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Mass spectrometry is one of the most versatile and powerful tools chemical analysis because of its capacity to discriminate between atoms of different masses. When a sample containing a mixture of isotopes is introduced into a mass spectrometer, the ratio of the peaks observed reflects the ratio of the percent
An analysis was done on a rock sample to determine its rubidium content. The rubidium content of a portion of rock weighing 0.350 g was extracted, and to the extracted sample was added an additional 29.45 μg of
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- Reference Section 5-2 to find the atomic masses of 12C and 13C, the relative abundance of 12C and 13C in natural carbon, and the average mass (in u) of a carbon atom. If you had a sample of natural carbon containing exactly 10,000 atoms, determine the number of 12C and 13C atoms present. What would be the average mass (in u) and the total mass (in u) of the carbon atoms in this 10,000-atom sample? If you had a sample of natural carbon containing 6.0221 1023 atoms, determine the number of 12C and 13C atoms present What would be the average mass (in u) and the total mass (in u) of this 6.0221 1023 atom sample? Given that 1 g = 6.0221 1023 u, what is the total mass of I mole of natural carbon in units of grams?arrow_forwardThe element europium exists in nature as two isotopes: 151Eu has a mass of 150.9196 u and 153Eu has a mass of 152.9209 u. The average atomic mass of europium is 151.96 u. Calculate the relative abundance of the two europium isotopes.arrow_forwardClick on the site (http://openstaxcollege.org/l/16PhetAtomMass) and select the Mix Isotopes tab, hide the Percent Composition and Average Atomic Mass boxes, and then select the element boron. Write the symbols of the isotopes of boron that are shown as naturally occurring in significant amounts. Predict the relative amounts (percentages) of these boron isotopes found in nature. Explain the reasoning behind your choice. Add isotopes to the black box to make a mixture that matches your prediction in (b). You may drag isotopes from their bins or click on More and then move the sliders to the appropriate amounts. Reveal the Percent Composition and Average Atomic Mass boxes. How well does your mixture match with your prediction? If necessary, adjust the isotope amounts to match your prediction. Select Nature’s mix of isotopes and compare it to your prediction. How well does your prediction compare with the naturally occurring mixture? Explain. If necessary, adjust your amounts to make them match Nature’s amounts as closely as possible.arrow_forward
- Neon has three stable isotopes, one with a small abundance. What are the abundances of the other two isotopes? 20Ne, mass = 19.992435 u; percent abundance = ? 21Ne mass = 20.993843 u; percent abundance = 027% 22Ne mass = 21.991383 u: percent abundance = ?arrow_forwardThe element europium exists in nature as two isotopes: 151Eu has a mass of 150.9196 amu, and 153Eu has a mass of 152.9209 amu. The average atomic mass of europium is 151.96 amu. a. Calculate the relative abundance of the two europium isotopes. b. Graph each fractional abundance value as a y-axis value in association with its corresponding mass value on the x-axis. Starting from each x-axis value, where y = 0, draw a vertical line up to the fractional abundance value. The result will approximate the type of visual graph a mass spectrometer would yield for europium in the 150155 amu range.arrow_forwardClick on the site (http://openstaxcollege.org/l/16PhetAtomMass) and select the Mix Isotopes tab, hide the Percent Composition and Average Atomic Mass boxes, and then select the element boron. Write the symbols of the isotopes of boron that are shown as naturally occurring in significant amounts. Predict the relative amounts (percentages) of these boron isotopes found in nature. Explain the reasoning behind your choice. Add isotopes to the black box to make a mixture that matches your prediction in (b). You may drag isotopes from their bins or click on More and then move the sliders to the appropriate amounts. Reveal the Percent Composition and Average Atomic Mass boxes. How well does your mixture match with your prediction? If necessary, adjust the isotope amounts to match your prediction. Select Nature’s mix of isotopes and compare it to your prediction. How well does your prediction compare with the naturally occurring mixture? Explain. If necessary, adjust your amounts to make them match Nature’s amounts as closely as possible. 21. Repeat Exercise 2.20 using an element that has three naturally occurring isotopes.arrow_forward
- Europium has two stable isotopes, 151Eu and 153Eu, with masses of 150.9197 u and 152.9212 u, respectively. Calculate the percent abundances of these isotopes of europium.arrow_forwardAn element X bas five major isotopes, which are listed below along with their abundances. What is the element? Isotope Percent Natural Abundance Mass (u) 46x 8.00% 45.95232 47x 7.30% 46.951764 48x 73.80% 47.947947 49x 5.50% 48.947841 50x 5.40% 49.944792arrow_forward2.92 A candy manufacturer makes chocolate-covered cherries. Although all of the products look roughly the same, 3% of them are missing the cherry. The mass of the candy with a cherry is 18.5 g; those missing the cherry weigh only 6.4 g. (a) How would you compute the average mass of a box of 100 of these chocolate covered cherries from this manufacturer? (b) I low is this question analogous to the determination of atomic weights?arrow_forward
- Polystyrene can be prepared by heating styrene with tribromobenzoyl peroxide in the absence of air. A sample prepared by this method has the empirical formula Br3C6cH3(C8H8)n, where the value of n can vary from sample to sample. If one sample has 0.105% Br, what is the value of n?arrow_forwardThe average atomic masses of some elements may vary, depending upon the sources of their ores. Naturally occurring boron consists of two isotopes with accurately known masses ( 10B, 10.0129 amu and 11B, 11.0931 amu). The actual atomic mass of boron can vary from 10.807 to 10.8 19, depending on whether the mineral source is from Turkey or the United States. Calculate the percent abundances leading to the two values of the average atomic masses of boron from these two countries.arrow_forwardThe mass spectrum of CH3Cl is illustrated here. You know that carbon has two stable isotopes, and 13C with relative abundances of 98.9% and 1.1%, respectively, and chlorine has two isotopes, 35a and 37CI with abundances of 75.77% and 24.23%, respectively. (a) What molecular species gives rise to the lines at m/Z of 50 and 52? Why is the line at 52 about 1/3 the height of the line at 50? (b) What species might be responsible for the line at m/Z = 51?arrow_forward
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
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