Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Draw the structure of all products of the
mechanism below.
H:I:SH
1:54
H₂N—C—C—C=c
CH3
H
H
H
Two products will form in the following
reaction. However only one is given.
Identify one of the major products in the
nitration reaction.
A
B
||
II
D IV
CH3
HNO3
H2SO4
CH,NO2
CH3
CH3
NO2
NO2
NO2
II
IV
In addition to organic halides, alkyl tosylates react with organocuprates (R2CuLi) to form coupling products R–R′. When 2° alkyl tosylates are used as starting materials (R2CHOTs), inversion of the configuration at a stereogenic center results. Keeping this in mind, draw the product formed when each compound is treated with (CH3)2CuLi.
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