Organic Chemistry, 12e Study Guide/Student Solutions Manual
Organic Chemistry, 12e Study Guide/Student Solutions Manual
12th Edition
ISBN: 9781119077329
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 24, Problem 20P
Interpretation Introduction

Interpretation:

Outlining the reactions that are involved in the synthesis of DL-Glutamic acid from diethyl acetamidomalonate. Outlining the reactions which are involved in the preparation of DL-ornithine by the intermediate compound, ‘G’.

Concept Introduction:

The reaction of an aldehyde with ammonia and hydrogen cyanide produces an αa-aminonitrile, which on hydrolysis, gives amino acid. This synthetic strategy is called the Strecker synthesis.

Organic Chemistry, 12e Study Guide/Student Solutions Manual, Chapter 24, Problem 20P

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(a) Compound Z is a tertiary aromatic amine with the formula, C8H11N. Provide a chemical structure for compound Z. (b)nDraw the structure of the product formed exclusively when nitrous acid reacts with Z.
Predict the products formed in each of the following reactions, and write a balanced equation: (a) CH3NHNH2(g) + O2(8) → ? (b) Mg3P2(s) + H20(1) → ?
(b) (i) The reaction between aromatic compound W, C,H$OC1 with an amine X, CH>N was carried out. The compound Y was extracted and purified from this reaction. It was then reduced by LİAIH4 followed by hydrolysis to obtain compound Z, which is a tertiary amine. Draw the structures for compounds W, X, Y and Z.
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