Concept explainers
(a)
Interpretation: The products formed by the treatment of benzoic anhydride
Concept introduction: Anhydrides involve two carbonyl groups. The nucleophilic substitution reaction of anhydride involves the attack of nucleophilic at one carbonyl group, which causes the second carbonyl group to be the part of leaving group.
Answer to Problem 22.14P
The products formed by the treatment of benzoic anhydride
Explanation of Solution
The given treatment involves reaction of benzoic anhydride
Anhydrides involve two carbonyl groups. The nucleophilic substitution reaction of anhydride involves the attack of nucleophilic at one carbonyl group, which causes the second carbonyl group to be the part of leaving group.
Anhydrides yield two equivalents of carboxylic acids, when they are treated with
The products formed by the treatment of benzoic anhydride
Figure 1
The products formed by the treatment of benzoic anhydride
(b)
Interpretation: The products formed by the treatment of benzoic anhydride
Concept introduction: Anhydrides involve two carbonyl groups. The nucleophilic substitution reaction of anhydride involves the attack of nucleophilic at one carbonyl group, which causes the second carbonyl group to be the part of leaving group.
Answer to Problem 22.14P
The products formed by the treatment of benzoic anhydride
Explanation of Solution
The given treatment involves reaction of benzoic anhydride
Anhydrides involve two carbonyl groups. The nucleophilic substitution reaction of anhydride involves the attack of nucleophilic at one carbonyl group, which causes the second carbonyl group to be the part of leaving group.
Anhydrides yield esters, and carboxylic acids, when they are treated with
The products formed by the treatment of benzoic anhydride
Figure 2
The products formed by the treatment of benzoic anhydride
(c)
Interpretation: The products formed by the treatment of benzoic anhydride
Concept introduction: Anhydrides involve two carbonyl groups. The nucleophilic substitution reaction of anhydride involves the attack of nucleophilic at one carbonyl group, which causes the second carbonyl group to be the part of leaving group.
Answer to Problem 22.14P
The products formed by the treatment of benzoic anhydride
Explanation of Solution
The given treatment involves reaction of benzoic anhydride
Anhydrides involve two carbonyl groups. The nucleophilic substitution reaction of anhydride involves the attack of nucleophilic at one carbonyl group, which causes the second carbonyl group to be the part of leaving group.
Anhydrides yield amide and an ammonium salt of carboxylic acid, when they are treated with
The products formed by the treatment of benzoic anhydride
Figure 3
The products formed by the treatment of benzoic anhydride
(d)
Interpretation: The products formed by the treatment of benzoic anhydride
Concept introduction: Anhydrides involve two carbonyl groups. The nucleophilic substitution reaction of anhydride involves the attack of nucleophilic at one carbonyl group, which causes the second carbonyl group to be the part of leaving group.
Answer to Problem 22.14P
The products formed by the treatment of benzoic anhydride
Explanation of Solution
The given treatment involves reaction of benzoic anhydride
Anhydrides involve two carbonyl groups. The nucleophilic substitution reaction of anhydride involves the attack of nucleophilic at one carbonyl group, which causes the second carbonyl group to be the part of leaving group.
Anhydrides yield amide and an ammonium salt of carboxylic acid, when they are treated with
The products formed by the treatment of benzoic anhydride
Figure 4
The products formed by the treatment of benzoic anhydride
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Chapter 22 Solutions
Organic Chemistry
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- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning