Organic Chemistry & Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
7th Edition
ISBN: 9780321950123
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 24, Problem 26P
S-Adenosylmethionine (SAM) is formed from the reaction of methionine with ATP (Section 10.12). The other product of the reaction is triphosphate. Propose a mechanism for this reaction.
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Chapter 24 Solutions
Organic Chemistry & Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
Ch. 24.1 - Prob. 2PCh. 24.1 - Prob. 3PCh. 24.2 - How many conjugated double bonds are there in a....Ch. 24.2 - Instead of adding to the 4a position and...Ch. 24.2 - Prob. 7PCh. 24.3 - Prob. 8PCh. 24.3 - Acetolactate synthase is another TPP-requiring...Ch. 24.3 - Acetolactate synthase transfers the acyl group of...Ch. 24.5 - Prob. 12PCh. 24.5 - The enzyme that catalyzes the C C bond cleavage...
Ch. 24.5 - Propose a mechanism for the ,-elimination reaction...Ch. 24.5 - Which compound is more easily decarboxylated?Ch. 24.5 - Explain why the ability of PLP to catalyze an...Ch. 24.5 - Explain why the ability of PLP to catalyze an...Ch. 24.6 - Ethanolamine ammonia lyase, a coenzyme...Ch. 24.6 - Prob. 19PCh. 24.7 - How do the structure of tetrahydrofolate and...Ch. 24.7 - What is the source of the methyl group in...Ch. 24.8 - Thiols such as ethanethiol and propanethiol can be...Ch. 24 - How does the metal ion in carboxypeptidase A...Ch. 24 - Prob. 23PCh. 24 - Prob. 24PCh. 24 - Prob. 25PCh. 24 - S-Adenosylmethionine (SAM) is formed from the...Ch. 24 - Prob. 27PCh. 24 - What acyl groups have we seen transferred by...Ch. 24 - Propose a mechanism for the following reaction:Ch. 24 - When transaminated, the three branched-chain amino...Ch. 24 - Draw the products of the following reaction, where...Ch. 24 - When UMP is dissolved in T2O, exchange of T for H...Ch. 24 - Dehydratase is a PLP-requiring enzyme that...Ch. 24 - In addition to the reaction mentioned in Section...Ch. 24 - PLP can catalyze both ,-elimination reactions...Ch. 24 - The glycine cleavage system is a group of four...Ch. 24 - Prob. 37PCh. 24 - FADH2 reduces , -unsaturated thioesters to...
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- Draw the structure of cyclic adenosine monophosphate (cAMP), a messenger involved in the regulation of glucose production in the body. Cyclic AMP has a phosphate ring connecting the 39- and 59-hydroxyl groups on adenosine.arrow_forwardIn the pentose phosphate pathway for degrading sugars, ribulose 5-phosphate is converted to ribose 5-phosphate. Propose a mechanism for the isomerization.arrow_forwardQ9 and Q10 and Q11 pleeeeeeeeeeasearrow_forward
- The components of ATP are (circle one) a. adenosine, ribose and triphosphate b. aniline and triphosphate c. alanine, ribose and triphosphate d. adenine, ribose and triphosphate e. adenosine, deoxyribose and triphosphatearrow_forwardThe nitrogen atom in the indole ring of tryptophan is derived from which amino acid? asparagine glutamine aspartic acid arginine glutamic acidarrow_forward(a) Draw the structural formula for the sugar -D-2 -deoxyribose. (b) Draw the structural formula for the nucleoside deoxyadenosine (it consists of -D-2-deoxyribose and adenine). (c) Draw the structural formula for the nucleotide deoxyadenosine 5'-monophosphate.arrow_forward
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