(a)
Interpretation:
The choice of system and surroundings has to be indicated and explained considering the given statement.
Concept Introduction:
Generally, in
(b)
Interpretation:
The choice of system and surroundings selected from given reaction has to be explained.
Concept Introduction:
Refer part (a).
(c)
Interpretation:
The energy and material transferred has to be identified.
Concept Introduction:
Refer part (a).
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Chapter 4 Solutions
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
- Solid ammonium chloride is added to water in a beaker and dissolves. The beaker becomes cold to the touch. Make an appropriate choice of system and surroundings and describe it unambiguously. Explain why you chose the system and surroundings you did. Identify transfers of energy and material into and out of the system that would be important for you to monitor in your study. Is the process of dissolving NH4Cl(s) in water exothermic or endothermic? Explain your answer.arrow_forwardSuppose that you are studying kinetic energy of helium molecules: A helium weather balloon rises to an altitude of 40,000 ft; the temperature of the gas drops to 70 F. (a) Make an appropriate choice of system and surroundings and describe it unambiguously. (b) Explain why you chose the system and surroundings you did. (c) Identify transfers of energy and material into and out of the system that would be important for you to monitor in your study.arrow_forwardA rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.arrow_forward
- Describe the interconversions of potential and kinetic energy in a moving pendulum. A moving pendulum eventually comes to rest. Has the energy been lost? If not, what has happened to it?arrow_forwardThe temperature of the cooling water as it leaves the hot engine of an automobile is 240 F. After it passes through the radiator it has a temperature of 175 F. Calculate the amount of heat transferred from the engine to the surroundings by one gallon of water with a specific heat of 4.184 J/g oC.arrow_forwardA piece of chocolate cake contains about 400 calories. A nutritional calorie is equal to 1000 calories (thermochemical calories), which is equal to 4.184 kJ. How many 8-in-high steps must a 180-lb man climb to expend the 400 Cal from the piece of cake? See Exercise 28 for the formula for potential energy.arrow_forward
- Determine whether the statements given below are true or false. Consider enthalpy (H). (a) It is a state property. (b) qreaction(atconstantP)=H=HproductsHreactants (c) The magnitude of H is independent of the amount of reactant. (d) In an exothermic process, the enthalpy of the system remains unchanged.arrow_forwardInsoluble PbBr2(s) precipitates when solutions of Pb(NO3)2(aq) and NaBr(aq) are mixed. Pb(NO3)2(aq) + 2 NaBr(aq) PbBr2(s) + 2 NaNO3(aq) rH = ? To measure the enthalpy change, 200. mL. of 0.75 M Pb(NO3)2(aq) and 200. mL of 1.5 M NaBr(aq) are mixed in a coffee-cup calorimeter. The temperature of the mixture rises by 2.44 C. Calculate the enthalpy change for the precipitation of PbBr2(s), in kJ/mol. (Assume the density of the solution is 1.0 g/mL., and its specific heat capacity is 4.2 J/g K.)arrow_forwardA gas is cooled and loses 82 J of heat. The gas contracts as it cools, and work done on the system equal to 29 J is exchanged with the surroundings. What are q, w, and U?arrow_forward
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