Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134066639
Author: Bruice
Publisher: PEARSON
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Chapter 27.5, Problem 9P
Why does methyl methacrylate not undergo cationic
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List the following group of monomers in order of decreasing ability to undergo cationic polymerization.
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Chapter 27 Solutions
Organic Chemistry (8th Edition)
Ch. 27.3 - Prob. 1PCh. 27.3 - Prob. 2PCh. 27.3 - Prob. 3PCh. 27.3 - Prob. 4PCh. 27.3 - Prob. 5PCh. 27.3 - Prob. 6PCh. 27.4 - Prob. 7PCh. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P
Ch. 27.6 - Explain why, when propylene oxide undergoes...Ch. 27.6 - Which monomer and which type of initiator can you...Ch. 27.6 - Prob. 13PCh. 27.8 - Draw a short segment of gutta-percha.Ch. 27.8 - Prob. 15PCh. 27.11 - Prob. 16PCh. 27.11 - Write an equation that explains what happens if a...Ch. 27.11 - What happens to polyester slacks if aqueous NaOH...Ch. 27.11 - a. Propose a mechanism for the formation of the...Ch. 27.11 - Explain why, when a small amount of glycerol is...Ch. 27.12 - Propose a mechanism for the formation of melmac.Ch. 27.12 - Prob. 22PCh. 27.13 - Prob. 23PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Prob. 25PCh. 27 - Prob. 26PCh. 27 - Draw the structure of the monomer or monomers used...Ch. 27 - Prob. 28PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Quiana is a synthetic fabric that feels very much...Ch. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Prob. 33PCh. 27 - Poly(vinyl alcohol) is a polymer used to make...Ch. 27 - Five different repeating units are found in the...Ch. 27 - Prob. 37PCh. 27 - A particularly strong and rigid polyester used for...Ch. 27 - Prob. 39PCh. 27 - Which Monomer gives a greater yield of polymer,...Ch. 27 - Prob. 41PCh. 27 - Prob. 42PCh. 27 - Why do vinyl raincoats become brittle as they get...Ch. 27 - The polymer shown below is synthesized by...Ch. 27 - Prob. 45PCh. 27 - How can head-to-head poly(vinyl bromide) be...Ch. 27 - Delrin (polyoxymethylene) is a tough...
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- Order the following monomers with respect to their expected reactivity toward cationic polymerization, and explain your answer:arrow_forwardOrder the following monomers with respect to their expected reactivity toward anionic polymerization, and explain your answer:arrow_forwardCommercial polyisobutylene (PIB or butyl rubber) is synthesized via cationic polymerization. Explain why it cannot be made through free radical or anionic polymerizationarrow_forward
- Write equations for the following reactions: a. Linear polymerization of formaldehyde b. Cyclic polymerization of formaldehyde c. Linear polymerization of acetaldehyde d. Cyclic polymerization of acetaldehydearrow_forwardPolyisobutylene is one of the components of butyl rubber used for making inner tubes. What conditions (cationic, anionic, free-radical) would be most appropriate for polymerization of isobutylene? Explain your answer.arrow_forwardexplain in detail the mechanism for the photoinduced step-growth polymerization of n-ethylcarbazole.arrow_forward
- Do you think that 4-methoxystyrene will more easily undergo anionic or cationic polymerization? Explain your answer.arrow_forwardPoly(vinyl alcohol), a hydrophilic polymer used in aqueous adhesives, is made by polymerizing vinyl acetate and then hydrolyzing the ester linkages. Why is poly(vinyl alcohol) made by this circuitous route? Why not just polymerize vinyl alcohol?arrow_forwardChain branching occurs in cationic polymerization much as it does in free-radical polymerization. Propose a mechanism to show how branching occurs in the cationic polymerization of styrene. Suggest why isobutylene might be a better monomer for cationic polymerization than styrene.arrow_forward
- Please show the product and mechanism for the cationic polymerization of 2-butene using BF3/H2O to catalyze polymerization. Do you expect this to be an effective polymerization strategy for this monomer? Why or why not?arrow_forwardAcrylonitrile polymerized with DMF at 25C, with fecl3.h2o as catalyst and PPh3 as initiator Controlled or not and why(write the reason) Is it Broad or narrow Write the equationarrow_forwardWhy do you think initiator molecule is needed to induce the polymerization of ethylenearrow_forward
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