Concept explainers
Which compound in each pair has the higher boiling point?
a. or c. or
b. or d. or
(a)
Interpretation: In the given pair, the compound with the higher boiling point is to be predicted.
Concept introduction: Boiling point is defined as the temperature at which the compound is converted to a gaseous state.
The boiling point of compounds depends upon the molecular weight and the intermolecular forces present in the compounds. The intermolecular forces are the forces that exist in between the two or more atoms in a compound. Due to strong intermolecular forces, the molecule will require more energy to break the bonds. The compounds that have ionic bonding and hydrogen bonding will possess higher boiling point.
Answer to Problem 3.13P
In the given pair of compounds,
Explanation of Solution
The given compounds are
In
The increasing order of boiling point with intermolecular forces is,
Hence, the boiling point of
In the given pair of compounds,
(b)
Interpretation: In the given pair, the compound with the higher boiling point is to be predicted.
Concept introduction: Boiling point is defined as the temperature at which the compound is converted to a gaseous state.
The boiling point of compounds depends upon the molecular weight and the intermolecular forces present in the compounds. The intermolecular forces are the forces that exist in between the two or more atoms in a compound. Due to strong intermolecular forces, the molecule will require more energy to break the bonds. The compounds that have ionic bonding and hydrogen bonding will possess higher boiling point.
Answer to Problem 3.13P
In the given pair of compounds,
Explanation of Solution
The given compounds are
In
In the given pair of compounds,
(c)
Interpretation: In the given pair, the compound with the higher boiling point is to be predicted.
Concept introduction: Boiling point is defined as the temperature at which the compound is converted to a gaseous state.
The boiling point of compounds depends upon the molecular weight and the intermolecular forces present in the compounds. The intermolecular forces are the forces that exist in between the two or more atoms in a compound. Due to strong intermolecular forces, the molecule will require more energy to break the bonds. The compounds that have ionic bonding and hydrogen bonding will possess higher boiling point.
Answer to Problem 3.13P
In the given pair of compounds,
Explanation of Solution
The given compounds are
In both the compounds,
In the given pair of compounds,
(d)
Interpretation: In the given pair, the compound with the higher boiling point is to be predicted.
Concept introduction: Boiling point is defined as the temperature at which the compound is converted to a gaseous state.
The boiling point of compounds depends upon the molecular weight and the intermolecular forces present in the compounds. The intermolecular forces are the forces that exist in between the two or more atoms in a compound. Due to strong intermolecular forces, the molecule will require more energy to break the bonds. The compounds that have ionic bonding and hydrogen bonding will possess higher boiling point.
Answer to Problem 3.13P
In the given pair of compounds,
Explanation of Solution
The given compounds are
Van der Waals forces exist in both the compounds due to the presence of
In the given pair of compounds,
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Chapter 3 Solutions
ORGANIC CHEMISTRY (LOOSE)-MOLYMOD PKG.
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- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning