ORGANIC CHEMISTRY W/CONNECT & ALEKS
6th Edition
ISBN: 9781264683888
Author: SMITH
Publisher: MCG
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Question
Chapter 28.8, Problem 21P
Interpretation Introduction
Interpretation: The
Concept introduction: In step-growth
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Nomex, another aromatic polyamide (compare aramid), is prepared by polymerization
of 1,3-benzenediamine and the diacid chloride of 1,3-benzenedicarboxylic acid. The
physical properties of the polymer make it suitable for high-strength, high-temperature
applications such as parachute cords and jet aircraft tires. Draw a structural formula for
the repeating unit of Nomex.
H,N.
NH2
CI polymerization
Nomex
1,3-Benzenediamine
1,3-Benzene-
dicarbonyl chloride
Thermosetting resins similar to Bakelite (Section 30.7) have also been prepared from renewable feedstocks. One method uses cardinol, the major constituent of the liquid obtained from roasted cashew nutshells. What polymer is obtained when cardinol is treated with formaldehyde (H2C = O) in the presence of a proton source?
Thermosetting resins similar to Bakelite (Section 31.7) have also been prepared from renewable
feedstocks. One method uses cardinol, the major constituent of the liquid obtained from roasted
cashew nutshells. What polymer is obtained when cardinol is treated with formaldehyde (H2C=O)
in the presence of a proton source?
он
H2C=0
H+
cardinol
Chapter 28 Solutions
ORGANIC CHEMISTRY W/CONNECT & ALEKS
Ch. 28.1 - Prob. 1PCh. 28.2 - Prob. 2PCh. 28.2 - Prob. 3PCh. 28.2 - Draw the mechanism for the radical polymerization...Ch. 28.2 - Prob. 8PCh. 28.2 - Prob. 9PCh. 28.2 - Prob. 10PCh. 28.3 - Problem 30.12
What polymer is formed by anionic...Ch. 28.5 - Prob. 12PCh. 28.5 - Prob. 13P
Ch. 28.6 - Problem 30.15
What polyamide is formed from each...Ch. 28.6 - Prob. 19PCh. 28.7 - Prob. 20PCh. 28.8 - Prob. 21PCh. 28.9 - Prob. 22PCh. 28.9 - Prob. 23PCh. 28 - Prob. 24PCh. 28 - Prob. 25PCh. 28 - 30.30 Draw each polymer in Problem 30.29 using the...Ch. 28 - Prob. 44PCh. 28 - 30.49 Draw the products of each reaction.
a. e....Ch. 28 - Prob. 56PCh. 28 - 30.56 Compound A is a novel poly (ester amide)...Ch. 28 - 30.57 Researchers at Rutgers University have...Ch. 28 - 30.58 Melmac, a thermosetting polymer formed from...Ch. 28 - 30.59 Although chain branching in radical...Ch. 28 - Prob. 61P
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