Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 22, Problem 22.53QP
Interpretation Introduction
Interpretation: The discrepancy between the minimum value and the actual value to be interpreted.
Concept Introduction:
Crystal field splitting: The energy gap between the splitting of d-orbitals of the metal ion in presence of ligands is known as the crystal field splitting
Reaction of coordination compounds: Complex ion undergoes ligand exchange (or substitution) reactions in solution. The
To Identify: The discrepancy between the minimum value and the actual value to be interpreted.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
What are the ligands of Hemoglobin?
True or false:
a.
The metal center in cisplatin, cis-[PtCl2(NH3)2], has an oxidation state of 0 and a coordination number of 4.
b.
Thiocyanate (SCN–) and oxalate (C2O42–) ions are examples of bidentate ligands.
c.
Dichloridobis(ethylenediamine)chromium(III) has three stereoisomers but no structural isomers.
Draw the structure of the following speciesΛ-tris(oxalato)cobaltate(III) iontriaquacyanodipyridinechromium(III) ion
Chapter 22 Solutions
Chemistry: Atoms First
Ch. 22.1 - Prob. 22.1WECh. 22.1 - Give oxidation numbers for the metals in (a)...Ch. 22.1 - Prob. 1PPBCh. 22.1 - Prob. 1PPCCh. 22.1 - Write the names of the following coordination...Ch. 22.1 - Give the correct name for (a) [Co(NH3)4Br2]Cl, (b)...Ch. 22.1 - Prob. 2PPBCh. 22.1 - Prob. 2PPCCh. 22.1 - Prob. 22.3WECh. 22.1 - Prob. 3PPA
Ch. 22.1 - Prob. 3PPBCh. 22.1 - Prob. 3PPCCh. 22.1 - Prob. 22.1.1SRCh. 22.1 - Prob. 22.1.2SRCh. 22.1 - Prob. 22.1.3SRCh. 22.1 - Write the correct formula for...Ch. 22.3 - Prob. 22.4WECh. 22.3 - Prob. 4PPACh. 22.3 - Prob. 4PPBCh. 22.3 - Prob. 4PPCCh. 22.3 - Prob. 22.3.1SRCh. 22.3 - Prob. 22.3.2SRCh. 22 - What distinguishes a transition metal from a main...Ch. 22 - Prob. 22.2QPCh. 22 - Prob. 22.3QPCh. 22 - Without referring to the text, write the...Ch. 22 - Write the electron configurations of the following...Ch. 22 - Prob. 22.6QPCh. 22 - Prob. 22.7QPCh. 22 - Prob. 22.8QPCh. 22 - Describe the interaction between a donor atom and...Ch. 22 - Prob. 22.10QPCh. 22 - Prob. 22.11QPCh. 22 - Prob. 22.12QPCh. 22 - Prob. 22.13QPCh. 22 - What are the systematic names for the following...Ch. 22 - Prob. 22.15QPCh. 22 - Write the formulas for each of the following ions...Ch. 22 - Prob. 22.17QPCh. 22 - Prob. 22.18QPCh. 22 - Prob. 22.19QPCh. 22 - Prob. 22.20QPCh. 22 - Prob. 22.21QPCh. 22 - Prob. 22.22QPCh. 22 - Prob. 22.23QPCh. 22 - Prob. 22.24QPCh. 22 - Prob. 22.25QPCh. 22 - Briefly describe crystal field theory.Ch. 22 - Prob. 22.27QPCh. 22 - What is the origin of color in a coordination...Ch. 22 - Prob. 22.29QPCh. 22 - Prob. 22.30QPCh. 22 - Prob. 22.31QPCh. 22 - Prob. 22.32QPCh. 22 - The absorption maximum for the complex ion...Ch. 22 - Prob. 22.34QPCh. 22 - Prob. 22.35QPCh. 22 - Prob. 22.36QPCh. 22 - Prob. 22.37QPCh. 22 - Prob. 22.38QPCh. 22 - Prob. 22.39QPCh. 22 - Prob. 22.40QPCh. 22 - The [Fe(CN)6]3 complex is more labile than the...Ch. 22 - Prob. 22.42QPCh. 22 - Prob. 22.43QPCh. 22 - Prob. 22.44QPCh. 22 - Prob. 22.45QPCh. 22 - Prob. 22.46QPCh. 22 - Prob. 22.47QPCh. 22 - Prob. 22.48QPCh. 22 - Prob. 22.49QPCh. 22 - Prob. 22.50QPCh. 22 - Prob. 22.51QPCh. 22 - Prob. 22.52QPCh. 22 - Prob. 22.53QPCh. 22 - Prob. 22.54QPCh. 22 - A student in 1895 prepared three coordination...Ch. 