Concept explainers
Draw the products formed in the crossed aldol reaction of phenylacetaldehyde
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Chapter 24 Solutions
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- Draw the product formed when pentanal (CH3CH2CH2CH2CHO) is treated with each reagent. With some reagents, no reaction occurs. [1] CH3CH2CH2CH2CHOH, then TBDMS—Cl, imidazolearrow_forwardWhat product is formed when attached compound is treated with either Ag2O, NH4OH or Na2Cr2O7, H2SO4, H2O?arrow_forwardDraw the products formed when A or B is treated with each reagent. In some cases, no reaction occurs. [1] C6H5Li (excess); [2] H2Oarrow_forward
- Draw a stepwise mechanism for the conversion of acrylonitrile (CH2 = CHC ≡ N) to polyacrylonitrile, –[CH2CHC ≡ N]n–, using butyllithium (BuLi) as the initiator and CO2 as the electrophile to terminate the chain.arrow_forwardDraw the substitution product formed (including stereochemistry) when (R)-hexan-2-ol is treated with each series of reagents: (a) NaH, followed by CH3I; (b) TsCl and pyridine, followed by NaOCH3; (c) PBr3, followed by NaOCH3. Which two routes produce identical products?arrow_forwardDraw the product formed when phenylacetic acid (C6H5CH2COOH) istreated with following reagent. With some reagents, no reaction occurs. NH3 (1 equiv)arrow_forward
- What enolate is formed when each ketone is treated with LDA in THF solution? What enolate is formed when these same ketones are treated with NaOCH3 in CH3OH solution?arrow_forwardDraw the product formed when pentanal (CH3CH2CH2CH2CHO) is treatedwith following reagent. With some reagents, no reaction occurs. Na2Cr2O7, H2SO4, H2Oarrow_forwardWhat product is formed when D-Gulose is treated with a. CH3I, Ag2O b. The product in (a), then H3O+ c. The product in (b), then C6H5CH2Cl, Ag2Oarrow_forward