Concept explainers
Tin(IV) chloride is used as an external coating on glass to toughen glass containers. It is prepared by reacting tin with chlorine gas.
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Chapter 3 Solutions
CHEMISTRY:PRIN.+REACTIONS-OWLV2 ACCESS
- Nitric acid is produced commercially by the Ostwald process, represented by the following equations: 4NH3(g)+5O24NO(g)+6H2O(g)2NO(g)+O2(g)2NO2(g)3NO2(g)+H2O(l)2HNO3(aq)+NO(g) What mass of NH3 must be used to produce 1.0 106 kg HNO3 by the Ostwald process? Assume 100% yield in each reaction, and assume that the NO produced in the third step is not recycled.arrow_forwardEthanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.arrow_forward(a) Butane gas, C4H10, can burn completely in air [use O2(g) as the other reactant] to give carbon dioxide gas and water vapor. Write a balanced equation for this combustion reaction. (b) Write a balanced chemical equation for the complete combustion of C3H7BO3, a gasoline additive. The products of combustion are CO2(g), H2O(g), and B2O3(s).arrow_forward
- 3.14 A number of compounds are used in cement, and reactions among them occur when water is added. In one, CaO reacts with Al2O3 and water to form Ca3Al2(OH)12. Write a bal- anced chemical equation for this process.arrow_forwardOne of the ways to remove nitrogen monoxide gas, a serious source of air pollution, from smokestack emissions is by reaction with ammonia gas, NH3. The products of the reaction, N2 and H2O, are not toxic. Write the balanced equation for this reaction. Assign an oxidation number to each element in the reactants and products, and indicate which element is oxidized and which is reduced.arrow_forwardThe carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.arrow_forward
- Silicon is produced for the chemical and electronics industries by the following reactions. Give the balanced equation for each reaction. a. SiO2(s)+C(s)arefurnaceElectricSi(s)+CO(g) b. Liquid silicon tetrachloride is reacted with very pure solid magnesium, producing solid silicon and solid magnesium chloride. c. Na2SiF6(s) + Na(s) Si(s) + NaF(s)arrow_forward4.8 In an experiment carried out at very low pressure, 13x1015 molecules of H2 are reacted with acetylene, C2H2, to form ethane, C2H6, on the surface of a catalyst. Write a balanced chemical equation for this reaction. How many molecules of acetylene are consumed?arrow_forwardDisulfur dichloride, S2Cl2, is used to vulcanize rubber. It can be made by treating molten sulfur with gaseous chlorine. S8() + 4 Cl2(g) 4 S2Cl2(g) Complete this table of reaction quantities for the production of 103.5 g S2Cl2.arrow_forward
- 4.28 One of the steps in the manufacture of nitric acid is the oxidation of ammonia shown in this equation: 4NH3(g)+5O2(g)4NO(g)+6H2O(g) If 43.0 kg of NH3 reacts with 35.4 kg of O2, what mass of NO forms?arrow_forward4.69 The pictures below show a molecular-scale view of a chemical reaction between H2 and CO to produce methanol, CH3OH. The box on the left represents the reactants at the instant of mixing, and the box on the right shows what is left once the reaction has gone to completion. Was there a limiting reactant in this reaction? If so, what was it? Write a balanced chemical equation for this reaction. As usual, your equation should use the smallest possible whole number coefficients for all substances.arrow_forwardWhen organic compounds containing sulfur are burned, sulfurdioxide is produced. The amount of SO2 formed can be determined by the reaction with hydrogen peroxide: H2O2(aq)+SO2(g)H2SO4(aq) The resulting sulfuric acid is then titrated with a standard NaOH solution. A 1.302-g sample of coal is burned and the SO2 is collected in a solution of hydrogen peroxide. It took 28.44 mL of a 0.1000-M NaOH solution to titrate the resulting sulfuric acid. Calculate the mass percent of sulfur in the coal sample. Sulfuric acid has two acidic hydrogens.arrow_forward
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