22 - Prob. 22.56QPCh. 22 - Prob. 22.57QPCh. 22 - Prob. 22.58QPCh. 22 - Prob. 22.59QPCh. 22 - Prob. 22.60QPCh. 22 - Prob. 22.61QPCh. 22 - Hydrated Mn2+ ions are practically colorless (see...Ch. 22 - Which of the following hydrated cations are...Ch. 22 - Prob. 22.64QPCh. 22 - Prob. 22.65QPCh. 22 - Prob. 22.66QPCh. 22 - Prob. 22.67QPCh. 22 - Prob. 22.68QPCh. 22 - Prob. 22.69QPCh. 22 - Prob. 22.70QPCh. 22 - Commercial silver-plating operations frequently...Ch. 22 - Prob. 22.72QPCh. 22 - Prob. 22.73QPCh. 22 - Prob. 22.74QPCh. 22 - Prob. 22.75QPCh. 22 - Prob. 22.76QPCh. 22 - Prob. 22.77QPCh. 22 - Prob. 22.78QPCh. 22 - Prob. 22.79QPCh. 22 - Prob. 22.80QP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- (a) Name this coordination compound: [Ag(NH3)2]NO3. (b) Write the formula of pentaaquaisothiocyanatoiron(III) chloride.arrow_forwardA protein has a binding affinity for its lignd of Ka =2 x 10^5M at pH 7.0 and 25 degrees celcius. At what concentration of the ligand is half of the protein bound?arrow_forward>Hemoglobin exists in two predominant forms in our bodies. One form, known as oxyhemoglobin, has O2 bound to the iron and the other, known as deoxyhemoglobin, has a water molecule bound instead. Oxyhemoglobin is a low-spin complex that gives arterial blood its red color, and deoxyhemoglobin is a high-spin complex that gives venous blood its darker color. Explain these observations in terms of crystal field splitting. Would you categorize O2 as a strong- or weak-field ligand?arrow_forward
- In what directions do you expect the bond length andvibrational frequency of a free CO molecule to changewhen it becomes a CO ligand in a Ni(CO)4 molecule?Explain your reasoning.arrow_forwardThe Lewis structure :C≡O: indicates that the CO molecule has two lone pairs of electrons. When CO binds to a transition-metalatom, it nearly always does so by using the C lone pair. How many geometric isomers are there for tetracarbonyldichloroiron(II)?arrow_forwardOxyhemoglobin, with an O2 bound to iron, is a low-spin Fe(II) complex; deoxyhemoglobin, without the O2 molecule, is a high-spin complex. Explain in a general way why the two forms of hemoglobin have different colors (hemoglobin is red, whereas deoxyhemoglobin has a bluish cast).arrow_forward
- Which of the actinides are radioactive?arrow_forwardWrite the formula for each of the following compounds, being sure to use brackets to indicate the coordination sphere: (a) potassium tetrabromo(ortho-phenanthroline)cobaltate(III) (b) cesium diamminetetracyanochromate(III)arrow_forwardHow is ligand bound to a protein? List the physical forces?arrow_forward
- What coordination isomer can be written for [Co(en)3][Cr(ox)3]?arrow_forwardOxyhemoglobin, with an O2 bound to iron, is a low-spin Fe(II) complex; deoxyhemoglobin, without the O2 molecule, is a high-spin complex. Assuming that the coordination environment about the metal is octahedral, how many unpaired electrons are centered on the metal ion in each case?arrow_forwardChemical formula of the coordination compound amminebromochloromethylamineplatinum(II)arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
The Bohr Model of the atom and Atomic Emission Spectra: Atomic Structure tutorial | Crash Chemistry; Author: Crash Chemistry Academy;https://www.youtube.com/watch?v=apuWi_Fbtys;License: Standard YouTube License, CC-BY