The following group of monomers should be ranked from most able to least able to undergo cationic polymerization . Concept Introduction: Cationic polymerization: The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation. The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp 2 carbon bonded to the most h y d r o g e n s .

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Rank the following groups of monomers from most able to least able to undergo anionic polymerization:

List the following group of monomers in order of decreasing ability to undergo cationic polymerization.

Consider monomers A–C. (a) Rank the monomers in order of increasing reactivity in cationic polymerization. (b) Rank the monomers in order of increasing reactivity in anionic polymerization.

Answer 2

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 5

Chapter 27.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 6

Chapter 27.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

Answer 7

Chapter 27.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 12

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Answer 15

Ch. 27.2 - Prob. 1P Ch. 27.2 - Prob. 2P Ch. 27.2 - Prob. 3P Ch. 27.2 - Prob. 4P Ch. 27.2 - Prob. 5P Ch. 27.2 - Prob. 6P Ch. 27.2 - Prob. 7P Ch. 27.2 - Rank the following groups of monomers from most...Ch. 27.2 - Why does methyl methacrylate not undergo cationic...Ch. 27.2 - Explain why, when propylene oxide undergoes...

Solution Summary: The author explains that the order of ability in which the given compounds undergo cationic polymerization is based on the stability of carbocation.

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Chapter 27 Solutions