The mechanism for the rearrangement that converts an α -hydroxyimine to α -aminoketone in the presence of trace amount of acid has to be given. Concept Introduction: “ Keto-enol tautomerism ” is defined as the rearrangement to a chemical equilibrium between a keto form and an enol. The enol and keto forms are said to be tautomers of each other.

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Answer 1

Question

Chapter 21, Problem 64P

Interpretation Introduction

Interpretation:

The mechanism for the rearrangement that converts an α-hydroxyimine to α-aminoketone in the presence of trace amount of acid has to be given.

Concept Introduction:

“Keto-enol tautomerism” is defined as the rearrangement to a chemical equilibrium between a keto form and an enol. The enol and keto forms are said to be tautomers of each other.

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Answer 2

Question

Chapter 21, Problem 64P

Interpretation Introduction

Interpretation:

The mechanism for the rearrangement that converts an α-hydroxyimine to α-aminoketone in the presence of trace amount of acid has to be given.

Concept Introduction:

“Keto-enol tautomerism” is defined as the rearrangement to a chemical equilibrium between a keto form and an enol. The enol and keto forms are said to be tautomers of each other.

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Answer 3

Question

Chapter 21, Problem 64P

Interpretation Introduction

Interpretation:

The mechanism for the rearrangement that converts an α-hydroxyimine to α-aminoketone in the presence of trace amount of acid has to be given.

Concept Introduction:

“Keto-enol tautomerism” is defined as the rearrangement to a chemical equilibrium between a keto form and an enol. The enol and keto forms are said to be tautomers of each other.

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Answer 4

Question

Chapter 21, Problem 64P

Interpretation Introduction

Interpretation:

The mechanism for the rearrangement that converts an α-hydroxyimine to α-aminoketone in the presence of trace amount of acid has to be given.

Concept Introduction:

“Keto-enol tautomerism” is defined as the rearrangement to a chemical equilibrium between a keto form and an enol. The enol and keto forms are said to be tautomers of each other.

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Answer 5

Chapter 21, Problem 64P

Interpretation Introduction

Interpretation:

The mechanism for the rearrangement that converts an α-hydroxyimine to α-aminoketone in the presence of trace amount of acid has to be given.

Concept Introduction:

“Keto-enol tautomerism” is defined as the rearrangement to a chemical equilibrium between a keto form and an enol. The enol and keto forms are said to be tautomers of each other.

Answer 6

Chapter 21, Problem 64P

Interpretation Introduction

Interpretation:

The mechanism for the rearrangement that converts an α-hydroxyimine to α-aminoketone in the presence of trace amount of acid has to be given.

Concept Introduction:

“Keto-enol tautomerism” is defined as the rearrangement to a chemical equilibrium between a keto form and an enol. The enol and keto forms are said to be tautomers of each other.

Answer 7

Chapter 21, Problem 64P

Interpretation Introduction

Interpretation:

The mechanism for the rearrangement that converts an α-hydroxyimine to α-aminoketone in the presence of trace amount of acid has to be given.

Concept Introduction:

“Keto-enol tautomerism” is defined as the rearrangement to a chemical equilibrium between a keto form and an enol. The enol and keto forms are said to be tautomers of each other.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 21.1 - Prob. 1P Ch. 21.2 - Prob. 2P Ch. 21.2 - Prob. 3P Ch. 21.3 - Prob. 4P Ch. 21.3 - Prob. 5P Ch. 21.3 - Prob. 6P Ch. 21.4 - Prob. 7P Ch. 21.4 - Prob. 8P Ch. 21.5 - Prob. 9P Ch. 21.5 - Prob. 10P

Solution Summary: The author defines 'keto-enol tautomerism' as the rearrangement to chemical equilibrium between a keto form and an en.

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Chapter 21 Solutions