Concept explainers
(a)
To draw: The pictorial representation of given molecule as stable chair conformation and to indicate the red group as axial or equatorial.
Interpretation: The pictorial representation of given molecule as stable chair conformation and the indication of red group as axial or equatorial is to be stated.
Concept introduction: The chair conformations are stable forms of cyclohexane and cyclopentane rings as they are free of strain. The substituents present on cyclohexane and cyclopentane rings are arranged at axial and equatorial positions in chair conformation.
(b)
To draw: The pictorial representation of given molecule as stable chair conformation and to indicate the red group as axial or equatorial.
Interpretation: The pictorial representation of given molecule as stable chair conformation and the indication of red group as axial or equatorial is to be stated.
Concept introduction: The chair conformations are stable forms of cyclohexane and cyclopentane rings as they are free of strain. The substituents present on cyclohexane and cyclopentane rings are arranged at axial and equatorial positions in chair conformation.
(c)
To draw: The pictorial representation of given molecule as stable chair conformation and to indicate the red group as axial or equatorial.
Interpretation: The pictorial representation of given molecule as stable chair conformation and the indication of red group as axial or equatorial is to be stated.
Concept introduction: The chair conformations are stable forms of cyclohexane and cyclopentane rings as they are free of strain. The substituents present on cyclohexane and cyclopentane rings are arranged at axial and equatorial positions in chair conformation.
(d)
To draw: The pictorial representation of given molecule as stable chair conformation and to indicate the red group as axial or equatorial.
Interpretation: The pictorial representation of given molecule as stable chair conformation and the indication of red group as axial or equatorial is to be stated.
Concept introduction: The chair conformations are stable forms of cyclohexane and cyclopentane rings as they are free of strain. The substituents present on cyclohexane and cyclopentane rings are arranged at axial and equatorial positions in chair conformation.
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Chapter 25 Solutions
ORGANIC CHEMISTRY MASTERINGCHEM ACCESS
- myo-Inositol, one of the isomers of 1,2,3,4,5,6-hexahydroxycyclohexane, acts as a growth factor in both animals and microorganisms. Draw the most stable chair conformation of myo-inositol.arrow_forwardFind the energy difference between the 2 chair conformations.arrow_forwardDraw both chair conformations of 1-t-butyl-1-methylcyclohexane. Indicate whichis more stable.arrow_forward
- 6. The following compound exhibits two chair conformations. Draw them and indicate which one is more stable. Explain. H H -CH3 H3C H3C CH3arrow_forwardDraw 10 chair conformations of cyclohexane: 5 of them showng the right side pointing up and 5 with the left side pointing up.arrow_forward4) How many axial substituents does the following molecule have in its most stable chair conformation? 2 c) 3 d) 4 eq" S CH₂CH₂ eq axarrow_forward
- Draw the two chair conformations of the following compound A, and indicate which is more stable. CME3 "NH2 Ph Aarrow_forward1) Which molecule is chiral? Redraw it in the R-configuration. H3C, CH3 CH3 H3C CH3 CH3 H3C H3C CH3 H3C H3C CH3 CH3 `CH3 C D E А Вarrow_forwardMenthol, a terpene, exists in a (1R,2S,5R) and(1S,2R,5S) form. Draw the two molecules in theirmost stable chair conformers (IUPAC name: 2-isopropyl-5-methylcyclohexanol).arrow_forward
- Select the Newman projection of the most stable conformation.arrow_forward6) Draw the energetically favored (more stable) chair conformer of the following cyclohexane. H3C OH 110arrow_forward2. Draw the compound in the skeletal form. CH,CH,CH,CH3 H₂CH₂C wy H H NH₂ CH3 3. Draw a chair conformation.arrow_forward
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