. 19.29PCh. 19 - Prob. 19.30PCh. 19 - Draw structural formulas for the -ketoesters...Ch. 19 - Prob. 19.32PCh. 19 - Prob. 19.33PCh. 19 - Propose a synthesis for each ketone, using as one...Ch. 19 - Prob. 19.35PCh. 19 - Claisen condensation between diethyl phthalate and...Ch. 19 - Prob. 19.37PCh. 19 - Prob. 19.38PCh. 19 - Prob. 19.39PCh. 19 - Enamines normally react with methyl iodide to give...Ch. 19 - Prob. 19.41PCh. 19 - Prob. 19.42PCh. 19 - Prob. 19.43PCh. 19 - Prob. 19.44PCh. 19 - Prob. 19.45PCh. 19 - Prob. 19.46PCh. 19 - Prob. 19.47PCh. 19 - Prob. 19.48PCh. 19 - Prob. 19.49PCh. 19 - Prob. 19.50PCh. 19 - Prob. 19.51PCh. 19 - Prob. 19.52PCh. 19 - Show experimental conditions by which to carry out...Ch. 19 - Prob. 19.55PCh. 19 - The compound 3,5,5-trimethyl-2-cyclohexenone can...Ch. 19 - Prob. 19.57PCh. 19 - Prob. 19.58PCh. 19 - The widely used anticoagulant warfarin (see...Ch. 19 - Following is a retrosynthetic analysis for an...Ch. 19 - Following are the steps in one of the several...Ch. 19 - Prob. 19.62PCh. 19 - Prob. 19.63PCh. 19 - Prob. 19.65PCh. 19 - Prob. 19.67PCh. 19 - Prob. 19.68PCh. 19 - Prob. 19.69PCh. 19 - In Problem 7.28, we saw this two-step sequence in...Ch. 19 - Using your reaction roadmaps as a guide, show how...Ch. 19 - Using your reaction roadmaps as a guide, show how...Ch. 19 - Using your reaction roadmaps as a guide, show how...Ch. 19 - Using your reaction roadmaps as a guide, show how...Ch. 19 - Using your reaction roadmaps as a guide, show how...Ch. 19 - Prob. 19.79PCh. 19 - Prob. 19.80PCh. 19 - Prob. 19.81PCh. 19 - The following molecule undergoes an intramolecular...
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- 64. Which of the following reactant-product relationship is correct? A. 2-methylbutan-2-ol 2-methylbutanoic acid KMnO4 B. 2-methylbutan-2-ol 2-methylbut-3-ene H2504 C. 4-tert-butylcyclohexanol 4- tertbutylcyclohexanone Na2Cr207 D. 4- tertbutylcyclohexanol 4- tertbutylcyclohexanone 7 H2504 65. Choose the correct steps in the dehydration of secondary alcohol; then, arrange in chronological order. 1- Formation of Alkene Il-Formation of Aldehyde III- Formation of Protonated alcohol IV-Undergoes E2 mechanism V-Undergoes E1 mechanism A. V-III-I B. IV-III-II C. III-V-I D. III-IV-II 66. ALL of the following Ether can be prepared by Williamson's method, EXCEPT: A. Ditert-butyl ether B. Ethyl-tert-butyl ether C. anisole D. Both A & B 67. Ethanol is heated with an acidified potassium manganate (VII) solution. What would be the product of this reaction? A. Ethanal B. Ethene C. Ethanoic acid D. Ethanearrow_forwardWhat is the major organic product obtained from the following reaction? A. Ph B. Ph N=Ph -NH₂ OH H3O+ heat C. D. Ph Ph =NH NH₂arrow_forwardCompare aldehydes and ketones as to (Use acetaldehyde and acetone as examples). 1. Reaction with Tollen’s reagent 2. Reaction with Fehling’s reagent 3. Reaction with dilute NaOHarrow_forward
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