GENERAL CHEMISTRY(LL)-W/MASTERINGCHEM.
GENERAL CHEMISTRY(LL)-W/MASTERINGCHEM.
11th Edition
ISBN: 9780134566030
Author: Petrucci
Publisher: PEARSON
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Chapter 3, Problem 3E

Give the structure formulas of the molecules shown in Exercise 1 (b), (d), and (e).

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1. (a) 5.00g of caffeine is found to contain 2.47g of carbon, 0.26g of hydrogen, 1.44g of nitrogen and 0.83g of oxygen. The molar mass of caffeine is twice the mass of its empirical formula unit.(R.A.M. C=12.01, H=1.01, O=16.00, N=14.01)(i) Calculate the empirical formula of caffeine.
(a) What is a hydrocarbon? (b) Butane is the alkane with a chain of four carbon atoms. Write a structural formula for this compound and determine its molecular and empirical formulas.
In your own words, define or explain the followingterms or symbols: (a) formula unit; (b) (c) molecular compound; (d) binary compound; (e) hydrate.

Chapter 3 Solutions

GENERAL CHEMISTRY(LL)-W/MASTERINGCHEM.

Ch. 3 - Determine the number of moles of a. N2O4 in a 115...Ch. 3 - Determine the mass, in grams, of a. 2.10102 molS2...Ch. 3 - The content of is 15.5g/100 mLblood. The molar...Ch. 3 - In white phosphorus, P atoms are joined into P,...Ch. 3 - Prob. 15ECh. 3 - Prob. 16ECh. 3 - For the mineral torbernite, Cu( UO2)2( PO4)2,8H2O...Ch. 3 - For the compound Ge[S( CH 2 )4CH2]4 determine a....Ch. 3 - Determine the mass percent H in the hydrocarbon...Ch. 3 - Determine the mass percent O in the mineral...Ch. 3 - Determine the mass percent H in the hydrocarbon...Ch. 3 - Prob. 22ECh. 3 - Determine the mass percent of each of the elements...Ch. 3 - Prob. 24ECh. 3 - Determine the percent, by mass,of the indicated...Ch. 3 - All of the following minerals are semiprecious or...Ch. 3 - Without doing calculations, arrange the following...Ch. 3 - Prob. 28ECh. 3 - Two oxides of sulfur have nearly identical...Ch. 3 - An oxide of chromium used in chrome plating has a...Ch. 3 - Diethylene glycol, used to de-ice aircraft, is a...Ch. 3 - Prob. 32ECh. 3 - Determine the empirical formula of (a) the...Ch. 3 - Prob. 34ECh. 3 - A compound of carbon and hydrogen consists of...Ch. 3 - Selenium, an element used in the manufacture of...Ch. 3 - Indigo, the dye for blue jeans, has a percent...Ch. 3 - Prob. 38ECh. 3 - Prob. 39ECh. 3 - The element X forms the compound XOCI2 containing...Ch. 3 - Prob. 41ECh. 3 - Two compounds of CI and X are found to have...Ch. 3 - A 0.1888 g sample of a hydrocarbon produces 0.6260...Ch. 3 - Para-cresol (p-cresol) is used as a disinfectant...Ch. 3 - Dimethylhydrazine is a carbon-hydrogen-nitrogen...Ch. 3 - Prob. 46ECh. 3 - Without doing detailed calculations, explain which...Ch. 3 - Prob. 48ECh. 3 - A 1.562 g sample of the alcohol CH2CHOHCH2CH2 is...Ch. 3 - Prob. 50ECh. 3 - Indicate the oxidation state of the underlined...Ch. 3 - Indicate the oxidation state of S in (a) SO42 (b)...Ch. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Prob. 55ECh. 3 - Hydrogen and oxygen usually have oxidation states...Ch. 3 - Prob. 57ECh. 3 - Name these compounds: (a)Ba(...Ch. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - Prob. 61ECh. 3 - Prob. 62ECh. 3 - Write a formula for (a) the chloride of titanium...Ch. 3 - Write formula for (a) an oxide of nitrogen with N...Ch. 3 - Prob. 65ECh. 3 - Supply the formula for the acids: (a) hydrofluoric...Ch. 3 - Name the following compounds and specify which...Ch. 3 - Prob. 68ECh. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - Anhydrous CuSO4 can be used to dry liquids in...Ch. 3 - Anhydrous sodium sulfate, Na2SO4 absorbs water...Ch. 3 - A certain hydrate is found to have the composition...Ch. 3 - An 8.129 g sample of MgSO4H2O is heated until all...Ch. 3 - Prob. 75ECh. 3 - Prob. 76ECh. 3 - Prob. 77ECh. 3 - Prob. 78ECh. 3 - Prob. 79ECh. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - The mineral spodumene has the empirical formula...Ch. 3 - Prob. 84IAECh. 3 - Prob. 85IAECh. 3 - The important natural sources of boron compounds...Ch. 3 - Prob. 87IAECh. 3 - By analysis, a compound was found to contain 26.58...Ch. 3 - Prob. 89IAECh. 3 - What is the molecular formula of a hydrocarbon...Ch. 3 - A hydrocarbon mixture consists of 601% by mass of...Ch. 3 - A 0.732 g mature of methane, CH4 and ethane, C2H5...Ch. 3 - The density of a mixture of H2SO4 and water is...Ch. 3 - Prob. 94IAECh. 3 - Prob. 95IAECh. 3 - Prob. 96IAECh. 3 - Prob. 97IAECh. 3 - Prob. 98IAECh. 3 - The metal M forms the sulfate M2( SO4)2. A 0.738 g...Ch. 3 - Prob. 100IAECh. 3 - Prob. 101IAECh. 3 - Prob. 102IAECh. 3 - A 1.013 g sample of ZnSO4H2O is dissolved in water...Ch. 3 - The iodide ion in a 1.552 g sample of the compound...Ch. 3 - Prob. 105IAECh. 3 - The insecticide dieldrin contains carbon, oxygen,...Ch. 3 - Prob. 107IAECh. 3 - The atomic mass of Bi is to be determined by...Ch. 3 - A piece of gold (Au) foil measuring 0.25mm15mm is...Ch. 3 - Prob. 110IAECh. 3 - Prob. 111IAECh. 3 - All-purpose fertilizers contain the essential...Ch. 3 - A hydrate of copper(II) sulfate, when heated, goes...Ch. 3 - Prob. 114FPCh. 3 - Prob. 115SAECh. 3 - Prob. 116SAECh. 3 - Prob. 117SAECh. 3 - Prob. 118SAECh. 3 - Prob. 119SAECh. 3 - Three of the following formulas might be ether an...Ch. 3 - Prob. 121SAECh. 3 - Prob. 122SAECh. 3 - Iron is present red blood and acts to carry oxygen...Ch. 3 - Prob. 124SAECh. 3 - Prob. 125SAECh. 3 - Prob. 126SAECh. 3 - Prob. 127SAECh. 3 - Prob. 128SAECh. 3 - Prob. 129SAECh. 3 - Which compound has a molar mass of...Ch. 3 - Prob. 131SAECh. 3 - Prob. 132SAECh. 3 - A hydrate of Na2SO2 contains almost exactly 50%...Ch. 3 - Malachite is a common copper-containing mineral...Ch. 3 - Prob. 135SAECh. 3 - Ibuprofen is a compound used in painkiller. When a...Ch. 3 - Prob. 137SAE
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