EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
12th Edition
ISBN: 9781119233664
Author: Snyder
Publisher: VST
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Chapter 24, Problem 20P
Interpretation Introduction

Interpretation:

Outlining the reactions that are involved in the synthesis of DL-Glutamic acid from diethyl acetamidomalonate. Outlining the reactions which are involved in the preparation of DL-ornithine by the intermediate compound, ‘G’.

Concept Introduction:

The reaction of an aldehyde with ammonia and hydrogen cyanide produces an αa-aminonitrile, which on hydrolysis, gives amino acid. This synthetic strategy is called the Strecker synthesis.

EBK ORGANIC CHEMISTRY, Chapter 24, Problem 20P

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(a) Compound Z is a tertiary aromatic amine with the formula, C8H11N. Provide a chemical structure for compound Z. (b)nDraw the structure of the product formed exclusively when nitrous acid reacts with Z.
Please draw the skeletal formula of the following compounds: (A) Isobutyraldehyde (B) α-Ethyl-γ-methoxycaproaldehyde   (C) 6-Hydroxyhexanal (D) 2,4-Pentanedione (E)3-Cyano-7-oxoheptanoic acid
(b) (i) The reaction between aromatic compound W, C,H$OC1 with an amine X, CH>N was carried out. The compound Y was extracted and purified from this reaction. It was then reduced by LİAIH4 followed by hydrolysis to obtain compound Z, which is a tertiary amine. Draw the structures for compounds W, X, Y and Z.
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