During the synthesis of cancer drug cis-platin, cis-Pt(NH 3 ) 2 Cl 2 the reason for K 2 [PtCl 4 ] getting converted to K 2 [PtI 4 ] needs to be explained. Concept introduction: The substitution reactions of coordination complexes often visualize the ligands being directed towards a position which is trans to themselves. This nature of ligand decides the the leaving groups. Hence, this effect of ligand over the rate of substitution of another ligand that is trans to it is the trans effect. It is often witnessed in platinum complexes.

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Answer 1

Question

Chapter 24, Problem 37E

Interpretation Introduction

Interpretation:

During the synthesis of cancer drug cis-platin, cis-Pt(NH₃)₂Cl₂ the reason for K₂[PtCl₄] getting converted to K₂[PtI₄] needs to be explained.

Concept introduction:

The substitution reactions of coordination complexes often visualize the ligands being directed towards a position which is trans to themselves. This nature of ligand decides the the leaving groups. Hence, this effect of ligand over the rate of substitution of another ligand that is trans to it is the trans effect. It is often witnessed in platinum complexes.

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Answer 2

Question

Chapter 24, Problem 37E

Interpretation Introduction

Interpretation:

During the synthesis of cancer drug cis-platin, cis-Pt(NH₃)₂Cl₂ the reason for K₂[PtCl₄] getting converted to K₂[PtI₄] needs to be explained.

Concept introduction:

The substitution reactions of coordination complexes often visualize the ligands being directed towards a position which is trans to themselves. This nature of ligand decides the the leaving groups. Hence, this effect of ligand over the rate of substitution of another ligand that is trans to it is the trans effect. It is often witnessed in platinum complexes.

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Answer 3

Question

Chapter 24, Problem 37E

Interpretation Introduction

Interpretation:

During the synthesis of cancer drug cis-platin, cis-Pt(NH₃)₂Cl₂ the reason for K₂[PtCl₄] getting converted to K₂[PtI₄] needs to be explained.

Concept introduction:

The substitution reactions of coordination complexes often visualize the ligands being directed towards a position which is trans to themselves. This nature of ligand decides the the leaving groups. Hence, this effect of ligand over the rate of substitution of another ligand that is trans to it is the trans effect. It is often witnessed in platinum complexes.

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Answer 4

Question

Chapter 24, Problem 37E

Interpretation Introduction

Interpretation:

During the synthesis of cancer drug cis-platin, cis-Pt(NH₃)₂Cl₂ the reason for K₂[PtCl₄] getting converted to K₂[PtI₄] needs to be explained.

Concept introduction:

The substitution reactions of coordination complexes often visualize the ligands being directed towards a position which is trans to themselves. This nature of ligand decides the the leaving groups. Hence, this effect of ligand over the rate of substitution of another ligand that is trans to it is the trans effect. It is often witnessed in platinum complexes.

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Answer 5

Chapter 24, Problem 37E

Interpretation Introduction

Interpretation:

During the synthesis of cancer drug cis-platin, cis-Pt(NH₃)₂Cl₂ the reason for K₂[PtCl₄] getting converted to K₂[PtI₄] needs to be explained.

Concept introduction:

The substitution reactions of coordination complexes often visualize the ligands being directed towards a position which is trans to themselves. This nature of ligand decides the the leaving groups. Hence, this effect of ligand over the rate of substitution of another ligand that is trans to it is the trans effect. It is often witnessed in platinum complexes.

Answer 6

Chapter 24, Problem 37E

Interpretation Introduction

Interpretation:

During the synthesis of cancer drug cis-platin, cis-Pt(NH₃)₂Cl₂ the reason for K₂[PtCl₄] getting converted to K₂[PtI₄] needs to be explained.

Concept introduction:

The substitution reactions of coordination complexes often visualize the ligands being directed towards a position which is trans to themselves. This nature of ligand decides the the leaving groups. Hence, this effect of ligand over the rate of substitution of another ligand that is trans to it is the trans effect. It is often witnessed in platinum complexes.

Answer 7

Chapter 24, Problem 37E

Interpretation Introduction

Interpretation:

During the synthesis of cancer drug cis-platin, cis-Pt(NH₃)₂Cl₂ the reason for K₂[PtCl₄] getting converted to K₂[PtI₄] needs to be explained.

Concept introduction:

The substitution reactions of coordination complexes often visualize the ligands being directed towards a position which is trans to themselves. This nature of ligand decides the the leaving groups. Hence, this effect of ligand over the rate of substitution of another ligand that is trans to it is the trans effect. It is often witnessed in platinum complexes.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 24 - Prob. 1E Ch. 24 - Prob. 2E Ch. 24 - Prob. 3E Ch. 24 - Write appropriate formulas for the following. a....Ch. 24 - Prob. 5E Ch. 24 - Prob. 6E Ch. 24 - Prob. 7E Ch. 24 - Prob. 8E Ch. 24 - Prob. 9E Ch. 24 - Prob. 10E

Solution Summary: The author explains that the substitution reactions of coordination complexes visualize the ligands being directed towards a position which is trans to themselves.

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