Study Guide for Chemistry: Structure and Properties
2nd Edition
ISBN: 9780134460680
Author: Nivaldo Tro
Publisher: PEARSON
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Chapter 22, Problem 57E
Interpretation Introduction
Introduction: Electronic configurations of elements can be reliably predicted with Aufbau principle.As the
To determine:
The ground state configuration of the following species of Cr and Cu which are exceptions to normal orbital filing
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20. Which absorbs photons of the longest
wavelength?
A. [COCI4]²-
B. [Co(H20)6]*
C. [Co(NH3)6]?*
D. [Cola]2-
Draw the d orbital diagram for the following molecules/ions and calculate CFSE energy.
a. Cr(H2O)62+
b. Co(NH3)62+
c. Mn(NH3)62+
d. NiI42-
e. Mn(CN)63-
f. PtCl42-
Which of the following orbitals will have the lowest (most negative) energy if we are considering the
5
20.
electron configuration for a transition metal?
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Е.
4fxyz
Chapter 22 Solutions
Study Guide for Chemistry: Structure and Properties
Ch. 22 - When a transition metal atom forms an ion, which...Ch. 22 - Explain why transition metals exhibit multiple...Ch. 22 - Why is the +2 oxidation state so common for...Ch. 22 - Explain why atomic radii of elements in the third...Ch. 22 - Gold is the most electronegative transition metal....Ch. 22 - Prob. 6ECh. 22 - Prob. 7ECh. 22 - Explain the differences between each pair of...Ch. 22 - Prob. 9ECh. 22 - Prob. 10E
Ch. 22 - Prob. 11ECh. 22 - Prob. 12ECh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Prob. 15ECh. 22 - Prob. 16ECh. 22 - Prob. 17ECh. 22 - Write the ground state electron configuration for...Ch. 22 - Determine the highest possible oxidation state for...Ch. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Prob. 24ECh. 22 - Prob. 25ECh. 22 - Prob. 26ECh. 22 - Prob. 27ECh. 22 - Write the formula and the name of each complex ion...Ch. 22 - Prob. 29ECh. 22 - Prob. 30ECh. 22 - Prob. 31ECh. 22 - Prob. 32ECh. 22 - Prob. 33ECh. 22 - Prob. 34ECh. 22 - Prob. 35ECh. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Prob. 39ECh. 22 - Prob. 40ECh. 22 - Prob. 41ECh. 22 - Prob. 42ECh. 22 - Prob. 43ECh. 22 - Prob. 44ECh. 22 - Prob. 45ECh. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - Prob. 49ECh. 22 - Prob. 50ECh. 22 - Prob. 51ECh. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Most of the second-row transition metals do not...Ch. 22 - Prob. 59ECh. 22 - Prob. 60ECh. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Hexacyanomanganate(III) ion is a low-spin complex....Ch. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Prob. 71ECh. 22 - Prob. 72ECh. 22 - Prob. 73ECh. 22 - Calculate the solubility of Zn(OH)2(s) in 2.0 M...Ch. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - Prob. 79ECh. 22 - Prob. 80ECh. 22 - Have each group member choose a row of the...Ch. 22 - Prob. 82ECh. 22 - Prob. 83ECh. 22 - Prob. 84ECh. 22 - Prob. 85ECh. 22 - Many aqueous solutions of complex ions display...Ch. 22 - What is the electron configuration of the Cu+ ion?...Ch. 22 - Prob. 2SAQCh. 22 - Prob. 3SAQCh. 22 - Prob. 4SAQCh. 22 - Prob. 5SAQCh. 22 - Prob. 6SAQCh. 22 - Prob. 7SAQCh. 22 - Estimate the crystal field splitting energy (in...Ch. 22 - Use crystal field theory to determine the number...Ch. 22 - Prob. 10SAQ
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- What two first-row transition metals have unexpected electron configurations? A statement in the text says that first-row transition metal ions do not have 4s electrons. Why not? Why do transition metal ions often have several oxidation states, whereas representative metals generally have only one?arrow_forwardNonearrow_forwardDraw the d orbital diagram for the following molecules/ions and calculate CFSE energy. d. NiI42- e. Mn(CN)63- f. PtCl42-arrow_forward
- 4 Illustrate how complex formation between Fe³* and SCN occurs by presenting electrons by arrows (1) in two colors (one color for Fe³+ and another color for SCN) in the orbital diagram below (only from 3d-orbital of Fe³+) 3d 4s 4parrow_forwardThe three of the four ions shown below have the same electron configuration, but the fourth does not. Identify the one that does not match with the others A. Mn2+ B. Fe3+ C. Cr+ D. Fe2+arrow_forwardThe electronic configuration of 15 X 3- ion is a. [Ne]3s23p2 b. [Ne]3s2 c. [Ne]3s23p6 d. [Ne]3s23p1arrow_forward
- Calculate the electron in the following complexes. a,b,c,darrow_forwardWhich of the following is the electronic configuration of the Chromium(III)? Cr3+ [Ar] 3d3 .a O Cr3+ [Ar] 4s1 3d5 .BO Cr3+ [Ar] 4s2 3d4. .CO C3+ [Ar] 3d° DOarrow_forwardThe electron configuration of a Cr 3+ ion is [Ar]4s23d4. [Ar]4s13d2. [Ar]3d5. [Ar]3d3. [Ar]4s13d5.arrow_forward
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